• Textile Coloration and Finishing
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• v.31 no.3
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• pp.135-146
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• 2019

A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Fashion & Textile Research Journal
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• v.9 no.1
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• pp.103-112
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• 2007

The purpose of this study was to investgate dyeing, moradnting properties and colorfastness activities of silk, polyamide, acetate treated black soybean extracts. The color of extract by buffer solution (pH=1) red, but the higher pH of extracted black soybean solution the paler of color strength. Black soybean extracts was approved anthocyanin of 3type(Delphinidin3-glucoside, Cyanidin 3-glucoside, Petunidin 3-glucoside) by chemiclal analysis. This anthocynin, in acid condition, is oxinium structure (red color, soluable) but, in alkali condition quinoid structure(dark brown, in soluable). The optimum dyeing condition of black soybean anthocynin was 10min at $30^{\circ}C$, pH -1. Colorfastness to washing and light showed generally low but crocking fastness was excellent.

• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.2
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• pp.406-413
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• 1997

The dyeability and colorfastness of browning extracts from mushroom were investigated. The results of this study are as follows, 1. Browning extracts from mushroom exhibited dyeability to wool, nylon and silk. The wool and silk had the greatest K/S value at pH 4 and nylon at pH 5 2. Furthermore, the increase in K/S value corresponded to temperature, time, and the number of dyeing. 3. In most cases, the value of K/S was increased by mordant treatment. The treatment of pre-mordant caused the increase in K/S value depending on the concentration of mordant, but not in the color. Co.mordant and post-mordant treaments, however, showed various colors of YR, Y, and GY types of Munsell color wheel. 4. In the most cases, color fastness of light, drycleaning, laundry, sweat, rubbing was excellent.

• Korean Journal of Human Ecology
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• v.9 no.3
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• pp.63-68
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• 2006

Walnut colorants were extracted from walnut hull and their dyeing properties on cotton were investigated. Effect of dyeing conditions on dye uptake and effect of mordanting on dye uptake, color change and colorfastness were explored. Walnut colorants showed low affinity to cotton compared with wool and its isotherm adsorption curve was Freundlich type. It was considered that hydrogen bonding and van der Waal's force were involved in the adsorption of walnut colorants onto cotton. The dyed cotton showed YR color and there was no significant color change as pH changed. The dyed cotton showed generally high colorfastness except fastness to washing and light. Mordanting did not improve dye uptake and colorfastness, and not affect color of the dyed cotton significantly.

• The Research Journal of the Costume Culture
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• v.22 no.6
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• pp.890-898
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• 2014

This study focuses on the effects of dyeing conditions and mordanting conditions, changes of colorfastness, antibacterial properties and UV protective of silk fabric dyed with Laminaria japonica extracts. A natural colorant was extracted from Laminaria japonica using distilled water as extractants. According to the results, maximum dye uptake (K/S) were obtained at 100% V/V colorant concentration, $80^{\circ}C$, 60 min and pH 2. Silk fabric was dyed with Laminaria japonica extract at $80^{\circ}C$ for 60 min with pre-treatment or post-treatment of various metal salts as mordants. The Laminaria japonica extracts produced yellow hue on silk fabric in pre-mordanting and manifested green yellow hue mordanted with $CuSO_4$ in post-mordanting method. Mordant $CuSO_4$ for silk fabric was found to give good light fastness (rating 4). UV protection property did not increase significantly upon mordanting.

• Korean Journal of Human Ecology
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• v.16 no.5
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• pp.979-986
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• 2007

