• Title/Summary/Keyword: Filler effect

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Development of Hybrid Calcium Carbonate for High Loading Paper (II) - Comparison with GCC - (고충전지 제조를 위한 하이브리드 탄산칼슘 충전제의 개발 (II) - 중질탄산칼슘과 비교 -)

  • Jung, Jae Kwon;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.76-80
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    • 2015
  • In filler loaded paper, the size of the filler affects its strength, optical and surface properties. As the size of the filler increases, tensile strength and bulk usually increases, opacity decreases, and smoothness becomes worse. Pre-flocculation of GCC (grounded calcium carbonate) makes large diameter flocs at aqueous medium that consists of multiple GCC particles, but they collapse to 2-dimensional shape in dried paper and makes low bulk paper. The hybrid calcium carbonate (HCC) that was made by in-situ $CaCO_3$ formation between GCC in aqueous medium made high bulk paper without harming tensile strength, bulk, opacity, and smoothness. The GCC that has equivalent size as HCC failed to make high opacity and smoothness as much as HCC.

Study on fatigue life and mechanical properties of BRBs with viscoelastic filler

  • Xu, Zhao-Dong;Dai, Jun;Jiang, Qian-Wei
    • Steel and Composite Structures
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    • v.26 no.2
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    • pp.139-150
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    • 2018
  • In this paper, two kinds of buckling restrained braces (BRBs) are designed to improve the mechanical properties and fatigue life, the reserved gap and viscoelastic filler with high energy dissipation capacity are employed as the sliding element, respectively. The fatigue life of BRBs considering the effect of sliding element is predicted based on Manson-Coffin model. The property tests under different displacement amplitudes are carried out to evaluate the mechanical properties and fatigue life of BRBs. At last, the finite element analysis is performed to study the effects of the gap and viscoelastic filler on mechanical properties BRBs. Experimental and simulation results indicate that BRB employed with viscoelastic filler has a higher fatigue life and more stable mechanical property compared to BRB employed with gap, and the smaller reserved gap can more effectively improve the energy dissipation capacity of BRB.

Preparation, Characterizations and Conductivity of Composite Polymer Electrolytes Based on PEO-LiClO4 and Nano ZnO Filler

  • ElBellihi, Abdelhameed Ahmed;Bayoumy, Wafaa Abdallah;Masoud, Emad Mohamed;Mousa, Mahmoud Ahmed
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2949-2954
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    • 2012
  • Nano ZnO with an average size of 8 nm was prepared by thermal decomposition of zinc oxalate at $450^{\circ}C$. A series of based composite polymer electrolyte PEO-$LiClO_4$ and nano ZnO as a filler have been synthesized using solution cast technique, with varying the filler ratio systematically. XRD, DSC and FTIR studies have been conducted to investigate the structure and interaction of different groups in the composite polymer electrolyte. Effect of nano ZnO ceramic filler concentration on the structure of composites and their electrical properties (DC-conductivity, AC-conductivity, dielectric constant, dielectric loss and impedance) at different frequencies and temperatures was studied. Melting temperature ($T_m$) of PEO decreased with the addition of both $LiClO_4$ salt and nano ZnO filler due to increasing the amorphous state of polymer. All composite samples showed an ionic conductivity. The maximum room temperature ionic conductivity is found for $(ZnO)_{0.5}(PEO)_{12}(LiClO_4)$ composite sample. All the results are correlated and discussed.

Preflocculation of GCC with Cationic PAM and Cationic Starch and the Influence of Their Dosage and Shear Rate on Prefloc Size (양이온성 PAM과 양성전분에 의한 GCC의 선응집과 이들의 투입량과 전단속도가 선응집체의 크기에 미치는 영향)

  • Lee, Kyong-Ho;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.1-9
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    • 2006
  • Increasing the filler content of sheet provides an opportunity for saving production cost through fiber replacement with relatively low-priced filler. But increasing the filler content tends to decrease the strength of paper and filler retention. To overcome these problems, preflocculation technology of fillers has been suggested. To evaluate the effect cationic polymers on the size and size distribution of preflocculated GCC and their shear stability, cationic PAM and cationic starch were used. Results showed that cationic PAM formed large prefloc at low dosage. It was required to add 15 times as high as cationic starch to cationic PAM to obtain the same size prefloc. But preflocs formed with cationic starch was superior in shear stability to those formed with cationic PAM. With the increase of shear rate the size of preflocs decreased. Greater amount of small preflocs or un-flocculated fillers was observed when the dosage of polymers was low and this ended up low ash retention in handsheets.

The Synthesis and Characterization of Thin Film for Anti-Glare Using Silica Particles (실리카 입자를 이용한 눈부심 방지용 박막의 제조 및 특성)

  • Ahn, Jae-Beom;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.685-689
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    • 2008
  • The effect of filler type and dispersion time on thin film characterization is studied. Hollow silica powders which have the advantage of transmittance are selected. In this paper, the characterization of haze, transmittance, and gloss are analyzed in terms of filler concentration and coating thickness, respectively. As a result, the value of haze and gloss increased with increasing of filler concentration and coating thickness, respectively. In addition, the variation of transmittance by filler concentration and coating thickness is not occurred. In conclusion, it is assumed that hollow silica powders as a filler have an advantage of concentration increment and transmittance.

