• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.436-442
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• 2017

Fischer-Tropsch synthesis is the technology of converting a syngas (CO+$H_2$) derived from such as coal, natural gas and biomass into a hydrocarbon using a catalyst. The catalyst used in the Fischer-Tropsch synthesis consists of active metal, promoter and support. The types of these components and composition affect the reaction activity and product selectivity. In this study, we manufactured an iron catalyst using ${\gamma}-Al_2O_3/SiO_2$ mixed support (100/0 wt%, 75/25 wt%, 50/50 wt%, 25/75 wt%, 0/100 wt%) by an impregnation method to investigate how the composition of ${\gamma}-Al_2O_3/SiO_2$ mixed support effects on the reaction activity and product selectivity. The physical properties of catalyst were analyzed by $N_2$ physical adsorption and X-Ray diffraction method. The Fischer-Tropsch synthesis was conducted at $300^{\circ}C$, 20bar in a fixed bed reactor for 60h. According to the results of the $N_2$ physical adsorption analysis, the BET surface area decreases as the composition of ${\gamma}-Al_2O_3$ decreases, and the pore volume and pore average diameter increase as the composition of ${\gamma}-Al_2O_3$ decreases except for the composition of ${\gamma}-Al_2O_3/SiO_2$ of 50/50 wt%. By the results of the X-Ray diffraction analysis, the particle size of ${\alpha}-Fe_2O_3$ decreases as the composition of ${\gamma}-Al_2O_3$ decreases. As a result of the Fischer-Tropsch synthesis, the CO conversion decreases as the composition of ${\gamma}-Al_2O_3$ decreases, and the selectivity of C1-C4 decreases until the composition of ${\gamma}-Al_2O_3$ was 25 wt%. In contrast, the selectivity of C5+ increases until the composition of ${\gamma}-Al_2O_3$ is 25 wt%.

• Analytical Science and Technology
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• v.28 no.6
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• pp.409-416
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• 2015

ICP-AES has been used in many laboratories due to the advantages of wide calibration range and multi-element analysis, but it may give erroneous results and suffer from spectral interference due to the large number of emission lines associated with each element. In this study, certified reference materials (CRMs) and field samples were analyzed by ICP-AES and HG-AAS according to the official Korean testing method for soil pollution to investigate analytical problems. The applicability of HG-ICP-AES was also tested as an alternative method. HG-AAS showed good accuracies (90.8~106.3%) in all CRMs, while ICP-AES deviated from the desired range in CRMs with low arsenic and high Fe/Al. The accuracy in CRM030 was estimated as below 39% at the wavelength of 193.696 nm by ICP-AES. Significant partial overlaps and sloping background interferences were observed near to 193.696 nm with the presence of 50 mg/L Fe and Al. Most CRMs were quantified with few or no interferences of Fe and Al at 188.980 nm. ICP-AES properly assessed low and high level arsenic for field samples, at 188.980 nm and 193.696 nm, respectively. The importance of the choice of measurement wavelengths corresponding to relative arsenic level should be noted. Because interferences were affected by the sample matrix, operation conditions and instrument figures, the analysts were required to consider spectral interferences and compare the analytical performance of the recommended wavelengths. HG-ICP-AES was evaluated as a suitable alternative method for ICP-AES due to improvement of the detection limit, wide calibration ranges, and reduced spectral interferences by HG.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.4
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• pp.1295-1302
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• 2013

The structural deformed shape is important information to structural analysis. If the sufficient measuring points are secured at the structural monitoring system, reasonable and accurate structural deformation shapes can be obtained and structural analysis is possible using this deformation. However, the accurate estimation of the global structural shapes might be difficult if sufficient measuring points are not secure under cost limitations. In this study, SFSM-LS algorithm, the economic and effective estimation method for the structural deformation shapes with limited displacement measuring points is developed and suggested. In the suggested method, the global structural deformation shape is determined by the superposition of the pre-investigated structural deformed shapes obtained by preliminary FE analyses, with their optimum weight factors which lead minimization of the estimate errors. 2-span continuous bridge model is used to verify developed algorithm and parametric studies are performed. By the parametric studies, the characteristics of the estimation results obtained by the suggested method were investigated considering essential parameters such as pre-investigated structural shapes, locations and numbers of displacement measuring points. By quantitative comparison of estimation results with the conventional methods such as polynomial, Lagrange and spline interpolation, the applicability and accuracy of the suggested method was validated.

