• 제목/요약/키워드: Exhaustion yield

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Swelling agent에 따른 메타계 아라미드 섬유의 Cationic dye 염색특성 (Study of Dyeing Properties by Swelling Agent on meta-aramid Fiber with Cationic Dyes)

  • 김은미;박청원;최재홍
    • 한국염색가공학회지
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    • 제24권1호
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    • pp.1-7
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    • 2012
  • Dyeing and fastness characteristics of 100% meta-aramid fiber were investigated with cationic dyes and swelling agents under various dyeing conditions such as dyeing temperature and pH of dye bath. Dye exhaustion started at around $80^{\circ}C$ and settled down at $130^{\circ}C$. Among swelling agents used, N-methyl formanilide showed comparatively higher K/S values comparing to 1-phenoxypropan-2-ol. Under weak acidic conditions in the range pH 5 to 7, the exhaustion of cationic dyes could be enhanced leading to higher adsorption and stability of colorimetric property. Wash and rubbing fastness were generally good but low light fastness found can be attributable to the poor photo-stability of the cationic dyes.

Physiological and Nutritional Factors for Efficient Sporulation and Toxin Formation in Bacillus tthuringiensis

  • 이은희;반재구;김정일
    • 한국미생물생명공학회:학술대회논문집
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    • 한국미생물생명공학회 1986년도 추계학술대회
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    • pp.522.2-522
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    • 1986
  • In order to optimally induce sporulation and toxin formation in Bacillus thuringiensis, exhaustion of specific nutrients as well as resuspension experiments were tried. Sporulation and toxin formation was most abunduntly occurred when the growth was limited by carbon source. It was also occurred in a resuspension medium containing only distilled water. Various environmental and physiological factors affecting the efficiencies of spore and toxin formation were examined in chemically defined media. As a result of these studies, a batch fermentation resulted in higher spore and toxin yield than ever reported

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Development of Cationic Dyeable Polyamide Substrates by Pretreatment with Synthetic Tanning Agent: Statistical Optimization and Analysis

  • Son, Young-A;Ravikumar, K.;Bae, Jin-Seok
    • 한국염색가공학회지
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    • 제21권5호
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    • pp.41-50
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    • 2009
  • Design of experiments (DoE) concept was successfully applied to determine the optimum processing conditions that yield maximum % exhaustion for berberine interaction with synthetic tanning agent pretreated polyamide substrates. The potential of synthetic tanning agent to provide anionic sites on the polyamide for berberine interaction which is cationic in nature was tested to increase the % exhaustion of berberine in this article. Experiments were designed according to Central Composite Rotatable Design (CCRD). The three factors for synthetic tanning agent pretreatment and two factors for berberine interaction each at five different levels, including central and axial points were considered. Experiments were conducted in a laboratory scale infra-red treatment instrument according to CCRD. For each response, second order polynomial models were developed using multiple linear regression analysis incorporating linear, interactions and squared effects of all variables and then optimized. The significance of the mathematical model developed was ascertained using Excel regression (solver) analysis module. Analysis of variance (ANOVA) was performed to check the adequacy and accuracy of the fitted models. The response surfaces and contour maps showing the interaction of process variables were constructed. Applying Monte Carlo simulation, response surface and contour plots, optimum operating conditions were found and at this optimum point, % exhaustion of 81% and 74% respectively for synthetic tanning agent pretreatment and berberine interaction were observed and subsequently the results were experimentally investigated.

군쇄석다짐말뚝의 지지력 특성에 관한 연구 (A Study on Bearing Capacity Characteristics of Group Crushed-Stone Compaction Piles)

  • 황근배;이민희;신현철;최용규
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.705-712
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    • 2005
  • Among soft ground treatment methods with granular soil used in domestic, the sand compaction pile method has been utilized greatly, but, as a result of exhaustion of sand and increase of unit cost, a necessity of an alternative method is suggested. In this study, the static load tests for group crushed-stone compaction piles which were constructed at in-situ site were performed. Pile diameter was 700mm and area of loading plates were changed. The static load tests of single and group piles were performed for area replacement ratio of 20, 30 and 40%. Based on test results, bearing capacity of group crushed-stone compaction pile were estimated. The more both single pile and group pile increase, the more yield bearing capacity tended to increase. Also, the yield bearing capacity of a group pile is about 50% less than the yield bearing capacity of a single pile. If the ground reinforced with the crushed-stone compaction pile is replacement ratio of $20{\sim}40%$, RIYB of both single pile and group pile increases qualitative tendency of linear more than original ground

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바이오디젤의 생산 공정 비교 및 생성물 수율에 미치는 인자들 (Evaluation of Biodiesel Production Systems and Factors Affecting Product Yield)

  • 이종만;이재흥;조남준
    • 한국실천공학교육학회논문지
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    • 제3권1호
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    • pp.183-192
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    • 2011
  • 현재 화석연료사용의 급증으로 인하여 지구온난화와 자원고갈의 문제가 전 세계적으로 크게 대두되어지고 있다. 이를 해결하기 위한 일환으로 재생 가능한 에너지로서 바이오매스의 활용에 관심을 기울이고 있다. 바이오디젤은 식물성 유지 또는 동물성지방, 폐식용유로부터 전이에스테르화반응을 통해 생산되는 친환경적인 연료로 기존의 석유디젤을 대체할 수 있는 연료로 관심을 받고 있다. 본 논문에서는 현재 연구 되고 있는 다양한 바이오디젤의 생산방법들과 수율에 영향을 주는 인자들에 대해 살펴보았다.

