• 제목/요약/키워드: F-T synthesis

검색결과 101건 처리시간 0.023초

Bio-jet fuel 제조용 합성원유 수첨이성화 촉매 (Catalysts for Hydroisomerization of Synthesis-Oil for Bio-jet fuel Production)

  • 윤소영;이은옥;박영권;전종기;정순용;한정식;정병훈
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.795-796
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    • 2010
  • 바이오매스로부터 합성액체오일을 생산하기 위한 방법의 하나로써 Fischer-Tropsch 합성이 세계적으로 주목을 받고 있다. $C_7-C_{15}$ 파라핀의 수첨이성화 반응은 세탄넘버의 향상과 저점도, 유동점, 및 어는점 등의 저온유동특성의 개선을 위하여 디젤연료의 생산 공정에 적용된다. Fischer-Tropsch 합성으로부터 생산되는 Jet fuel 등의 상업적인 제품들은 낮은 끓는점과 유동점을 개선해야 한다. 본 연구는 합성 오일로부터 bio-jet fuel을 제조하기 위한 수첨이성화 반응용 촉매를 개발하는데 있다. 수첨이성화 반응용 백금/제올라이트 촉매의 특성을 분석하고 모델반응으로써 도데칸의 수첨이성화반응 성능을 회분식반응기에서 조사하였다.

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두 개의 플랫폼을 가지는 새로운 타입의 공간 4 자유도 병력기구의 조합 및해석 (Synthesis and Analysis of a New Class of Spatial4-DOF Parallel Mechanism with Two Platforms)

  • 윤정원;류제하
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1482-1487
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    • 2003
  • This paper presents a new family of 4-DoF parallel mechanism with two platforms. The new mechanism is composed of front and rear platforms, and three limbs. Two limbs with 6dof joint (P-P-S-P) are attached to the each platform and are perpendicular to baseplate, while the middle limb with 4-Dof joints (R-R-R-P or R-R-P-P) is attached to the revolute joint that connect front and rear platform. The two-DoF-driving mechanism at the middle limb with two base-fixed prismatic actuators can generate the heaving and roll motions or two translational motions. Therefore, Therefore, the new 4-Dof parallel mechanism (1T-3R) can generate pitch motions at each platforms, roll, and heaving motions, while another type of new 4-Dof parallel mechanism (2T-2R) can generate pitch motions at each platforms, x and z translational motions. For 1T-3R mechanism, kinematic analyses including inverse, forward kinematics, and Jacobian are performed.

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Translation Initiation Factor IF1-Dependent Stimulation of 30 S Preinitiation Complex Formation: Rapid Isolation and fMEt-tRNA Binging Activity of IF1

  • CHOIK, SANG-YUN;HYUN-JUNG KIM;JUNG-IK YANG;HYO-IL CHANG
    • Journal of Microbiology and Biotechnology
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    • 제11권6호
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    • pp.986-993
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    • 2001
  • Translation Initiation in prokaryotes involves the formation of a 30 S preinitiation complex, in which translation initiation factors play a role in the stimulation of fMet-tRNA (fMet) binding. However, the specific function and precise mechanism of initiation factor IF1 are still unclear. One a functionally active factor with a high purity. In the present study a large quantity of active IF was rapidly purified, obtained by the overexpression of the infA gene, and then used for a functional study. The induction of infA did not appreciably affect the growth rate of the protease-deficient strain E. coli AR68 harboring the IF1 overproducing plasmid. The level of IF1 obtained was approximately $1-2\%$ of the total cell protein, which enabled the yield of highly purified IF1 (>$98\%$ pure) to be increased to 0.15 mg of IF1/g of cells. The IF1 was isolated within one day by the centrifugatioin of the ribosomal washed fraction, by ammonium sulfate fractionation, chromatography on batch of phosphocellulose, and FPLC Mono S. The overexpressed IF1 was found to be comparable to the factor isolated from normal cells, as determined by migration in NEPHGE/SDS 2-D gels. For binding of fMet-tRNA(fMet) to the 30 S ribosomal subunitis, relatively high levels of binding were obtained when IF2 was present. The addition of IF1 up to 110 pmol proportionally stimulated the binding to a variable extent. This IF1-dependent stimulation of the 30 S preinitiation complex formation demonstrated that IF1 would appear to be exclusively essential for promoting the initiation phase of protein synthesis.

