• Journal of Information Display
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• 제4권2호
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• pp.35-42
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• 2003

The field emission and luminescent properties of carbon nanotubes (CNTs) that were straightened by argon ion irradiation were investigated. Argon ion irradiation permanently straightened both as-grown and screen-printed CNTs (SP-CNTs) in the presence of a strong electric field. The straightening process enhanced the emission properties of as-grown CNT films by showing a decrease in turn-on field, an increase in total emission current, and a stable emission. Recurring problems associated with SP-CNTs, such as bent or/and buried CNTs and the degradation in binder-residue-induced emission, were improved by the permanent straightening of CNTs and protruding CNTs from binders by the irradiation treatment, in addition to its surface cleaning effect. Furthermore, we confirmed that the number of emission sites increases by observing the luminescent properties of CNT films after the straightening. These findings here suggest that ion irradiation treatment is an effective method for achieving uniform field emission and to reduce the electrical aging time.

• Journal of Korean Vacuum Science & Technology
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• 제3권1호
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• pp.10-15
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• 1999

Using micro-wells on the Mo substrate, we could obtain various tubular-volcano-types of free-standing diamond field emitters by depositing a diamond film detaching the film and turning the film upside down. The field emission characteristics of these structures were investigated as a function of size, shape and the number density of the tubular-volcano-type diamond field emitters. The field emission characteristics, especially the current density, were greatly enhanced with increasing the number density of the tubular-volcano-type diamond field emitters on the Mo substrate. Based on these results, we suggest that the reduction of the well size can give better field emission characteristics by the increase in the number density of the tubular-volcano-type diamond field emitters. Finally, we suggest the feasibility of fabricating a large-area field emission display using our patterned tubular-volcano-type free-standing diamond field emitters.

• Journal of Information Display
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• 제2권4호
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• pp.23-28
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• 2001

Field emission characteristics of carbon nanotubes(CNTs) on four kinds of metallic substrates have been investigated under the irradiation of a laser. The field emission measurement reveals that after laser irradiation the current was increased and new humps at the field emission current was found. The current enhancement was thought to have occurred due to the fact that the electrical contact between CNTs and metals was improved due to the irradiation of the laser.

• 한국표면공학회지
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• 제37권6호
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• pp.313-318
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• 2004

Vertically-aligned and uniformly-distributed CuO nanowires were formed on copper-coated Si substrates by wet chemical process, immersing them in a hot alkaline solution. The effects of hydrogen plasma treatment on the field emission characteristics of CuO nanowires were investigated. It was found that hydrogen plasma treatment enhanced the field emission properties of CuO nanowires by showing a decrease in turn-on voltage, and an increase in emission current density, and stability of current-voltage curves. However, the excessive hydrogen plasma treatment made the I-V curves unstable. It was confirmed by XPS (X-ray Photoelectron Spectroscopy) analysis that hydrogen plasma treatment deoxidized CuO nanowires, thereby the work function of the nanowires decreased from 4.35 eV (CuO) to 4.1 eV (Cu). It is thought that the decrease in the work function enhanced the field emission characteristics. It is well-known that the lower the work function, the better the field emission characteristics. The results suggest that the hydrogen plasma treatment is very effective in achieving enhanced field emission properties of the CuO nanowires, and there may exist an optimal hydrogen plasma treatment condition.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.383-383
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• 2011

Generally, field emitters can be categorized into two types according to the emitter shape, one is a planar field emitter and the other is a point emitter. The planar field emitter is used for displays, flat lamps and signage boards. On the other hands, the point field emitter is expected to play a significant role in x-ray sources and electron beam sources. Such applications of the point field emitters, especially, need large emission current and high emission stability with a small electron beam size. A few reports announced point emitters made by carbon nanotubes (CNTs). However, they still have suffered from poor reproducibility and low emission current. Here, we demonstrated high performance CNT point emitters by attaching CNTs onto graphite rod. Graphite rod exhibited good electrical conductivity and chemical stability. In this method, the shape of the point emitter could be easily controlled by changing the length and diameter of the graphite rod. The CNT point emitter showed emission current over 1 mA at an applied electric field of 1.4 V/${\mu}m$. We consider that the stable emission performance is attributed to the stable contact between CNTs and graphite rod.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권4호
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• pp.275-280
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• 1999

The glass-to-glass electrostatic bonding process in vacuum environment was developed and the tubeless-packaged FED was fabricated based on the bonding process. The fabricated tubeless-packaged FED showed stable field emission characteristics and potential applicability to the FED tubeless packaging and vacuum in-line sealing.

