• 제목/요약/키워드: Entropy production

검색결과 38건 처리시간 0.029초

Nonlinear Entropy Production in a Reversible Oregonator Model

  • Basavaraja, C.;Pierson, R.;Park, Seung-Hyun;Jeon, Eun-Ji;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • 제29권5호
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    • pp.1051-1054
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    • 2008
  • The entropy production in a non-equilibrium state based on the reversible Oregonator model of the Belousov-Zhabotinskii (BZ) reaction system has been studied. The reaction affinity and the reaction rate for the individual steps have been calculated by varying the concentrations of key variables in the system. The result shows a linear relationship between the reaction affinity and the reaction rate in the given concentration range. However, the overall entropy calculated on the basic assumption that the entropy in a reaction system corresponds to the summation of a product of reaction affinity and reaction rate of individual steps shows a nonlinearity of the reaction system. The results well agrees with the fact that the entropy production is not linear or complicated function in a non-linear reaction system.

통합생산량분석법에 의한 한국 서해 어획대상 잠재생산량 추정 연구 (A study on the estimation of potential yield for Korean west coast fisheries using the holistic production method (HPM))

  • 김현아;서영일;차형기;강희중;장창익
    • 수산해양기술연구
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    • 제54권1호
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    • pp.38-53
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    • 2018
  • The purpose of this study is to estimate potential yield (PY) for Korean west coast fisheries using the holistic production method (HPM). HPM involves the use of surplus production models to apply input data of catch and standardized fishing efforts. HPM compared the estimated parameters of the surplus production from four different models: the Fox model, CYP model, ASPIC model, and maximum entropy model. The PY estimates ranged from 174,232 metric tons (mt) using the CYP model to 238,088 mt using the maximum entropy model. The highest coefficient of determination ($R^2$), the lowest root mean square error (RMSE), and the lowest Theil's U statistic (U) for Korean west coast fisheries were obtained from the maximum entropy model. The maximum entropy model showed relatively better fits of data, indicating that the maximum entropy model is statistically more stable and accurate than other models. The estimate from the maximum entropy model is regarded as a more reasonable estimate of PY. The quality of input data should be improved for the future study of PY to obtain more reliable estimates.

공기사이클 냉동시스템의 성능해석 (Performance Analysis of an Air-Cycle Refrigeration System)

  • 원성필
    • 설비공학논문집
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    • 제24권9호
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    • pp.671-678
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    • 2012
  • The objective of this study is to analyze theoretically the performance of an open air-cycle refrigeration system in which environmental concerns increase. The pressure ratio of the external compressor and efficiencies of the components that compose of the system are selected as important parameters. As the pressure ratio of the external compressor increases, the pressure ratio of the ACM compressor is determined high, the refrigerating temperature and capacity increase, the COP decreases, and the total entropy production rate increases. The effect of heat exchanger effectiveness and turbine efficiency on the performance are greater than that of the ACM compressor efficiency. Also the performance of the air-cycle refrigeration system with two heat exchangers has been enhanced like high COP and low total entropy production rate, compared to the system with one heat exchanger.

다화학종 GH 방정식의 정확성 향상을 위한 벽면 경계조건 연구 및 GH 방정식의 엔트로피 특성 고찰 (The Slip-Wall Boundary Conditions Effects and the Entropy Characteristics of the Multi-Species GH Solver)

  • 안재완;김종암
    • 한국항공우주학회지
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    • 제37권10호
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    • pp.947-954
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    • 2009
  • 본 연구에서는 다화학종 희박유동의 해석을 위해, GH(Generalized Hydrodynamic) 방정식을 기반으로 한 축대칭 유동 해석이 가능한 다화학종 GH 수치해석 기법을 전산유체역학 수치해석자로서 개발하였다. 최초로 구현된 다화학종 GH 수치기법은 축대칭 형상의 물체 주위의 극초음속 희박유동을 대상으로 하여, DSMC(Direct Simulation Monte Carlo) 및 N-S(Navier-Stokes) 방정식의 결과와의 비교를 통해 정확도를 검증하고자 하였다. GH 해석자의 정확도 향상을 위해 고체 벽면에서의 여러 가지 slip-wall 경계조건을 적용하고 각각의 결과를 비교하였다. 또한, 높은 Knudsen 수의 1차원 수직 충격파 구조 문제를 통해 GH 방정식의 엔트로피 특성 및 정확성을 고찰하였다.

A CONSIDERATION OF THERMODYNAMIC ASPECTS OF WEAR: ENERGY AND ENTROPY

  • Ling, F.F.;Bryant, M.D.;Doelling, K.L.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.219-220
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    • 2002
  • To establish a thermodynamic basis for degradation, a hypothesis was made on the potential correlation between entropy and degradation for wear of machinery components. This paper reports an experimental study of wear of model machinery component pairs, on an accelerated testing basis. Measured were wear, friction, temperatures, and entropy flow. Results show a strong correlation between the referenced wear and the production of entropy flow. The hypothesis linking wear to entropy led to formulations consistent with the Archard/Holm wear law.

