Browse > Article
http://dx.doi.org/10.5764/TCF.2021.33.2.64

Durable Flame-Retardant Finish of Cotton Fabrics Using a Water-soluble Cyclophosphazene Derivative  

Kim, Jeong-Hwan (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Jang, Jinho (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Publication Information
Textile Coloration and Finishing / v.33, no.2, 2021 , pp. 64-71 More about this Journal
Abstract
Large amount of formaldehyde could be released inevitably during the flame-retardant (FR) treatments or from the finished fabrics using Provatex reagent and Proban polymers which have been used as durable FRs for cotton. A water-soluble cyclophosphazene derivative was synthesized as an ecofriendly phosphorus-based FR for cotton fibers. Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) was synthesized through the substiutution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] methacrylamide at a mole ratio of 1 : 4, which can be cured dually by both alkaline treatment and UV irradiation. More crosslinked networks were produced through the addition of Triacryloyl hexahydrotriazine and Acrylamide as a UV-curable crosslinker and a comonomer respectively. Both flame retardancy and washing durability of the FR cotton were improved synergistically. The durability improvement may be caused by the covalent bond formation of the FR with cellulose and the high degree of polymerization of DCTDCP, which can be verified by the pyrolysis and combustion behaviors analyzed by LOI, TGA, and microcalorimeter.
Keywords
formaldehyde-free; durable; flame retardant; cotton; crosslink;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 M. Kim, K. H. Sohn, and H. D. Ghim, Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (2) -Reaction of Resorcinol Bis(diphenyl phosphate)-, Textile Coloration and Finishing, 24, 39(2012).   DOI
2 G. Yanga, W. H. Wu, Y. H. Wang, Y. H. Jiao, L. Y. Lu, H. Q. Qua, and X. Y. Qin, Synthesis of a Novel Phosphazene-based Flame Retardant with Active Amine Groups and Its Application in Reducing the Fire Hazard of Epoxy Resin, J. Hazardous Mater., 366, 78(2019).   DOI
3 J. Alongi and G. Malucelli, Cotton Flame Retardancy: State of the Art and Future Perspectives, RSC Adv., 5, 24239 (2015).   DOI
4 K. L. Mittal and T. Bahners, "Textile Finishing: Recent Developments and Future Trends", Scrivener Publishing, USA, pp.69-127, 2017.
5 H. J. Choi, D. J. Gong, C. Youn, and S. Y. Yeo, Preparation of Flammability Artificial Hair based on Super Engineering Plastic, Textile Coloration and Finishing, 32, 103(2020).   DOI
6 A. Morgan, "Non-Halogenated Flame Retardant Handbook", Scrivener Publishing, USA, pp.50-55, 2014.
7 D. H. Lee and J. Jang, Synergistic Flame-Retardant Finishing of Cotton Using Dichlorotriazinyl Phosphonate and Triethanolamine, Fibers and Polymers, 21, 343(2020).   DOI
8 Z. Zhang, Z. Han, Y. T. Pan, D. Li, D. Y. Wang, and R. Yang, Dry Synthesis of Mesoporous Nanosheet Assembly Constructed by Cyclomatrix Polyphosphazene Frameworks and Its Application in Flame Retardant Polypropylene, Chem. Eng. J., 395, 125076(2020).   DOI
9 K. A. Salmeia, S. Gaan, and G. Malucelli, Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry, Polymers, 8, 319(2016).   DOI
10 S. Lu and I. Hamerton, Recent Developments in the Chemistry of Halogen-free Flame Retardant Polymers, Prog. Polym. Sci., 27, 1661(2002).   DOI
11 S. H. Lee, Fabrication and Characteristics of Flame Retardant Fabric Developed by using Bicomponent Filament, Textile Coloration and Finishing, 25, 110(2013).   DOI
12 M. Kim and H. D. Ghim, Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) -Reaction of Bisphenol A bis(diphenyl phosphate)-, Textile Coloration and Finishing, 24, 33(2012).   DOI
13 S. J. Kim and J. Jang, Synergistic UV-Curable Flame-retar dant Finish of Cotton Using Comonomers of Vinylphosphonic Acid and Acrylamide, Fibers and Polymers, 18, 2328(2017).   DOI
14 J. H. Kim and J. Jang, Formaldehyde-Free Durable Flame- Retardant Finish of Cotton Using Hexachlorocyclophos phazene and Triethanolamine, Textile Coloration and Finishing, 32(3), 150(2020).   DOI
15 X. Zhang, Y. Zhong, and Z. Mao, The Flame Retardancy and Thermal Stability Properties of Poly(ethyleneterephthalate) /Hexakis(4-nitrophenoxy) Cyclotriphosphazene Systems, Polym. Degrad. Stabil., 97, 1504(2012).   DOI
16 T. Li, S. Li, T. Ma, Y. Zhong, L. Zhang, H. Xu, B. Wang, X. Feng, X. Sui, Z. Chen, and Z. Mao, Novel Organic-Inorganic Hybrid Polyphosphazene Modified Manganese Hypophosphite Shuttles towards the Fire Retardance and Anti-dripping of PET, Eur. Polym. J., 120, 109270(2019).   DOI
17 Y. J. Shin, M. J. Shin, and J. S. Shin, Flame Retardant Properties of Cyclotriphosphazene Derivatives for ABS, Polym. and Polym. Composites, 26, 309(2018).   DOI
18 M. Lv, C. Yao, D. Yang, and H. Zeng, Synthesis of a Melamine-Cyclotriphosphazene Derivative and its Application as Flame Retardant on Cotton Gauze, J. Appl. Polym. Sci., 133, 43555(2016).
19 L. Zhao, C. Zhao, M. Wu, Y. Li, H. Li, D. Xianga, and C. Guoa, Curing Kinetics of Phenolphthalein based Polyphosphazene towards Thermal Stability and Flame Retardancy of Polybenzoxazine, RSC Adv, 9, 31583(2020).   DOI
20 O. Dagdag, A. E. Harfi, A. Essamri, M. E. Gouri, S. Chraibi, M. Assouag, B. Benzidia, O. Hamed, H. Lgaz, and S. Jodeh, Phosphorous-based Epoxy Resin Composition as an Effective Anticorrosive Coating for Steel, Int. J. Ind. Chem, 9, 231(2018).   DOI
21 M. Dutkiewicz, M. Przybylak, R. Januszewski, and H. Maciejewski, Synthesis and Flame Retardant Efficacy of Hexakis(3-(triethoxysilyl)propyloxy)cyclotriphosphazene/Silica Coatings for Cotton Fabrics, Polym. Degrad. Stabil., 148, 10(2018).   DOI
22 T. M. Gall, D. Plohl, L. Derksen, D. Lauer, P. Neldner, W. Ali, S. Fuchs, J. S. Gutmann, and K. Opwis, A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles, Molecules, 24, 3100(2019).   DOI