• Proceedings of the KSME Conference
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• 2007.05a
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• pp.409-414
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• 2007

Wettability of solid surfaces with liquids is governed by the chemical properties and the microstructure of the surfaces. We report on the preparation of liquid-repellent surfaces using surface-attached monolayers of perfluorinated polymer molecules on porous silica substrates. A covalent attachment of the polymer molecules to the substrate is achieved by generation of the polymer chains through starting a surface-initiated radical-chain polymerization of a fluorinated monomer. To this, self-assembled monolayers of azo initiators are attached to silica substrates, which are used to kick off the polymerization reaction in situ. The growth of the fluorinated polymer films and the characterization of the obtained surfaces by surface plasmon spectroscopy, XPS, and contact angle measurements is described. It is shown that perfluorinated polymer films can be grown with controlled thicknesses on flat and even on porous silica surfaces, essentially without changing the surface roughness. The combination of the low surface energy coating and the surface porosity allows generation of materials which are both water and oil repellent.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.10a
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• pp.33-37
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• 2009

Finite-element methods are used to study non-adhesive, frictionless rough contact of elastic and plastic solids. Roughness on spherical surfaces is realized by self-affine fractal. True contact area between the rough surfaces and flat rigid surfaces increases with power law under external normal loads. The power exponent is sensitive to surface roughness as well as the curvature of spherical geometry. Surface contact pressures are analyzed and compared for the elastic and plastic solids. Distributions of local contact pressure are shown dependent on the surface roughness and the yield stress of plastic solids.

• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1131-1136
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• 2008

The electrical repulsive energy between two model cylinders was calculated by solving nonlinear Poission- Boltzmann (P-B) equation under Derjaguin approximation. Effects of the surface potential, Debye screening length, and configuration of cylinders on the repulsive interaction energy were examined. Due to the anisotropy of the shape of cylinder, the interaction repulsive energy showed dependence to the configuration of particles; cylinders aligned in end-to-end configuration showed largest repulsive energy and crossed particles had lowest interaction energy. The configuration effect is originated from the curvature effect of the interacting surfaces. The curved surfaces showed less repulsive energy than flat surfaces at the same interacting surface area. The configuration dependency of interaction energy agreed with the previous analytical solution obtained under the linearized P-B equation. The approach and results present in this report would be applicable in predicting colloidal behavior of cylindrical particles.

• Journal of the Korean Society of Industry Convergence
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• v.14 no.3
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• pp.101-104
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• 2011

In this study, the experiments for surface enhancement of silver surfaces were done, where we checked the characteristics of silver surfaces made by Tollen's method. The surface enhancement of Quinoline was analyzed by three kind of silver mirror substrates. The assignments of the vibrational bands shown in SERS spectra are given based on both literature and the semi-empirical calculations at the PM3 methods. Finally, we deduced that the adsorption orientation of quinoline was little tilted flat to the silver mirror surfaces by using of the surface selection rules.

• Journal of the korean Society of Automotive Engineers
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• v.7 no.3
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• pp.42-55
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• 1985

The study is concerned with the investigation of curved line folding of developable surface from flat sheets of metal. General geometric relations among folding line, folded surface, folded angle are derived. From the derived geometric relations, the required plastic work and punch force are derived for the first approximation. Five methods of forming are suggested and the experiment is carried out using two chosen methods for the prismatic developable surfaces of which cross-sections have 103.deg.arc, 180.deg.arc, sinusoidal shape. In the die design for the tolding of prismatic developable surfaces, a stack of sheets were used to form shapes of the dies by which acceptable folded surfaces were obtained. The computed plastic work and punch force turned out to be in reasonable agreement with the experimental result.

• Korean Journal of Computational Design and Engineering
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• v.11 no.3
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• pp.157-163
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• 2006

Surfaces of many engineering structures, especially, those of ships are commonly made out of either single- or double-curved surfaces to meet functional requirements. The first step in the fabrication process of a three-dimensional design surface is unfolding or flattening the surface, otherwise known as planar development, so that manufacturers can determine the initial flat plate which is required to form the design shape. In this paper, an algorithm for optimal approximated development of a general curved surface, including both single- and double-curved surfaces, is established by minimizing the strain energy of deformation from its planar development to the design surface. The unfolding process is formulated into a constrained nonlinear programming problem, based on the deformation theory and finite element. Constraints are subjected to the characteristics of the fabrication method. And the design surface, or the curved shell plate is subdivided by automatic mesh generation.

