• Title/Summary/Keyword: Entropy production

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Nonlinear Entropy Production in a Reversible Oregonator Model

  • Basavaraja, C.;Pierson, R.;Park, Seung-Hyun;Jeon, Eun-Ji;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.1051-1054
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    • 2008
  • The entropy production in a non-equilibrium state based on the reversible Oregonator model of the Belousov-Zhabotinskii (BZ) reaction system has been studied. The reaction affinity and the reaction rate for the individual steps have been calculated by varying the concentrations of key variables in the system. The result shows a linear relationship between the reaction affinity and the reaction rate in the given concentration range. However, the overall entropy calculated on the basic assumption that the entropy in a reaction system corresponds to the summation of a product of reaction affinity and reaction rate of individual steps shows a nonlinearity of the reaction system. The results well agrees with the fact that the entropy production is not linear or complicated function in a non-linear reaction system.

A study on the estimation of potential yield for Korean west coast fisheries using the holistic production method (HPM) (통합생산량분석법에 의한 한국 서해 어획대상 잠재생산량 추정 연구)

  • KIM, Hyun-A;SEO, Yong-Il;CHA, Hyung Kee;KANG, Hee-Joong;ZHANG, Chang-Ik
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.54 no.1
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    • pp.38-53
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    • 2018
  • The purpose of this study is to estimate potential yield (PY) for Korean west coast fisheries using the holistic production method (HPM). HPM involves the use of surplus production models to apply input data of catch and standardized fishing efforts. HPM compared the estimated parameters of the surplus production from four different models: the Fox model, CYP model, ASPIC model, and maximum entropy model. The PY estimates ranged from 174,232 metric tons (mt) using the CYP model to 238,088 mt using the maximum entropy model. The highest coefficient of determination ($R^2$), the lowest root mean square error (RMSE), and the lowest Theil's U statistic (U) for Korean west coast fisheries were obtained from the maximum entropy model. The maximum entropy model showed relatively better fits of data, indicating that the maximum entropy model is statistically more stable and accurate than other models. The estimate from the maximum entropy model is regarded as a more reasonable estimate of PY. The quality of input data should be improved for the future study of PY to obtain more reliable estimates.

Performance Analysis of an Air-Cycle Refrigeration System (공기사이클 냉동시스템의 성능해석)

  • Won, Sung-Pil
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.9
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    • pp.671-678
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    • 2012
  • The objective of this study is to analyze theoretically the performance of an open air-cycle refrigeration system in which environmental concerns increase. The pressure ratio of the external compressor and efficiencies of the components that compose of the system are selected as important parameters. As the pressure ratio of the external compressor increases, the pressure ratio of the ACM compressor is determined high, the refrigerating temperature and capacity increase, the COP decreases, and the total entropy production rate increases. The effect of heat exchanger effectiveness and turbine efficiency on the performance are greater than that of the ACM compressor efficiency. Also the performance of the air-cycle refrigeration system with two heat exchangers has been enhanced like high COP and low total entropy production rate, compared to the system with one heat exchanger.

The Slip-Wall Boundary Conditions Effects and the Entropy Characteristics of the Multi-Species GH Solver (다화학종 GH 방정식의 정확성 향상을 위한 벽면 경계조건 연구 및 GH 방정식의 엔트로피 특성 고찰)

  • Ahn, Jae-Wan;Kim, Chong-Am
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.10
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    • pp.947-954
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    • 2009
  • Starting from the Eu's GH(Generalized Hydrodynamic) theory, the multi-species GH numerical solver is developed in this research and its computatyional behaviors are examined for the hypersonic rarefied flow over an axisymmetric body. To improve the accuracy of the developed multi-species GH solver, various slip-wall boundary conditions are tested and the computed results are compared. Additionally, in order to validate the entropy characteristics of the GH equation, the entropy production and entropy generation rates of the GH equation are investigated in the 1-dimensional normal shock structure test at a high Knudsen number.

A CONSIDERATION OF THERMODYNAMIC ASPECTS OF WEAR: ENERGY AND ENTROPY

  • Ling, F.F.;Bryant, M.D.;Doelling, K.L.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.219-220
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    • 2002
  • To establish a thermodynamic basis for degradation, a hypothesis was made on the potential correlation between entropy and degradation for wear of machinery components. This paper reports an experimental study of wear of model machinery component pairs, on an accelerated testing basis. Measured were wear, friction, temperatures, and entropy flow. Results show a strong correlation between the referenced wear and the production of entropy flow. The hypothesis linking wear to entropy led to formulations consistent with the Archard/Holm wear law.