The purpose of this study is to investigate the dyeability, and the hand of soybean/cotton blended fabric after dyeing with natural and synthetic dyes. Soybean/cotton blended fabrics dyed with extracted solution from turmeric, sappan wood, gardenia and synthetic dyes(weak-acid dyes, reactive dyes, direct dyes). The hand value of soybean/cotton blended fabrics dyed with 6 different dyes was measured using Kawabata Evaluation System. The results are as follows; 1. The K/S value of the soybean/cotton blended fabric dyed with sappan wood extracts was the highest. 2. The color fastness of the soybean/cotton blended fabric dyed with reactive dyes was excellent. The fastness to the light of the same fabric was much better than the other fabrics. 3. Linearity of load-extension and tensile energy of the soybean/cotton blended fabric dyed with sappan wood extracts showed very high. Shear stiffness of the soybean/cotton blended fabric dyed with weak-acid dyes was much higher than that of fabric of dyed with reactive dyes. Bending property of the fabrics dyed with natural colorants(sappan wood, gardenia) showed very high, but that the fabric dyed with reactive dyes was very poor. 4. In the primary hand value, stiffness and anti-drape stiffness of the fabric dyed with weak-acid dyes showed the highest. Fullness and softness of the fabric dyed with weak-acid dyes showed very low.

• Journal of the Korean Society of Clothing and Textiles
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• v.42 no.3
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• pp.516-529
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• 2018

This study investigated the dyeing properties and bio-functions of cotton fabrics dyed with naturally fermented Ecklonia cava extract in order to compare it with a comparison of unfermented extract. Hot water-extracted Ecklonia cava was fermented naturally under the various conditions of a fermenting period (2-8 days) and amount of molasses (0.1-1.8% v/v); in addition, it was also tested for characterization by FT-IR, antioxidant activity, total polyphenol content, and anti-microbial activity. For dyed cotton fabrics, color strength (K/S), physical color properties, dyeing fastness, sun protective property, and anti-microbial activity were evaluated considering dyeing conditions. As a result, the fermented dye under fermentation condition of 0.1% v/v with molasses during 4 days was revealed as having a similar chemical structure to the unfermented one and showed a total polyphenol content with 32.88mg/g and better antioxidant activity than the unfermented one. As for dyed fabrics, the color strength value by K/S was the highest under the condition of 0.1% v/v of molasses during 4 days among all fermenting conditions. The dyed fabrics had a reasonably good fastness (except for light). Anti-microbial activity against K. pneumoniae was better for the fermented extract-dyed fabric especially with lower dye concentrations.

• Fashion & Textile Research Journal
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• v.21 no.3
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• pp.356-362
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• 2019

This study investigated the substantivity of anionic dyes for cationic-modified new rayon (cocell) fabric treated with cationic agent (CA), 3-(Chloro-2-hydroxypropyl)-trimethylammonium chloride (CA). We also investigate the dyeability of cationic-modified new rayon fabric after dyeing with gallut. CA was converted in an aqueous solution of sodium hydroxide into epoxypropyl trimethylammonium chloride. Treating with this epoxy reagent modified the hydroxyl groups of the new rayon fabric into the trimethylammonium group through ether linkage. The introduction of new cationic sites into new rayon fabric by pretreating with cationic agent improved the substantivity of the Gallnut dye with the new rayon dyebath. The degree of the cationization of cationic-modified new rayon and cotton fabric was evaluated by nitrogen (N) content. This study extracted the colorant of gallnut with hot water at $90^{\circ}C$ and 120 min. Cationic-modified new rayon fabric dyed with extracted solution from gallnut according to concentration of gallnut, dyeing temperature, dyeing time and concentration of cationic agent. Dyeability (K/S) was obtained by CCM observation after dyeing with gallut solution. In addition, fastness to washing and light were also investigated. The degree of crystallinity of new rayon and cotton fabric were 42.15% and 54.94%, respectively. N (%) content of cationic-modified new rayon was higher than the cationic-modified cotton. Dyeability (K/S) increased significantly with the increasing concentration of CA and gallut.

• Textile Coloration and Finishing
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• v.33 no.1
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• pp.10-23
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• 2021

In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.04a
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• pp.123-125
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• 2008

The heating process for coloration of persimmon extracts was examined instead of the general light irradiation method. The raw and fermented persimmon extracts were investigated in terms of the coloration phenomena onto cotton fabrics at various conditions. For both extracts, the color strength of fabrics was increased with the increase of coloration temperature, time and concentration of the extracts. The color fastness to washing was excellent for both color change and staining showing a rating of 5.