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http://dx.doi.org/10.5012/bkcs.2010.31.5.1301

Indium Modified Mesoporous Zeolite AlMCM-41 as a Heterogeneous Catalyst for the Knoevenagel Condensation Reaction  

Katkar, Santosh S. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Lande, Machhindra K. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Arbad, Balasaheb R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Rathod, Sandip B. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.5, 2010 , pp. 1301-1304 More about this Journal
Abstract
The Indium modified mesoporous zeolite AlMCM-41 were synthesized by hydrothermal method and characterized by powder X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) techniques. The Knoevenagel condensation of aldehyde with malononitrile or ethyl cyanoacetate was carried out at reflux condition in ethanol by using heterogeneous In/AlMCM-41 catalyst. This method is fast, efficient, easy work-up and eco-friendly to afford the corresponding Knoevenagel adducts. The catalyst was recovered and reused for several cycles with consistent activity.
Keywords
Knoevenagel condensation; Mesoporous zeolite In/AlMCM-41; Heterogeneous catalyst;
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