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우리나라 멸치자원량추정을 위한 잉여생산모델과 최대엔트로피모델의 비교분석 (A Comparative Analysis of Surplus Production Models and a Maximum Entropy Model for Estimating the Anchovy's Stock in Korea)

  • 표희동
    • 수산해양교육연구
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    • 제18권1호
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    • pp.19-30
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    • 2006
  • For fishery stock assessment and optimum sustainable yield of anchovy in Korea, surplus production(SP) models and a maximum entropy(ME) model are employed in this paper. For determining appropriate models, five traditional SP models-Schaefer model, Schnute model, Walters and Hilborn model, Fox model, and Clarke, Yoshimoto and Pooley (CYP) model- are tested for effort and catch data of anchovy that occupies 7% in the total fisheries landings of Korea. Only CYP model of five SP models fits statistically significant at the 10% level. Estimated intrinsic growth rates are similar in both CYP and ME models, while environmental carrying capacity of the ME model is quite greater than that of the CYP model. In addition, the estimated maximum sustainable yield(MSY), 213,287 tons in the ME model is slightly higher than that of CYP model (198,364 tons). Biomass for MSY in the ME model, however, is calculated 651,000 tons which is considerably greater than that of the CYP model (322,881 tons). It is meaningful in that two models are compared for noting some implications about any significant difference of stock assessment and their potential strength and weakness.

습공기사이클 냉동시스템의 성능해석 (Performance Analysis of a Wet Air-Cycle Refrigeration System)

  • 원성필
    • 설비공학논문집
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    • 제26권11호
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    • pp.504-511
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    • 2014
  • The objective of this study is to theoretically analyze the performance of an open wet air-cycle refrigeration system, which nowadays is increasingly generating environmental concern. The temperature and relative humidity of the outside air are selected as the most important parameters. As the temperature and relative humidity of the outside air increase, the pressure ratio of the ACM compressor is determined to be nearly constant, the air temperature at the exit of the system increases, and the amount of condensed water, the cooling capacity, the COP, and the total entropy production rate increase overall. The effects of the effectiveness of the heat exchanger and the efficiency of the turbine on the performance are greater than that of the efficiency of the ACM compressor. Also, the performance of the wet air-cycle refrigeration system with two heat exchangers is enhanced, with a high COP and low total entropy production rate, compared to the system with a single heat exchanger.

Optimal Buffer Allocation in Multi-Product Repairable Production Lines Based on Multi-State Reliability and Structural Complexity

  • Duan, Jianguo;Xie, Nan;Li, Lianhui
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제14권4호
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    • pp.1579-1602
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    • 2020
  • In the design of production system, buffer capacity allocation is a major step. Through polymorphism analysis of production capacity and production capability, this paper investigates a buffer allocation optimization problem aiming at the multi-stage production line including unreliable machines, which is concerned with maximizing the system theoretical production rate and minimizing the system state entropy for a certain amount of buffers simultaneously. Stochastic process analysis is employed to establish Markov models for repairable modular machines. Considering the complex structure, an improved vector UGF (Universal Generating Function) technique and composition operators are introduced to construct the system model. Then the measures to assess the system's multi-state reliability and structural complexity are given. Based on system theoretical production rate and system state entropy, mathematical model for buffer capacity optimization is built and optimized by a specific genetic algorithm. The feasibility and effectiveness of the proposed method is verified by an application of an engine head production line.

월별 가격의 확률분포를 이용한 정보엔트로피 모델에 의한 농산물가격의 불확정성 (Uncertainty of Agricultural product Prices by Information Entropy Model using Probability Distribution for Monthly Prices)

  • 은상규;정남수;이정재;배연정
    • 한국농공학회논문집
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    • 제54권2호
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    • pp.7-14
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    • 2012
  • To analyze any given situation, it is necessary to have information on elements which affect the situation. Particularly, there is greater variability in both frequency and magnitude of agricultural product prices as they are affected by various unpredictable factors such as weather conditions etc. This is the reason why it is difficult for the farmers to maintain their stable income through agricultural production and marketing. In this research, attempts are made to quantify the entropy of various situations inherent in the price changes so that the stability of farmers' income can be increased. Through this research, we developed an entropy model which can quantify the uncertainties of price changes using the probability distribution of price changes. The model was tested for its significance by comparing its simulation outcomes with actual ranges and standard deviations of price variations of the past using monthly agricultural product prices data. We confirmed that the simulation results reflected the features of the ranges and standard deviations of actual price variations. Also, it is possible for us to predict standard deviations for changed prices which will occur after a certain time using the information entropy obtained from relevant agricultural product price data before the time.

Hyperbolic Reaction-Diffusion Equation for a Reversible Brusselator: Solution by a Spectral Method

  • 이일희;김광연;조웅인
    • Bulletin of the Korean Chemical Society
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    • 제20권1호
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    • pp.35-41
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    • 1999
  • Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.