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현장재하시험을 통한 쇄석다짐말뚝의 응력분담에 관한 연구 (A Study on the Stress Concentration of Crushed-stone Compaction Piles through Field Loading Test)

  • 이민희;최용규;임종철;황근배
    • 한국지반공학회논문집
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    • 제19권6호
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    • pp.107-114
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    • 2003
  • 국내에서는 조립토를 이용한 연약지반 처리공법 중 모래다짐말뚝공법이 많이 활용되고 있으나, 모래자원의 고갈과 단가상승으로 인해 적용이 제한되고 있어 대체공법이 필요한 실정이다. 본 연구에서는 육상부 현장에 시험시공된 쇄석다짐말뚝에 대한 정재하시험을 수행하였으며, 쇄석다짐말뚝과 연약지반의 응력분담비를 규명하고 성능을 평가하였다. 임의 압력에서 치환율이 증가할수록 침하량이 작아지는 경향을 보였다. 치환율 20%일 때의 항복압력은 치환율 30%, 40%일 때 보다 작았다. 치환율 30%와 40%일 때의 항복응력과 침하량은 비슷하였다. 응력분담비는 1.7∼-3.0의 범위에 있었으며, 치환율이 증가할수록 응력분담비가 증가하는 경향을 보이고 있었다.

저온융착사를 이용한 섬유의 염색성 및 열처리 특성 (Dyeing and Heat Setting Properties of Low Melting PET Fiber)

  • 황세정;최현석;김동권;정인식;김성군
    • 한국염색가공학회지
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    • 제21권3호
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    • pp.37-42
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    • 2009
  • The low melting PET yarn has sheath/core structure: sheath portion consists of low melting point PET and core portion is regular PET. Dyeing properties of fabric made from low melting PET yarn were investigated at different dyeing temperatures. It was found that the exhaustion yield on the low melting PET fabric was higher than on regular PET fabric. The total K/S value of the dyed low melting PET fabric increased as heat setting temperature increased above $150^{\circ}C$ because the sheath portion of the low melting yarn melted. Although fastness to light of the low melting PET fabric was similar to regular PET fabric, fastness to washing was inferior to regular PET fabric by 1 grade.

pH Control for Dyebath Reuse in Dyeing of Polyamide with Binary Mixtures of Acid Dyes

  • Koh, Joonseok;Park, Sang Hyuck;Shim, Goo Hwan;Cho, Dae Hwan;Kim, Jae Pil
    • Fibers and Polymers
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    • 제5권2호
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    • pp.110-116
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    • 2004
  • Hydrolyzable organic esters were compared with ammonium sulphate as an acid donor for the pH control in dye-bath-reuse system of acid dyes mixtures. The ability of pH control, levelness, dyeing properties and reproducibility in dye-bath-reuse system were investigated comparatively. Hydrolyzable organic esters showed higher exhaustion and color yield than ammonium sulphate. In addition, hydrolyzable organic ester exhibited very low conductivity less than 0.5 mS, while ammonium sulphate give high conductivity. However, we could not observe any difference in levelness of dyed samples between two kinds of acid donors in laboratory scale dyeing. Over 10 cycles of reuse, hydrolyzable organic esters showed higher reproducibility than ammonium sulphate. No deterioration of the color fastness and levelness occurs over 10 cycles of reuse.

Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성 (Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dyes)

  • 최종윤;최재홍
    • 한국염색가공학회지
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    • 제21권6호
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    • pp.46-55
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    • 2009
  • Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di($\beta$-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at $120^{\circ}C$ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

Coloration of Poly(lactic acid) with Disperse Dyes. 1. Comparison to Poly(ethylene terephthalate) of Dyeability, Shade and Fastness

  • Choi Jae-Hong;Seo Woon-Young
    • Fibers and Polymers
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    • 제7권3호
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    • pp.270-275
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    • 2006
  • The dyeability of poly(lactic acid) [PLA] with a range of commercial disperse dye was examined and compared to that of poly(ethylene terephthalate) [PET] in addition to the colour and fastness of the resultant dyeings. A screening exercise in which twenty dyes of differing energy types and chemical classes were applied to PLA revealed a substantial variation between the dyes in terms of dye uptake (12-88 % at 4 % o.w.f.). Nine dyes exhausted above 70 % and were selected for further study, which involved comparison of shade and fastness of PLA dyeings with those of the corresponding PET dyeings. Differences in shade depended on hue while wet fastness of each of the PLA dyeings was either the same or 0.5-1.0 point lower than its PET counterpart. In all but one case, dye photostability in PLA was found to be very similar to that in PET. Dye build-up profiles on PLA were also investigated and from these results mixtures of compatible dyes identified.