• Journal of the Society of Naval Architects of Korea
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• v.41 no.4
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• pp.59-67
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• 2004

Direct numerical simulations of turbulent flows over riblet-mounted surfaces are performed to educe the mechanism of drag reduction by riblets. Numerical simulations are performed for flow fields with R $e_$\tau$/=180. For riblet ridge angle $\alpha$=60$^{\circ}$, two different riblet spacings of $s^+/=20 and 40 are used in this study. The computed drag on the riblet surfaces is in good agreement with existing computational and experimental data. The mean velocity profiles show upward and downward shifts in the log-law for drag-decreasing and drag-increasing cases, respectively Turbulence statistics above the riblets are computed and compared with those above a flat plate. The purpose of this study is in two categories: first, to understand the drag reduction mechanism on riblet surface, second, to verify our own code by comparison of the present results with those from previous studies.udies.

• Tribology and Lubricants
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• v.22 no.5
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• pp.237-242
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• 2006

Surfaces found in nature, including biological surfaces have been providing inspiration to modify/fabricate artificial surfaces as solutions for tribological applications. As an example, the concept of 'lotus-effect' has motivated tribologists world wide to modify/fabricate surfaces for enhanced tribological performance. These was done by creating nano/micro-scale asperities on various surfaces using ion beam milling and ion-beam assisted roughening. In order to understand the attributes of natural surfaces, which are inspirational to tribologists, we characterized the surface of two natural surfaces-Nelumbo nucifera (lotus) and Colocasia esculenta leaves. Further, we evaluated their micro-scale friction property, both in their fresh and dried conditions. The characterization of surfaces was conducted using a confocal microscope and SEM, which involved the evaluation of size and distribution of protuberances. The micro-scale friction property was evaluated using a ball-on-flat type micro-tribo tester, under reciprocating motion. A soda lime glass ball (2 mm diameter) was used in these tests. Tests were conducted at the applied normal load of $3000{\mu}N$, at a sliding speed of 1 mm/sec for a scan length of 3 mm. All experiments were conducted at ambient temperature ($24{\pm}1^{\circ}C}$) and relative humidity ($45{\pm}5%$). It was observed that the friction behaviour of the natural surfaces was influenced by their surface characteristics (morphology and distribution of protuberances) and also by the condition (fresh or dried) in which they were tested.

• Clean Technology
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• v.22 no.3
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• pp.203-207
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• 2016

Here, we report a novel fabrication technique for patchable organic lasing sheet based on non-volatile liquid organic semiconductors and freestanding polymeric film with high flexibility and patchability. For this work, we have fabricated the second-order DFB grating structure, which leads to surface emission, embedded in the freestanding polymeric film. Using an ultra-violet (UV) curable polyurethaneacrylate (PUA) mixture, the periodic DFB grating structure can be easily prepared on the freestanding polymeric film via a simple UV curing process. Due to unsaturated acrylate remained in the PUA mixture after UV curing, the freestanding PUA film provides adhesive properties, which enable mounting of the patchable organic lasing sheet onto non-flat surfaces with conformal contact. To achieve laser actions in the freestanding resonator structure, a composite material of liquid 9-(2-ethylhexyl)carbazole (EHCz) and organic laser dyes was used as the laser medium. Since the degraded active materials can be easily refreshed by a simple injection of the liquid composite, such a non-volatile liquid organic semiconducting medium has degradation-free and recyclable characteristics in addition to other strong advantages including tunable optoelectronic responses, solvent-free processing, and ultimate mechanical flexibility and uniformity. Lasing properties of the patchable organic lasing sheet were also investigated after mounting onto non-flat surfaces, showing a mechanical tunability of laser emission under variable surface curvature. It is anticipated that these results will be applied to the development of various patchable optoelectronic applications for light-emitting displays, sensors and data communications.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.6
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• pp.50-58
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• 2009

Micro laser fabrication techniques can potentially be used for the manufacture of microstructures on the thin flat surfaces with large diameter that are frequently used in semiconductor industries. However, the large size of wafers can cause the degraded machining accuracy of the surface because it can be tilted or distorted by geometric errors of machines or the holding fixtures, etc. To overcome these errors the off-line focusing error compensation method is proposed. By using confocal autofocus system, the focusing error profile of machined surface is measured along the pre-determined path and can be compensated at the next machining process by making the corrected motion trajectories. The experimental results for silicon wafers and invar flat surfaces show that the proposed method can compensate the focusing error within the level of below $6.9{\mu}m$ that is the depth of focus required for the laser micromachining process.