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Synthesis and Characterization of Fluorinated Poly(phenylmaleimide-co-pentafluorophenylmaleimide) for Optical Waveguides

  • Choi, Jongwan;Oh, Jin-Woo;Kim, Nakjoong
    • Bulletin of the Korean Chemical Society
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    • 제34권4호
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    • pp.1077-1080
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    • 2013
  • Fluorinated polymaleimides with high thermal stability and low optical absorption loss in the optical communication wavelength of $1.55{\mu}m$ were investigated for application in low-loss waveguide materials. The fluorinated polymaleimides were prepared from two monomers phenylmaleimide (H-PMI) and pentafluorophenylmaleimide (F-PMI). All synthesized copolymers had high thermal stability (decomposition temperature $(T_d)=380-430^{\circ}C$). The refractive index of the copolymers could be tuned from 1.4969 to 1.5950 in the TE mode and from 1.4993 to 1.5932 for the TM mode at 632.8 nm by copolymerizing different weight ratios of H-PMI and F-PMI. The refractive index of the copolymers decreased with increasing F-PMI content. In addition, when the amount of F-PMI was increased, optical loss and absorption loss at 632.8 nm and 1550 nm, respectively, decreased.

Synthesis and Implementation of a Multi-Port DC/DC Converter for Hybrid Electric Vehicles

  • Santhosh, T. K.;Natarajan, K.;Govindaraju, C.
    • Journal of Power Electronics
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    • 제15권5호
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    • pp.1178-1189
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    • 2015
  • A non-isolated Multiple Input Converter (MIC) with an input port, two storage ports and a load port is proposed. The synthesis of the proposed four port converter with its switch realization is presented. A steady state analysis of each operating mode with a small-signal model is derived, and a stability analysis is done. A mode selection controller is proposed to automatically choose a specific operating mode based on the voltage levels of the different source and storage units. In addition, a voltage control loop is used to regulate the output voltage. A 200W prototype is built with a TMS320F28027 DSP controller to test the feasibility of the operating modes. Simulation and experimental results show the ability of the proposed converter to handle multiple inputs either individually or simultaneously.

다중 스케일 그라디언트 조건부 적대적 생성 신경망을 활용한 문장 기반 영상 생성 기법 (Text-to-Face Generation Using Multi-Scale Gradients Conditional Generative Adversarial Networks)

  • ;;추현승
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2021년도 추계학술발표대회
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    • pp.764-767
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    • 2021
  • While Generative Adversarial Networks (GANs) have seen huge success in image synthesis tasks, synthesizing high-quality images from text descriptions is a challenging problem in computer vision. This paper proposes a method named Text-to-Face Generation Using Multi-Scale Gradients for Conditional Generative Adversarial Networks (T2F-MSGGANs) that combines GANs and a natural language processing model to create human faces has features found in the input text. The proposed method addresses two problems of GANs: model collapse and training instability by investigating how gradients at multiple scales can be used to generate high-resolution images. We show that T2F-MSGGANs converge stably and generate good-quality images.

Foeniculum vulgare essential oil nanoemulsion inhibits Fusarium oxysporum causing Panax notoginseng root-rot disease

  • Hongyan Nie;Hongxin Liao;Jinrui Wen;Cuiqiong Ling;Liyan Zhang;Furong Xu;Xian Dong
    • Journal of Ginseng Research
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    • 제48권2호
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    • pp.236-244
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    • 2024
  • Background: Fusarium oxysporum (F. oxysporum) is the primary pathogenic fungus that causes Panax notoginseng (P. notoginseng) root rot disease. To control the disease, safe and efficient antifungal pesticides must currently be developed. Methods: In this study, we prepared and characterized a nanoemulsion of Foeniculum vulgare essential oil (Ne-FvEO) using ultrasonic technology and evaluated its stability. Traditional Foeniculum vulgare essential oil (T-FvEO) was prepared simultaneously with 1/1000 Tween-80 and 20/1000 dimethyl sulfoxide (DMSO). The effects and inhibitory mechanism of Ne-FvEO and T-FvEO in F. oxysporum were investigated through combined transcriptome and metabolome analyses. Results: Results showed that the minimum inhibitory concentration (MIC) of Ne-FvEO decreased from 3.65 mg/mL to 0.35 mg/mL, and its bioavailability increased by 10-fold. The results of gas chromatography/mass spectrometry (GC/MS) showed that T-FvEO did not contain a high content of estragole compared to Foeniculum vulgare essential oil (FvEO) and Ne-FvEO. Combined metabolome and transcriptome analysis showed that both emulsions inhibited the growth and development of F. oxysporum through the synthesis of the cell wall and cell membrane, energy metabolism, and genetic information of F. oxysporum mycelium. Ne-FvEO also inhibited the expression of 2-oxoglutarate dehydrogenase and isocitrate dehydrogenase and reduced the content of 2-oxoglutarate, which inhibited the germination of spores. Conclusion: Our findings suggest that Ne-FvEO effectively inhibited the growth of F. oxysporum in P. notoginseng in vivo. The findings contribute to our comprehension of the antifungal mechanism of essential oils (EOs) and lay the groundwork for the creation of plant-derived antifungal medicines.

