• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.3
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• pp.183-189
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• 2013

The chalcogenide glass has superior optical properties in IR region transmittances. We have determined the composition of GeSbSe chalcogenide glass for the application of good IR lenses, resulting in the composite rate of $Ge_{19}Sb_{23}Se_{58}$. The optical, structural, thermal and physical properties were measured by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), X-ray computed tomography (X-ray CT) respectively. The fabrication of the chalcogenide glass lens for infrared optics applications was proposed using a diamond turning machining technology which is known as the suitable ways for the production cost reduction and the accurate fabrication process control.

• Bulletin of the Korean Chemical Society
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• v.11 no.5
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• pp.396-399
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• 1990

Fourier transform infrared spectroscopy has been applied to the characterization of titania surface. The bands due to surface OH groups were observed to be more intense in the reduced titania than in the oxidized titania. The IR spectra of CO adsorbed on titania exhibited two C-O stretching bands, namely at 2187 and 2209 cm$^{-1}$. The intensities were stronger in the oxidized titania.The 2187 cm$^{-1}$-peak was attributed to CO coordinated to $Ti^{4+}_{5c}$ (subscriptindicates the coordination number of the coordinatively unsaturated cation by oxygen ions), while the 2209 cm-1-peak due to the $Ti^{4+}_{4c}{\cdots}$CO complex.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1301-1304
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• 2010

The Indium modified mesoporous zeolite AlMCM-41 were synthesized by hydrothermal method and characterized by powder X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) techniques. The Knoevenagel condensation of aldehyde with malononitrile or ethyl cyanoacetate was carried out at reflux condition in ethanol by using heterogeneous In/AlMCM-41 catalyst. This method is fast, efficient, easy work-up and eco-friendly to afford the corresponding Knoevenagel adducts. The catalyst was recovered and reused for several cycles with consistent activity.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.158.1-158.1
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• 2011

In this work, we prepared ultramicroporous carbons (UC) prepared by pyrolyzing poly(vinylidene fluoride) with different carbonization temperatures, and investigated the hydrogen storage behaviors. The surface functional groups and specific elements of UC were confirmed by Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS), respectively. Textural properties were analyzed using $N_2$ adsorption isotherms at 77 K. The hydrogen storage capacity of the UC samples were investigated by BEL-HP at 298 K/10 MPa. From the results, it was found that the hydrogen storage capacity was enhanced with increasing of specific surface area, resulting from the formation of ultramicropore on the UC.

• Textile Coloration and Finishing
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• v.20 no.5
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• pp.1-6
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• 2008

3-(Hydroxyphenyl phosphinyl) propanoic acid (HPPA) has been one of the most commonly used durable flame retardant agents for polyethylene terephthalate (PET) for many years. We intended to explore the application of HPPA to cellulose fabrics as formaldehyde-free phosphorus based flame retardants (FRs) through green chemistry process. The flame retardancy of the flame-retardant treated cellulose fabrics were characterized by using inductively coupled plasma spectroscopy (ICP) and limiting oxygen index (LOI). Structural changes of the treated cellulose fabrics were carried out by thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. To enhance the flame retardancy of HPPA treated cellulose fibers, glycerol polyglycidyl ether (GPE), a crosslinking agent was employed. Both HPPA and GPE treated cotton fabric imparted an LOI value over 26.

• Journal of the Korean institute of surface engineering
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• v.34 no.3
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• pp.258-263
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• 2001

Siloxane thin films were fabricated on a silicon wafer by spin-coating using a siloxane solution made by the sol-gel process. Fluorine was doped using$ CF_4$ plasma treatment. The film was then annealed in-situ state in the nitrogen atmosphere. In order to examine the influence of annealing and fluorine doping on the siloxane thin film, thermogravimetric-differential thermal analysis (TG-DTA), Fourier transform-infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) were used and the dielectric constant was determined by the high-frequency capacitance-voltage method. Stable siloxane films could be obtained by in-situ annealing in a nitrogen atmosphere after $CF_4$ plasma treatment, and the dielectric value of the film was $\varepsilon$ 2.5.

• Textile Coloration and Finishing
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• v.20 no.4
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• pp.1-7
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• 2008

Methacryloxypropyl trimethoxysilane (MAPTMS), a hybrid organic-inorganic monomer, was photografted onto PET fabric using benzophenone (BP) as a photoinitiator. It was found that a UV energy of 43.2J/$cm^2$ was required to optimally photograft the MAPTMS onto PET fabrics which was applied with an aqueous formulation of 10% MAPTMS, 20% BP and 0.5% N-Methyldiethanol amine (MDEA). The MDEA additive was efficient in reducing atmospheric oxygen inhibition of polymer radicals which eliminated compulsory nitrogen inerting. The surface grafting of PET fabrics was verified by fourier transform infrared spectroscopy (FT-IR) and scanning electron spectroscopy (SEM). The grafted PET fabrics with the hybrid monomer showed higher thermal stability due to the introduced silane component in the monomer as ascertained by higher char content at 800$^{\circ}C$, which increased to 14.5% for the 15.8% grafting compared to 8.2% for the untreated.

• Journal of Magnetics
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• v.19 no.2
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• pp.101-105
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• 2014

In this work, Zinc ferrite nanoparticles have been prepared by various methods, conventional (ZC), mechanochemical processing (ZM) and Sol-Gel (ZS) method, to compare their structural and magnetic properties. The cation distribution obtained from XRD shows the degrees of inversions are 4%, 14.8%, and 16.4% from the normal $ZnFe_2O_4$ structure. Fourier transform infrared spectroscopy (FT-IR) confirms changes in cation distribution of $ZnFe_2O_4$ fabricated by sol-gel and mechanochemical processing. The $^{57}Fe$ M$\ddot{o}$ssbauer spectra of the samples were recorded at room temperature. The spectra exhibit a line broadening. The magnetic properties of the samples were studied by vibration sample magnetometer (VSM) at room temperature and the results show that the sample ZM has ferrimagnetic behaviour.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1856-1860
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• 2012

$SnO_2/SiO_2$ nanocomposite has been synthesized by using sol-gel method. Prepared catalytic materials has been well characterized by using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmer-Teller (BET) surface area, and temperature-programmed desorption of ammonia ($NH_3$-TPD). $SnO_2/SiO_2$ nanocomposite catalyzed synthesis of 2-arylbenzothiazoles by the cyclocondensation of 2-aminothiophenol and aromatic aldehydes under reflux condition in 1:1 EtOH:$H_2O$. After completion of the reaction, catalyst can be recovered efficiently and reused with consistent activity.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.159-159
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• 2013

In this studying, we investigated the basic properties of N-doped plasma polymer. The N-doped plasma polymer thin films were deposited by radio frequency (13.56 MHz) plasma-enhanced chemical vapor deposition method. Various carbon-source were used as organic precursor with hydrogen gas as the precursor bubbler gas. Additionally, ammonia gas [NH3] was used as nitrogen dopant. The as-grown polymerized thin films were analyzed using cyclic voltammetry, ellipsometry, Fourier-transform infrared [FT-IR] spectroscopy, Raman spectroscopy, FE-SEM, and water contact angle measurement. Electronic property of N-doped plasma thin film is changed as flow rate of the NH3 gas.