• 대한전자공학회논문지SD
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• 제44권8호
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• pp.8-15
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• 2007

본 논문에서는 산화된 다공질 폴리실리콘을 이용하여 전계 방출 소자를 제작하여, 각각의 픽셀에 따른 전기적 특성과 형광체의 발광 특성을 조사하였다. 실제 대면적 디스플레이 소자에 적용하기 위해서 PM 방식을 이용해서 소자를 픽셀별로 동작하였고, 상부금속 전극의 어레이에 따른 두께와 폭의 공정조건을 확립하였다. 산화된 다공질 폴리실리콘의 미세 구조를 분석하고, 각각의 픽셀에 따른 전계방출 특성을 조사해 보았다. 상부금속 전극의 두께와 폭에 따른 전자방출 특성을 조사해 본 결과 Ti/pt(2nm/7nm)가 가장 적절한 두께라는 것을 확인 할 수 있었고, 2.5 mm 이상 폭에서 전자방출 효율이 증가하는 모습을 확인 할 수 있었다. 각 픽셀에 따른 소자의 전기적 특성은 픽셀마다 조금씩의 차이는 있지만 거의 동일한 누설 전류와 방출 전류가 나타남을 확인할 수 있었고, 동일한 크기의 효율도 관찰할 수 있었다. 누설 전류와 방출 전류는 시간이 증가함에 따라 감소하는 모습이 나타나긴 하였으나, 모든 픽셀이 거의 동일하게 감소하였다. 각각의 픽셀에 따른 휘도는 큰 차이가 없음을 확인할 수 있었고, 20 V에서 $700cd/m^2$ 이상의 높은 휘도를 나타내었으므로 실제 디스플레이 소자로도 응용이 가능할 것이다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2006년도 제31회 학술논문발표회 초록집
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• pp.34-34
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• 2006

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.207-212
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• 2003

The field emission and luminescent properties of carbon nanotubes (CNTs) that were straightened out by argon ion irradiation were investigated. Argon ion irradiation permanently straightened out both as-grown and screen-printed CNTs in the presence of a strong electric field. The straightening process enhanced the emission properties of CNT films by showing a decrease in turn-on field, an increase in total emission current, and a stable emission. Furthermore, the number of emission sites was confirmed to increase by observing the luminescent properties of CNT films after the straightening. The mechanism involved in the straightening of the CNTs is proposed and the enhancement in field emission is discussed in detail.

• 전기학회논문지
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• 제62권3호
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• pp.376-379
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• 2013

Multi-walled carbon nanotubes (MWCNTs) were synthesized using catalytic chemical vapor deposition (CVD) method. Oxygen plasma treatment was applied to modify surface state of the CNTs synthesized for improvement of field emission performance. Surface state of the plasma treated CNTs was studied by X-ray photoelectron spectroscopy (XPS). The surface states of the CNTs were changed as a function of plasma treatment time. The oxygen related carbon shift was moved toward higher binding energy with the plasma treatment time. This result implies that the oxygen plasma treatment changes the surface state effectively. While any shift in carbon 1s peak was not detected for the as grown CNTs, oxygen related carbon shift was detected for the plasma treated CNTs. Carbon shift implies that closed CNT tips were opened by the oxygen plasma and reacted with oxygen species. Since the field emission occurs at pentagons or dangling bonds of the CNT tips, the increase of carbon-oxygen bonds plays an important role in field emission behavior by increasing the number of electron emission sites resulting in improvement of the field emission performance.