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A Comparative Analysis of Surplus Production Models and a Maximum Entropy Model for Estimating the Anchovy's Stock in Korea (우리나라 멸치자원량추정을 위한 잉여생산모델과 최대엔트로피모델의 비교분석)

  • Pyo, Hee-Dong
    • Journal of Fisheries and Marine Sciences Education
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    • v.18 no.1
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    • pp.19-30
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    • 2006
  • For fishery stock assessment and optimum sustainable yield of anchovy in Korea, surplus production(SP) models and a maximum entropy(ME) model are employed in this paper. For determining appropriate models, five traditional SP models-Schaefer model, Schnute model, Walters and Hilborn model, Fox model, and Clarke, Yoshimoto and Pooley (CYP) model- are tested for effort and catch data of anchovy that occupies 7% in the total fisheries landings of Korea. Only CYP model of five SP models fits statistically significant at the 10% level. Estimated intrinsic growth rates are similar in both CYP and ME models, while environmental carrying capacity of the ME model is quite greater than that of the CYP model. In addition, the estimated maximum sustainable yield(MSY), 213,287 tons in the ME model is slightly higher than that of CYP model (198,364 tons). Biomass for MSY in the ME model, however, is calculated 651,000 tons which is considerably greater than that of the CYP model (322,881 tons). It is meaningful in that two models are compared for noting some implications about any significant difference of stock assessment and their potential strength and weakness.

Performance Analysis of a Wet Air-Cycle Refrigeration System (습공기사이클 냉동시스템의 성능해석)

  • Won, Sung Pil
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.11
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    • pp.504-511
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    • 2014
  • The objective of this study is to theoretically analyze the performance of an open wet air-cycle refrigeration system, which nowadays is increasingly generating environmental concern. The temperature and relative humidity of the outside air are selected as the most important parameters. As the temperature and relative humidity of the outside air increase, the pressure ratio of the ACM compressor is determined to be nearly constant, the air temperature at the exit of the system increases, and the amount of condensed water, the cooling capacity, the COP, and the total entropy production rate increase overall. The effects of the effectiveness of the heat exchanger and the efficiency of the turbine on the performance are greater than that of the efficiency of the ACM compressor. Also, the performance of the wet air-cycle refrigeration system with two heat exchangers is enhanced, with a high COP and low total entropy production rate, compared to the system with a single heat exchanger.

Optimal Buffer Allocation in Multi-Product Repairable Production Lines Based on Multi-State Reliability and Structural Complexity

  • Duan, Jianguo;Xie, Nan;Li, Lianhui
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.4
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    • pp.1579-1602
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    • 2020
  • In the design of production system, buffer capacity allocation is a major step. Through polymorphism analysis of production capacity and production capability, this paper investigates a buffer allocation optimization problem aiming at the multi-stage production line including unreliable machines, which is concerned with maximizing the system theoretical production rate and minimizing the system state entropy for a certain amount of buffers simultaneously. Stochastic process analysis is employed to establish Markov models for repairable modular machines. Considering the complex structure, an improved vector UGF (Universal Generating Function) technique and composition operators are introduced to construct the system model. Then the measures to assess the system's multi-state reliability and structural complexity are given. Based on system theoretical production rate and system state entropy, mathematical model for buffer capacity optimization is built and optimized by a specific genetic algorithm. The feasibility and effectiveness of the proposed method is verified by an application of an engine head production line.

Uncertainty of Agricultural product Prices by Information Entropy Model using Probability Distribution for Monthly Prices (월별 가격의 확률분포를 이용한 정보엔트로피 모델에 의한 농산물가격의 불확정성)

  • Eun, Sang-Kyu;Jung, Nam-Su;Lee, Jeong-Jae;Bae, Yeong-Joung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.2
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    • pp.7-14
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    • 2012
  • To analyze any given situation, it is necessary to have information on elements which affect the situation. Particularly, there is greater variability in both frequency and magnitude of agricultural product prices as they are affected by various unpredictable factors such as weather conditions etc. This is the reason why it is difficult for the farmers to maintain their stable income through agricultural production and marketing. In this research, attempts are made to quantify the entropy of various situations inherent in the price changes so that the stability of farmers' income can be increased. Through this research, we developed an entropy model which can quantify the uncertainties of price changes using the probability distribution of price changes. The model was tested for its significance by comparing its simulation outcomes with actual ranges and standard deviations of price variations of the past using monthly agricultural product prices data. We confirmed that the simulation results reflected the features of the ranges and standard deviations of actual price variations. Also, it is possible for us to predict standard deviations for changed prices which will occur after a certain time using the information entropy obtained from relevant agricultural product price data before the time.

Hyperbolic Reaction-Diffusion Equation for a Reversible Brusselator: Solution by a Spectral Method

  • 이일희;김광연;조웅인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.35-41
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    • 1999
  • Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.