• Title/Summary/Keyword: Flame retardancy

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A Comparative Study on the Effect of Fire Retardancy of the Plywood Treated by Ammonium Sulphate and Monoammonium Phosphate (황산암모늄과 제 1 암모늄처리(處理) 합판(合板)의 내화효과에 관(關)한 비교연구(比較硏究))

  • Lee, Phil-Woo;Kim, Cheol-San
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.3
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    • pp.23-30
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    • 1983
  • This experiment was carried out for diminishing the material loss and the damage of human life due to the fire disaster by treating plywood with fire retardant chemical solution. At this study, we observed and measured chemical retention, burning point, maximum flame length, flame exausted time, carbonized area, and weight loss of plywood treated by each solution of ammonium sulphate [$(NH_4)_2SO_4$] and monoammonium phosphate [$NH_4H_2PO_4$]. Obtained results at the study may be summarized as follows: 1. In case of monoammonium phosphate-treated plywood, every tested item of fire retardancy was shown more excellent at the 25% chemical concentration and shown also at 9 hours treatment except maximum flame length compared with ammonium sulphate-treated plywood. 2. However in case of ammonium sulphate-treated plywood, 6 hours treatment of fire retardancy was better than 9 hours treating time. 3. Monoammonium phosphate was generally better than ammonium sulphate in every tested item.

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Flame Retardant Synergistic Performance between Cyclic Diphosphonate Ester and Melamine in Polyamide 6 (Polymide 6에서 Cyclic Diphosphonate Ester와 Melamine의 난연 효과)

  • Wang, Xueli;Jiang, Jianming;Yang, Shenglin;Jin, Junhong;Li, Guang
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.125-130
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    • 2008
  • A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

Durable Flame-Retardant Finish of Cotton Fabrics Using a Water-soluble Cyclophosphazene Derivative (수용해성 사이클로포스파젠 유도체를 이용한 면섬유의 내구성 방염가공)

  • Kim, Jeong-Hwan;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.33 no.2
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    • pp.64-71
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    • 2021
  • Large amount of formaldehyde could be released inevitably during the flame-retardant (FR) treatments or from the finished fabrics using Provatex reagent and Proban polymers which have been used as durable FRs for cotton. A water-soluble cyclophosphazene derivative was synthesized as an ecofriendly phosphorus-based FR for cotton fibers. Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) was synthesized through the substiutution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] methacrylamide at a mole ratio of 1 : 4, which can be cured dually by both alkaline treatment and UV irradiation. More crosslinked networks were produced through the addition of Triacryloyl hexahydrotriazine and Acrylamide as a UV-curable crosslinker and a comonomer respectively. Both flame retardancy and washing durability of the FR cotton were improved synergistically. The durability improvement may be caused by the covalent bond formation of the FR with cellulose and the high degree of polymerization of DCTDCP, which can be verified by the pyrolysis and combustion behaviors analyzed by LOI, TGA, and microcalorimeter.

Flame-retarding effects depending on the number of phosphonate groups attached to phosphorus flame-retarding compounds and coating binder resins (인계 난연화합물 및 코팅 바인더 수지에 부착된 phosphonate group에 따른 난연효과)

  • Park, Hyo-Nam;Kim, Hae-Rim;Choi, Seong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1678-1686
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    • 2021
  • In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

A Effects of applying the noise reduction method between existing buildings (기존 건축물 층간소음 저감공법 적용 효과 분석)

  • Song, Tae-Hyeob;Jeon, Chan-Soo;Kim, Ji-Hoon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.249-250
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    • 2018
  • To control the floor noise generated in the apartment building, a method of reinforcing the floor at the floor is applied. However, since existing buildings are difficult to reinforce upper generations, the ceilings of lower generations should be reinforced. The purpose of this study is to analyze the reduction effect by measuring the impact noise after reinforcing the floor soundproofing material on the ceiling of the existing building. In order to ensure the economical efficiency and flame retardancy of the products used as building interior materials, the existing polyurethane foam was impregnated with mineral to prepare test specimens and attached to the concrete slab surface. As a result, it was shown that heavy impact sound can reduce 2dB~5dB and light impact sound can reduce 4~8dB.

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A Study on Flame Retardant Treatment on Bamboo Nonwoven Fabric and Manufacturing of Sandwich Structure Composites (대나무 섬유의 난연화 및 샌드위치 구조 복합재료 제조연구)

  • Lee, Dong-Woo;Prabhakar, M.N.;Song, Jung-Il
    • Composites Research
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    • v.33 no.6
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    • pp.408-414
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    • 2020
  • The present engineering sector focused on the sandwich composites and almost covered all engineering fields because of decent mechanical properties with a lightweight structure. It mainly consists of high strength fiber skin and porous structure core like corrugated, honeycomb, balsa wood, and foams which is playing a pivotal role in weight reduction. Recently researchers attention grabbed by Natural fiber sandwich composites due to biodegradability, renewable, low-cost, and environmentally friendly. However special focus is highly needed towards the flammability behavior of natural fibers used as reinforcement for composites. Herein, for the first time, the flame retardant natural fiber sandwich composite was fabricated by using flame retardant treated bamboo fabric and vinyl ester via the VARTM process. The impact of flame retardant treated bamboo fabric on mechanical and flame retardant properties were studied. The results concluded that the fabricated bamboo sandwich composites show structurally lightweight with significant mechanical strength and feasibility with respect to the flame.