• Title/Summary/Keyword: Energy and Atmosphere

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Influence of Oxygen Annealing on Temperature Dependent Electrical Characteristics of Ga2O3/4H-SiC Heterojunction Diodes (산소 후열처리가 Ga2O3/4H-SiC 이종접합 다이오드의 온도에 따른 전기적 특성에 미치는 영향 분석)

  • Chung, Seung Hwan;Lee, Hyung Jin;Lee, Hee Jae;Byun, Dong Wook;Koo, Sang Mo
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.138-143
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    • 2022
  • We analyzed the influence of post-annealing on Ga2O3/n-type 4H-SiC heterojunction diode. Gallium oxide (Ga2O3) thin films were deposited by radio frequency (RF) sputtering. Post-deposition annealing at 950℃ in an Oxygen atmosphere was performed. The material properties of Ga2O3 and the electrical properties of the diodes were investigated. Atomic Force Microscopy (AFM), X-Ray Diffraction and Scanning Electron Microscope (SEM) images show a significant increase in the roughness and crystallinity of the O2-annealed films. After Oxygen annealing X-ray Photoelectron Spectroscopy (XPS) shows that the atomic ratio of oxygen increases which is related to a decrease in oxygen vacancy within the Ga2O3 film. The O2-annealed diodes exhibited higher on-current and lower leakage current. Moreover, the ideality factor, barrier height, and thermal activation energy were derived from the current-voltage curve by increasing the temperature from 298 - 434K.

Surface treatment of silver-paste electrode by atmospheric-pressure plasma-jet (대기압 플라즈마 제트를 이용한 실버페이스트 전극의 표면처리)

  • Sheik Abdur Rahman;Shenawar Ali Khan;Yunsook Yang;Woo Young Kim
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.1
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    • pp.71-80
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    • 2023
  • Silver paste is a valuable electrode material for electronic device applications because it is easy to handle with relatively low heat treatment. This study treated the electrode surface using an atmospheric-pressure plasma jet on the silver-paste electrode. This plasma jet was generated in an argon atmosphere using a high voltage of 5.5 to 6.5 kV with an operating frequency of 11.5 kHz. Plasma-jet may be more beneficial to the printing process by performing it at atmospheric pressure. The electrode surface becomes hydrophilic quickly and contact angle variation is observed on the electrode surface as a function of plasma treatment time, applied voltage, and gas flow rate. Also, there was no deviation in the contact angle after the plasma treatment in the large-area sample, that means a uniform result could be obtained regardless of the substrate size. The outcomes of this study are expected to be very useful in forming a stacked structure in the manufacture of large-area electronic devices and future applications.

Characteristic of Injection According to CO2 Phases Using Surfactants (계면활성제를 활용한 이산화탄소 상태에 따른 주입특성 평가)

  • Seokgu Gang;Jongwon Jung
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.6
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    • pp.5-11
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    • 2023
  • The engineering industry heavily relies on fossil fuels such as coal and petroleum to generate energy through combustion. However, this process emits carbon dioxide into the atmosphere, leading to global warming. To mitigate this issue, researchers have explored various methods to reduce carbon dioxide emissions, one of which is carbon dioxide underground storage technology. This innovative technology involves capturing carbon dioxide from industrial plants and injecting it into the saturated ground layer beneath the earth's surface, storing it securely underground. Despite its potential benefits, carbon dioxide underground storage efficiency needs improvement to optimize storage in a limited space. To address this challenge, our research team has focused on improving storage efficiency by utilizing surfactants. Furthermore, we evaluated how different carbon dioxide states, including gaseous, liquid, and supercritical, impact storage efficiency based on their respective pressures and temperatures within the underground reservoir. Our findings indicate that using surfactants and optimizing the injection rate can effectively enhance storage efficiency across all carbon dioxide states. This research will pave the way for more efficient carbon dioxide underground storage, contributing to mitigating the environmental impact of fossil fuels on the planet.