철 촉매를 이용한 Fischer-Tropsch 합성 반응과 수성 가스 전환 반응에 대한 반응 속도 연구 (Kinetic Study of the Fischer-Tropsch Synthesis and Water Gas Shift Reactions over a Precipitated Iron Catalyst)

  • 양정일;천동현;박지찬;정헌
    • Korean Chemical Engineering Research
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    • 제50권2호
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    • pp.358-364
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    • 2012
  • 철 촉매를 이용한 Fischer-Tropsch 합성 반응과 수성 가스 전환 반응에 대한 반응 메커니즘과 반응 속도식을 5 채널 고정층 반응기를 이용하여 조사하였다. 실험 조건은, 반응물 합성가스 $H_2$/CO 비 0.5~2, 반응물 공급 유량 60~80 ml/min, 반응 온도 $255{\sim}275^{\circ}C$로서 반응 압력은 1.5 MPa을 유지하였다. F-T 합성 반응의 반응 속도식($r_{FT}$)은 반응 속도 결정 단계로서 분자로 흡착된 CO와 기상의 수소 분자와의 반응을 바탕으로 하는 Eley-Rideal 반응 메카니즘을 통해 계산되었고, WGS 반응의 반응 속도식($r_{WGS}$)은 formate 중간체 생성 반응을 반응 속도 결정 단계로 가정하여 결정되었다. 실험 결과, F-T 합성 반응의 반응 속도식과 WGS 반응의 반응 속도식은 각각 탄화수소 생성과 $CO_2$ 생성에 대한 반응 속도 실험값을 잘 모사하였고, 또한 power law에 근거한 CO 전환 반응에 대한 반응 속도식도 실험값과 잘 일치하였다. 이처럼, 각각의 반응 메카니즘을 바탕으로 도출된 반응 속도식($r_{FT}$, $r_{WGS}$, $-r_{CO}$)은 실험값과 여러 가지 기존 문헌에서 보고된 반응 속도식 모델과 잘 일치하였다.

3-(1,8나프탈이미도)프로필메타아크릴레이트와 GMA공중합체의 합성과 물성 (Synthesis of 3-(1,8-Naphthalimido) Propyl Methacrylate-GMA Copolymers and Their Physical Properties)

  • 임덕점;오대희
    • 한국응용과학기술학회지
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    • 제30권4호
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    • pp.592-601
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    • 2013
  • 이 연구는 3-(1,8나프탈이미도)프로필메타아크릴레이트(NIPM)와 GMA공중합체의 합성과 물성에 관한 과제로서 나프탈이미드 발색단을 가진 공중합체의 조성, 모노머 반응성비, 공명효과(Q)와 극성효과 (e), 형광특성 등을 조사하였다. Azobisisobutyronitronitryl(AIBN) 개시제와 dimethylformamide(DMF) 용매를 $60^{\circ}C$에서 공중합하였다. Fineman-Ross(F-R)와 Kelen-$T\ddot{\bar{u}}d\ddot{\tilde{o}}s$(K-T)법으로 부터 단량체 반응성비를 구하였으며, $r_1$값이 $r_2$보다 크게 나타났다. NIPM이 공중합체내에서 GMA보다 더 많음을 알 수 있다. 380 nm에서 약한 분자형광띠와 460 nm에서 강한 중합체 엑시머 형광띠가 나타났다.

High Temperature Cooking of Fish Protein Extracts for Plastein Reaction

  • Lee, Keun-Tai;Park, Seong-Min;Lee, Sang-Ho;Ryu, Hong-Soo;Yoon, Ho-Dong
    • Preventive Nutrition and Food Science
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    • 제2권4호
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    • pp.321-327
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    • 1997
  • High Temperature-cooking conditions of cultured fishes(loach, crucian carp, bastard halibut, and jacopever) were optimized by response surface methodology(RSM), and plastein products were prepared using enzymatic hydrolysis. Four models were proposed with regard to effects of time(t), temperature(T), and water/fish meat (w/f) ratio on the amount of 0.3M TCA soluble fractions. The model coefficients were ranged from p<0.0001 for jacopever to p<0.0433 for bastared halibut. Cooking conditions for 60% hydrolysis were optimized at 1) 14$0^{\circ}C$ except for crucian carp(136$^{\circ}C$); 2) 10.08 hours(loach), 7.25 hours(crucian carp), 9.85 hours(ba-stard harlibut), and 9.37 hours(iacopever); 3) 1:1(w/f) ratio except for the crucian carp(1.1:1). When protein hydrolyzates were employed for the plastein synthesis, optimum plastein-reaction conditions were determined to be pH 9.0 with chymotrypsin for the loach and crucian carp hydrolyzates, pH 9.0 with papain for the bastard halibut hydrolyzate, and pH 11.0 with trypsin for the jacopever hydrolyzate. Plastein reaction could be performed in water at concentration up to 20%(w/f).

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