• Journal of the Society of Disaster Information
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• v.13 no.1
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• pp.81-88
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• 2017

In this paper, the behaviour of composite steel-CFRP members is studied experimentally and using FE-analysis. The use of advance composite materials in construction for repair and rehabilitation has become a frequent used method in the last decade. FRP composites have many advantages over the traditional technique of steel bonding for a number of reasons: 1. Composites add little or no additional weight to a building, eliminating the need for costly foundation strengthening. 2. FRP composites are very thin (1.2mm to 1.4mm). So there is no loss of floor space and negligible effect over the architectural aspect. 3. FRP composites do not corrode, this makes it long lasting. However, the method is yet to become a mainstream application due to a number of economical and design related issues. Brittle debonding failure, aging effect on bonding, broad based awareness and proper design guidelines are the main concern for future research works. This paper is focused on the ultimate load carrying capacity of the CFRP-strengthened beams and their effect on the deflection and failures modes by varying the amount of CFRP content.

• Structural Engineering and Mechanics
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• v.62 no.1
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• pp.21-31
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• 2017

Engineered Cementitious Composite (ECC) is a special class of the new generation of high performance fiber reinforced cementitious composites (HPFRCC) featuring high ductility with relatively low fiber content. In this research, the mechanical performance of ECC beams will be investigated with respect to the effect of slag and aggregate size and amount, by employing nonlinear finite element method. The validity of the models was verified with the experimental results of the ECC beams under monotonic loading. Based on the numerical analysis method, nonlinear parametric study was then conducted to evaluate the influence of the ECC aggregate content (AC), ECC compressive strength ($f_{ECC}$), maximum aggregate size ($D_{max}$) and slag amount (${\phi}$) parameters on the flexural stress, deflection, load and strain of ECC beams. The simulation results indicated that when increase the slag and aggregate size and content no definite trend in flexural strength is observed and the ductility of ECC is negatively influenced by the increase of slag and aggregate size and content. Also, the ECC beams revealed enhancement in terms of flexural stress, strain, and midspan deflection when compared with the reference beam (microsilica MSC), where, the average improvement percentage of the specimens were 61.55%, 725%, and 879%, respectively. These results are quite similar to that of the experimental results, which provides that the finite element model is in accordance with the desirable flexural behaviour of the ECC beams. Furthermore, the proposed models can be used to predict the flexural behaviour of ECC beams with great accuracy.

• Corrosion Science and Technology
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• v.13 no.5
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• pp.195-203
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• 2014

Modern industry has a wide variety of application areas such as ocean industry, construction and automobile industry. With the current circumstances, the need for anti-corrosion technology that can be used on materials to withstand in harsh environments, is increasing. In this study, we have sought to develop a metal coating technology with zinc and aluminum powders as a potential anti-corrosion material. To make a coating on metal products, a thermal diffusion coating method was used under the conditions of $350^{\circ}C$ for 30 minutes. Optical microscope, Field emission scanning electron microscope (FE-SEM&EDX) and X-ray diffraction analysis were used to analyze a coating layer. As a result, we have confirmed that the generated amount of rust on metal parts coated with thermal diffusion coating method decreased dramatically compared with non-coated metal parts. Furthermore, the anti-corrosion performance was evaluated according to the different ratio of zinc and aluminum. Finally, we confirmed the possibility of application and commercialization of our coating technique on metal parts used in harsh industrial based on the results of these performance.