Exemplary Teachers' Teaching Strategies for Teaching Word Problems (숙련된 교사의 문장제 문제해결 지도 전략 - 미국 교사들을 중심으로)

  • Lee, Kwang-Ho;Shin, Hyun-Sung
    • Journal of the Korean School Mathematics Society
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    • v.12 no.4
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    • pp.433-452
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    • 2009
  • This study investigated the teaching strategies of two exemplary American teachers regarding word problems and their impact on students' ability to both understanding and solving word problems. The teachers commonly explained the background details of the background of the word problems. The explanation motivated the students' mathematical problem solving, helped students understand the word problems clearly, and helped students use various solving strategies. Emphasizing communication, the teachers also provided comfortable atmosphere for students to discuss mathematical ideas with another. The teachers' continuous questions became the energy for students to plan various problem solving strategies and reflect the solutions. Also, this research suggested a complementary model for Polya's problem solving strategies.

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Physical-Chemical Properties of Graphite Foams Produced with Fluorinated Mesophase Pitch (불소화 메조페이스 핏치로 제조된 그라파이트 폼의 물리/화학적 특성)

  • Kim, Ji-Hyun;Kim, Do Young;Lee, Hyung-Ik;Lee, Young-Seak
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.830-837
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    • 2016
  • In order to improve the compressive strength of graphite foams (GFms), mesophase pitch (MP) was stabilized in air atmosphere and then fluorinated at different conditions. The Fluorine/Carbon (F/C) in surface-chemical contents of fluorinated MP has range of 23.75%~61.48% according to the different fluorine partial pressure. The compressive strengths of GFms prepared from fluorinated MP were increased in proportion to the apparent densities. The compressive strength of the GFm produced from MP with 35.93% of F/C (%) showed maximum value in $2.93{\pm}0.06MPa$, which was increased up to 27.95% than that of the GFm prepared from un-fluorinated MP. This result was attributed that the interface bonding between of MPs due to fluorine functional groups with high surface energy helped to improve compressive strength of the GFm.

Reactivity and Preparation of Perovskite-Type Mixed Oxides LaBO3(B = Mn, Fe, Co) by Citrate Sol-Gel Method (Citrate Sol-Gel법에 의한 Perovskite형 복합 산화물 LaBO3(B = Mn, Fe, Co)의 생성 및 환원 반응성)

  • Hwang, Ho Sun;Park, Il Hyeon
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.276-282
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    • 1994
  • Perovskite-type mixed oxides LaBO$_3$(B = Mn, Fe, Co) were prepared by citrate sol-gel method in $air(850^{\circ}C$, 24h). The oxygen stoichiometries and structures of these oxides were determined by XRD and TPR results as followings; LaMnO$_{3.16}$(a = 5.507, c = 13.329 $\AA$, hexagonal), LaFeO$_{3.17}$(a = 5.554, b = 5.555, c = 7.863 $\AA$, orthorhomibic), LaCoO$_{3.0}$(a = 5.436, c = 13.095 $\AA$, hexagonal). The temperature programmed reduction(TPR) experiments in static 300 torr H$_2$ atmosphere shows that the reduction reaction of LaBO$_3$(B = Mn, Fe, Co) proceeds into two stages, and thermal stabilities of these oxides decreased in the order of LaMnO$_3$ > LaFeO$_3$ > LaCoO$_3$. According to the kinetic analysis the lowest activation energy was obtained for LaCoO$_3$.

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A Study on the Kinetics of Thermal Degradation of Polyethylene (폴리에틸렌 열분해의 속도론적 연구)

  • Kim, Myung Soo;Oh, Sea Cheon;Lee, Hae Pyeong;Kim, Hee Taik;Yoo, Kyong Ok
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.548-556
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    • 1999
  • The thermal degradation of polyethylene has been studied using a nonisothermal thermogravimetric technique under a nitrogen atmosphere condition at several heating rates from 10 to $50^{\circ}C/min$. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative have been analyzed by a variety of analytical methods such as Kissinger, Freeman-Carroll, Flynn-Wall, Coats-Redfern, Chatterjee-Conrad, Friedman, Horowitz-Metzger, Ozawa and Denq methods. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because three are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis. From this work, it was found that the apparent activation energy of HDPE was larger than those of LDPE and LLDPE.

