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http://dx.doi.org/10.12925/jkocs.2013.30.4.592

Synthesis of 3-(1,8-Naphthalimido) Propyl Methacrylate-GMA Copolymers and Their Physical Properties  

Lim, Deok-Jum (Dept. of Industrial Chemistry, Pukyoung National University)
Oh, Dae-Hee (Dept. of Industrial Chemistry, Pukyoung National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.30, no.4, 2013 , pp. 592-601 More about this Journal
Abstract
This work, which was about the synthesis of 3-(1,8-Naphthalimido) propyl methacrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect(Q), polar effect(e) and fluorescence effect of 1,8-naphthalicanhydride. Azobisisobutyronitronitryl(AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide(DMF) of solvent for the copolymerization of NIPM. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from F-R and K-T methods. NIPM was found to be more copolymerized than GMA. The fluorescence spectrums of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm.
Keywords
3-(1,8-Naphthalimido) propyl methacrylate; GMA; reactivity ratios; resonance effect(Q); polar effect(e); excimer fluorescence;
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Times Cited By KSCI : 1  (Citation Analysis)
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