• Title/Summary/Keyword: Fe-based

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Effects of Flux Treatment on the Glass Forming Ability and Magnetic Properties of Fe-based Ternary Amorphous Alloys

  • Zuo, Mingqing;Yi, Seonghoon
    • Journal of Korea Foundry Society
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    • v.40 no.4
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    • pp.113-117
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    • 2020
  • A series of Fe-P-B and Fe-Si-B amorphous alloys with high Fe contents exceeding 90 wt.% was successfully prepared by combining flux treatment and melt-spinning technique. The effects of Fe content and the flux treatment on the thermal and magnetic properties of amorphous alloys were studied. The glass-forming ability and the thermal stability of amorphous ribbons can be improved by a flux treatment, revealing the effective removal of heterogeneous nucleation sites in the ribbons through the flux treatment. It was found that Fe-Si-B ribbons exhibit higher saturation magnetization levels than Fe-P-B ribbons.

Magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) Alloys: A First-principles Study (B2 구조 FeX(X = Al, Si, Ni, Ga, Ge, Sn) 합금의 자기변형에 대한 제일원리계산)

  • Lee, Sunchul;Odkhuu, Dorj;Kwon, Oryong;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.23 no.4
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    • pp.117-121
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    • 2013
  • In this study we investigated magnetism and magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) using a first-principles method, in order to survey the possibility of developing a transition metal based magnetostriction material. The Full-potential Linearized Augmented Plane Wave method was employed for solving the Kohn-Sham equation within the generalized gradient approximation for exchange-correlation interaction between electrons. FeX alloys are stabilized in ferromagnetic states except for the FeSi and FeGe alloys. Magnetostrcition coefficients of FeX (X = Al, Ni, Ga, and Sn) were calculated to be -5, +6, -84, -522ppm, respectively. It is noteworthy that the magnetostriction coefficient (-522ppm) of FeSn is larger than that (+400ppm) of Gafenol.

Corrosion Behaviors of Structural Materialsin High Temperature S-CO2 Environments

  • Lee, Ho Jung;Kim, Hyunmyung;Jang, Changheui
    • Corrosion Science and Technology
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    • v.13 no.2
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    • pp.41-47
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    • 2014
  • The isothermal corrosion tests of several types of stainless steels, Ni-based alloys, and ferritic-martensitic steels (FMS) were carried out at the temperature of 550 and $650^{\circ}C$ in SFR S-$CO_2$ environment (200 bar) for 1000 h. The weight gain was greater in the order of FMSs, stainless steels, and Ni-based alloys. For the FMSs (Fe-based with low Cr content), a thick outer Fe oxide, a middle (Fe,Cr)-rich oxide, and an inner (Cr,Fe)-rich oxide were formed. They showed significant weight gains at both 550 and $650^{\circ}C$. In the case of austenitic stainless steels (Fe-based) such as SS 316H and 316LN (18 wt.% Cr), the corrosion resistance was dependent on test temperatures except SS 310S (25 wt.% Cr). After corrosion test at $650^{\circ}C$, a large increase in weight gain was observed with the formation of outer thick Fe oxide and inner (Cr,Fe)-rich oxide. However, at $550^{\circ}C$, a thin Cr-rich oxide was mainly developed along with partially distributed small and nodular shaped Fe oxides. Meanwhile, for the Ni-based alloys (16-28 wt.% Cr), a very thin Cr-rich oxide was developed at both test temperatures. The superior corrosion resistance of high Cr or Ni-based alloys in the high temperature S-$CO_2$ environment was attributed to the formation of thin Cr-rich oxide on the surface of the materials.

Feature Extraction Based on Speech Attractors in the Reconstructed Phase Space for Automatic Speech Recognition Systems

  • Shekofteh, Yasser;Almasganj, Farshad
    • ETRI Journal
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    • v.35 no.1
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    • pp.100-108
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    • 2013
  • In this paper, a feature extraction (FE) method is proposed that is comparable to the traditional FE methods used in automatic speech recognition systems. Unlike the conventional spectral-based FE methods, the proposed method evaluates the similarities between an embedded speech signal and a set of predefined speech attractor models in the reconstructed phase space (RPS) domain. In the first step, a set of Gaussian mixture models is trained to represent the speech attractors in the RPS. Next, for a new input speech frame, a posterior-probability-based feature vector is evaluated, which represents the similarity between the embedded frame and the learned speech attractors. We conduct experiments for a speech recognition task utilizing a toolkit based on hidden Markov models, over FARSDAT, a well-known Persian speech corpus. Through the proposed FE method, we gain 3.11% absolute phoneme error rate improvement in comparison to the baseline system, which exploits the mel-frequency cepstral coefficient FE method.

Limit Loads for Pipe Bends under Combined Pressure and in-Plane Bending Based on Finite Element Limit Analysis (압력과 모멘트의 복합하중을 받는 곡관에 대한 유한요소 한계하중 해석)

  • Oh Chang-Sik;Kim Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.5 s.248
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    • pp.505-511
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    • 2006
  • In the present paper, approximate plastic limit load solutions fur pipe bends under combined internal pressure and bending are obtained from detailed three-dimensional (3-D) FE limit analyses based on elastic-perfectly plastic materials with the small geometry change option. The present FE results show that existing limit load solutions for pipe bends are lower bounds but can be very different from the present FE results in some cases, particularly for bending. Accordingly closed-form approximations are proposed for pipe bends under combined pressure and in-plane bending based on the present FE results. The proposed limit load solutions would be a basis of defective pipe bends and be useful to estimate non-linear fracture mechanics parameters based on the reference stress approach.