A Study on Vulcanization Characteristics and Physical Properties for the Filler Compounded NR Vulcanizates.(II) (각종(各種) 충전제(充塡劑)를 배합(配合)한 천연(天然)고무의 가황체(加黃體)의 특성(特性)에 관(關)한 연구(硏究)(II)(가황특성(加黃特性) 및 물리적성질(物理的性質)))

  • Choi, Jae-Woon;Hong, Cheong-Seok;Herh, Dong-Sub
    • Elastomers and Composites
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    • v.20 no.1
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    • pp.13-24
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    • 1985
  • It is generally agreed that strong linkages exist between rubber chains and reinforcing filler particles. The purpose of this study is to examine the effect of rubber-filler attachments on the various mechanical properties of the rubber. In particular, the modulus and strength will be altered by these attachments. For this study, the curing properties are examined by means of ODR (Oscillating Disk Rheometer), the physical properties by means of Instrong. The results of this study can be summarized as follows. In the ODR test, the carbon black filled stock has shorter scorch time than gum stock and, the silica and clay filled stock has longer scorch time than gum stock. In the modulus, ten sile and swelling properties, the vulcanizates filled with carbon black had higher those values than inorganic filler loaded NR vulcanizates, but the rebound rate showed that the silica filled NR vulcanizates was lower than other inorganic filler contained NR vulcanizates and the ISAF filled NR vulcanizates was lower than other carbon block contained NR vulcanizates.

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Effect of Tin Addition on the Melting Temperatures and Mechanical Properties of Al-Si-Cu Brazing Filler Metals (저온 브레이징용 Al-Si-Cu 합금의 Sn 첨가에 따른 융점 및 기계적 특성 변화 연구)

  • Kim, Min Sang;Park, Chun Woong;Byun, Jong Min;Kim, Young Do
    • Korean Journal of Materials Research
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    • v.26 no.7
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    • pp.376-381
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    • 2016
  • For the development of a low-melting point filler metal for brazing aluminum alloy, we analyzed change of melting point and wettability with addition of Sn into Al-20Cu-10Si filler metal. DSC results showed that the addition of 5 wt% Sn into the Al-20Cu-10Si filler metal caused its liquidus temperature to decrease by about 30 oC. In the wettability test, spread area of melted Al-Cu-Si-Sn alloy is increased through the addition of Sn from 1 to 5 wt%. For the measuring of the mechanical properties of the joint region, Al 3003 plate is brazed by Al-20Cu-10Si-5Sn filler metal and the mechanical property is measured by tensile test. The results showed that the tensile strength of the joint region is higher than the tensile strength of Al 3003. Thus, failure occurred in the Al 3003 plate.

Effect of New Organic Filler Made From Oil Palm Biomass on Paperboard Properties (오일팜 부산물을 이용한 유기충전제 제조 가능성 평가)

  • Lee, Ji Young;Kim, Chul Hwan;Sung, Yong Joo;Park, Jong-Hea;Kim, Eun Hea
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.61-67
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    • 2015
  • As the production of palm oil has been increased, the generation of oil palm biomass is also increased and the utilization of the oil palm biomass become more significant topic. One third of the oil palm biomass is empty fruit bunch (EFB) and the other two thirds are oil palm trunks and fronds. However, the effective use of oil palm biomass has not been developed and most of it is discarded near oil palm plants. In this study, we investigated the applicability of EFB to the paperboard mills, as an organic filler. The new organic filler was manufactured in a laboratory by grinding and fractionating dried EFB powder, and its properties were analyzed. The particles of EFB organic filler were larger and more spherical than those of the commercial wood powder. The use of EFB organic filler resulted in a higher bulk of the handsheets with similar trends of physical strength, compared to those made with wood powder. It was concluded that EFB could be used as a raw material to manufacture organic filler for paperboard production.

Preparation and Property of POSS-Based Organic-Inorganic Hybrid Filler and Polyamide Thermoplastic Elastomer (PA-TPE)/POSS Nanocomposite (POSS 기반 유-무기 하이브리드 충전제와 폴리아미드계 TPE로 이루어진 나노복합체의 제조 및 특성)

  • Han, Jae Hee;Kim, Hyung Joong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.34-40
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    • 2013
  • Commercially available polyamide thermoplastic elastomer (PA-TPE) was blended with hybrid filler which was prepared by means of the reaction between polyhedral oligomeric silsesquioxane (POSS) containing amine group and toluene diisocyanate (TDI)-caprolactam (CL) to explore the effect of blending the hybrid filler with the TPE. The chemical structure of the filler was identified by using FTIR and $^1H$ NMR. The composites, PA-TPE/POSS-(TDI+CL), which were the blends of TDI+CL modified POSS filler and PA-TPE up to 7 wt%, showed better elastic recovery delivered from lower tension setting compared to the PA-TPE and the PA-TPE/octaphenyl POSS blend. In addition the tensile strength and the initial modulus increased with increasing the hybrid filled content. Consequently it was assumed that the POSS-(TDI+CL) filler was a suitable material for enhancing strength and modulus without loss of elastic properties for the original PA-TPE.

Influence of the Filler's Particle Size on the Mechanical Properties of Ultra High Performance Concrete(UHPC) (충전재의 입경 크기가 초고성능 콘크리트의 역학적 특성에 미치는 영향)

  • Kang, Su Tae;Park, Jung Jun;Ryu, Gum Sung;Kim, Sung Wook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4A
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    • pp.573-580
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    • 2008
  • In this paper, we estimated the effect of the siliceous filler's particle size on the performance of Ultra High Performance Concrete (UHPC). Filler's particle diameters considered in this paper were about 2, 4, 8, 14, $26{\mu}m$ and the performance was evaluated by testing fluidity in fresh concrete, compressive strength, ultimate strain, elastic modulus and flexural strength in hardened concrete. We also carried out XRD and MIP tests to analyze the relationship between the mechanical properties and microstructure. Test results showed that the smaller filler's particle size improves flowability and strength properties. MIP results revealed that the smaller size of filler decreased the porosity and thus increased the strength of UHPC. From XRD analysis, we could find out there were little influence of filler's particle size on chemical reactivity in UHPC.