• Composites Research
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• v.24 no.2
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• pp.22-29
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• 2011

To increase the performance of thick-walled cylinders recently their length is continually enlarged. For that reason it is important to reduce weight of the thick-walled cylinders. In this paper the FE models to predict and estimate effects on the composite tapes were created with MSC.Nastran/Patran v.2005. First of all a autofrettage method was applied to the 2D model of the AISI4340 cylinder reduced the thick. And then the comparison of the numerical results with analysis results showed and verified by using T300/5208, IM7/PETI5, IM7/8552 tapes. Those are predicted to the effects of the angle of the composite tapes and elastic modulus according to the composite properties.

• Smart Structures and Systems
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• v.22 no.3
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• pp.335-340
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• 2018

The behavior of concrete slabs in composite beam with C and L shaped angle shear connectors has been studied in this paper. These two types of angle shear connectors' instalment have been commonly utilized. In this study, the finite element (FE) analysis and soft computing method have been used both to present the shear connectors' push out tests and providing data results used later in soft computing method. The current study has been performed to present the aforementioned shear connectors' behavior based on the variable factors aiming the study of diverse factors' effects on C and L shaped angle in shear connectors. ANFIS (Adaptive Neuro Fuzzy Inference System), has been manipulated in providing the effective parameters in shear strength forecasting by providing input-data comprising: height, length, thickness of shear connectors together with concrete strength and the respective slip of shear connectors. ANFIS has been also used to identify the predominant parameters influencing the shear strength forecast in C and L formed angle shear connectors.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.11a
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• pp.169-172
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• 2005

A flywheel system is an electromechanical energy storage device that stores energy by rotating a rotor. The rotating part, supported by magnetic bearings, consists of the metallic shaft, composite rims of fiber-reinforced materials, and a hub that connects the rotor to the shaft. The delamination in the fiber wound composite rotor often lowered the performance of the flywheel energy storage system. In this work, an advanced hybrid composite rotor with a split hub was designed to both overcome the delamination problem in composite rim and prevent separation between composite rim and metallic shaft within all range of rotational speed. It was analyzed using a three-dimensional finite clement method. In order to demonstrate the predominant perfom1ance of the hybrid composite rotor with a split hub, a high spin test was performed up to 40,000 rpm. Four radial strains and another four circumferential strains were measured using a wireless telemetry system. These measured strains were in excellent agreement with the FE analysis. Most importantly, the radial strains were reduced using the hybrid composite rotor with a split hub, and all of them were compressive. As a conclusion, a compressive pressure on the inner surface of the proposed flywheel rotor was achieved, and it can lower the radial stresses within the composite rotor, enhancing the performance of the flywheel rotor.

• Journal of Korea Foundry Society
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• v.40 no.3
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• pp.85-96
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• 2020

The effect of an aluminum scrap addition ratio on the tensile and solidification cracking properties of the AC4A aluminum alloy in the as-cast state and heat-treated state were investigated in this study. Generally, the expected problem of using scrap in aluminum casting is an increase of hydrogen and Fe element inside the aluminum melt. Another issue is an oxide film which has a weak interface with the molten aluminum and acts as potent nucleation sites for internal porosity and crack initiation. Solidification cracking is one of the critical defects that must be resolved to produce high quality castings. A conventional evaluation method for solidification cracking is a relative and qualitative analysis method which does not provide quantitative data on the thermal stress in the solidification process. Therefore, a newly designed solidification cracking test apparatus was used in this study, and the device can provide quantitative data. As a result, after conducting experiments with different scrap addition ratios (0%, 20%, 35%, 50%), the tensile strengths and elongations in the as-cast state were 214, 187.7, 182.1 and 170.4MPa and 4.6%, 3.4%, 3.1% and 2.3%, respectively. In the case of the T6 heat-treated state, the tensile strengths and elongations were 314.9, 294.6, 293.1 and 271.1MPa and 5.4%, 4.6%, 3.8% and 3.1%, respectively. The strength of the solidification cracking was 3.1, 2.4, 2.2and 1.6MPa as the scrap addition ratio increases.