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Kinetics of Pholopolymerization of Acrylonitrile Using Sensitizer (광증감제에 의한 Acrylonitrile의 광중합 속도 (I))

  • Seul, Soo-Duk
    • Elastomers and Composites
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    • v.34 no.1
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    • pp.3-10
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    • 1999
  • Kinetics of solution photopolymerization of acrylonitrile(AN) with sensitizer, such as $NaSCN,\;KSCN,\;Ba(SCN)_2,\;NH_4SCN,\;ZnCl_2$ and $Na_2SeO_3$, were studied using UV crosslinker at various monomer concentrations($1.8{\sim}7.58mo1/1$), sensitizer concentrations($10{\sim}60%$), reaction temperature($10{\sim}70^{\circ}C$), energy intensities($1,000{\sim}9,900{\mu}J/cm^2$) at isothermal condition under nitrogen atmosphere. Under the irradiation of high pressure mercury lamp(${\lambda}=365nm$). High conversion and uniform molecular weight were obtained compare to thermal polymerization at reaction temperature of $50^{\circ}C$, reaction time of 3hr and 50% NaSCN without any initiator. Their kinetic model was as follows : $R_p=0.0142[M]^{0.82}[I]^{0.49}[S]^{0.52}$ exp(-1.33/RT).

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A Study on Combustion Characteristics of Wood Biomass for Cogeneration Plant (열병합 발전소용 목질계 바이오매스의 연소 특성에 관한 연구)

  • Ryu, Jeong-Seok;Kim, Ki-Seok;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.296-300
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    • 2011
  • In this work, various wood biomasses were used to determine the combustion characteristics for the fuel of cogeneration plant. Combustion characteristics of four types, i.e., (i) forest products, (ii) recycled wood, (iii) empty fruit bunch, and (iv) palm kernel shell, were examined via thermal gravimetric analyzer (TGA) in air atmosphere and coal was used as a comparison group. From the TGA results, the combustion of the wood biomass was occurred in the range of 280 to $420^{\circ}C$, which was lower than that of coal. Forest product showed the lowest activation energy (0.4 kJ/mol) compared to that of other wood biomasses (about 6 to 14 kJ/mol) and coal (64 kJ/mol). In addition, the reaction rate constant of the wood biomass was lower than that of coal. These results indicate the higher combustion initiation rate of wood biomass due to the high content of volatile matter, which had a low boiling point.

Analysis of Vegetation Cover Fraction on Landsat OLI using NDVI (Landsat 8 OLI영상의 NDVI를 이용한 식생피복지수 분석)

  • Choi, Seokkeun;Lee, Soungki;Wang, Baio
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.32 no.1
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    • pp.9-17
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    • 2014
  • The Vegetation cover is a significant factor to comprehend characteristics of the ground surface for meterological and hydrological models, which measure energy in the atmosphere or predict the runoff of ground surface. Deardorff introduced vegetation cover fraction to quantitatively comprehend the vegetation cover in 1978. After Deardorff, most of previous researches were conducted on low-resolution or high-resolution images, but only few researches on Landsat that are in medium-resolution images. Therefore, this study aims to investigate a way of calculating the vegetation cover fraction by using NDVI of Landsat images, which were hardly handled previously. For accurate vegetation cover fraction, we compared the evaluated parameters from this study with past vegetation cover fraction parameters that have been calculated for using NDVI of Landsat OLI images. The result of research was shown that NDVI is quite correlated with the vegetation fraction cover in the previous researches. In fact, RMSE of vegetation cover fraction values that obtained through the suggested parameters on this study showed the highest accuracy of 7.3% among all the cases.