Limit Loads for Pipe Bends under Combined Pressure and in-Plane Bending Based on Finite Element Limit Analysis (압력과 모멘트의 복합하중을 받는 곡관에 대한 유한요소 한계하중 해석)

  • Oh C.S.;Kim Y.J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.401-402
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    • 2006
  • In the present paper, approximate plastic limit load solutions for pipe bends under combined internal pressure and bending are obtained from detailed three-dimensional (3-D) FE limit analyses based on elastic-perfectly plastic materials with the small geometry change option. The present FE results show that existing limit load solutions for pipe bends are lower bounds but can be very different from the present FE results in some cases, particularly for bending. Accordingly closed-form approximations are proposed for pipe bends under combined pressure and in-plane bending based on the present FE results. The proposed limit load solutions would be a basis of defective pipe bends and be useful to estimate non-linear fracture mechanics parameters based on the reference stress approach.

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Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence (고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성)

  • 조용수;김윤배;박우식;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.38-41
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    • 1995
  • The effects of Nb and Cu additives as will as substitutional Co into $Nd_{4}Fe_{85.5}B_{10.5}$ melt-spun alloy were studied aiming for finding a $\alpha$-Fe based Nd-Fe-B composite alloys with high energy product. The addition of Nb and Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ decreased the average grain size and increased the coercivity up to 207kA/m(2.6kOe), Further-more, the substitution of Co for Fe in $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ alloy resulted in the decrease of the average grain size (<20nm) and improved the hard magnetic properties. The remanence, coercivity and energy product of optimally annealed $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ alloy were 1.345, 219kA/m(2.75kOe) and $95.5kJ/m^{3}$(12MGOe), respectively.

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Improved high-performance La0.7Sr0.3MxFe1-xO3 (M = Cu, Cr, Ni) perovskite catalysts for ortho-para hydrogen spin conversion

  • Choi, Jeong-Gil;Choi, Euiji;Kweon, Soon-Cheol;Oh, In-Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.1
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    • pp.44-50
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    • 2018
  • The improved high-performance Fe-based perovskite-type oxides ($La_{0.7}Sr_{0.3}M_xFe_{1-x}O_3$, M = Cu, Cr, Ni) were synthesized by a citrate method and characterized by SEM, EDS, XRD and NMR spectroscopy analyses. The characterization analyses revealed that the stoichiometric amounts of lattice oxygen were existed in all of perovskite samples except for a nickel-doped perovskite. Fe-based perovskites exhibited a surprising result for ortho-para $H_2$ spin conversion reaction, indicating two orders of magnitude higher conversions and conversion rates than commercial $Fe_2O_3$. It was considered that this conversion difference might be attributed to the presence of oxygen vacancies in Fe-based perovskites prepared in this study.

Study of Dechlorination Sorbent for Pyrolysis of PVC Containing Wastes (PVC 함유 폐기물의 열분해를 위한 탈염흡수제 연구)

  • Kim, Seong-Soo;Park, Sung-Youl
    • Clean Technology
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    • v.19 no.3
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    • pp.233-242
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    • 2013
  • The influences of Ca and Fe based oxides as dechlorination sorbents on the product distribution, boiling point distribution of liquid product, concentration of Cl of the products from the pyrolysis of PVC containing combustible wastes were investigated. With Fe based oxides as the sorbents, the yield of liquid product remarkably decreased whereas the decrease of the boiling point distribution of the liquid product was not noticeable. This phenomenon indicated that Fe based oxides worked as catalysts with weak catalytic activity. With Ca based oxides as the sorbents, the yield of liquid product did not decrease and the boiling point distribution of liquid product did not change significantly, but the dechlorination performance of these was much better than that with Fe based oxides.

Preparation and properties of water-based magnetic fluid with synthesized magnetite (합성마그네타이트를 이용한 수상자성유체의 제조 및 특성)

  • Kim, Mahn;Oh, Jae-Hyun;Seo, Ho-Jun;Cho, Moung-Ho;Kim, Mi-Sung
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.173-178
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    • 1994
  • The water-based magnetic fluids were prepared with the synthesized ultra-fine magnetite, oleic acid and SDBS (sodium dodecyl benzene sulfonate) as surfactants. The dispersion of water-based magnetic fluids was about 90 % when the added amounts of oleic acid and SDBS for magnetite(27 g) were more than $2.66{\times}10^{-3}$ mol and 10 g respectively. As the solid content increased from o. 05 g/cc to 0.4 g/cc, saturation magnetization of magnetic fluids at 5 kOe increased from 1.98 emu/g to 9.63 emu/g at $Fe^{2+}/Fe^{3+}=0.5$ and from 2.7 emu/g to 14.63 emu/g at $Fe^{2+}/Fe^{3+}=1.0$, and the its viscosity increased from 1.3 cp to 4.4 cp at $Fe^{2+}/Fe^{3+}=0.5$. pH region of oleic acid and SDBS stabilized water-based mag¬netic fluids was stable was in the range of pH 3.0 to pH 11.0. Stability of Water-based magnetic fluids can be obtained by observation of magnetic memory patterns on the VCR tape.

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