• Title/Summary/Keyword: Energy and Atmosphere

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Growth and effect of thermal annealing for $AgGaSe_2$ single crystal thin film by hot wall epitaxy (Hot wall epitaxy(HWE)법에 의한 $AgGaSe_2$ 단결정 박막 성장과 열처리 효과)

  • Baek, Seung-Nam;Hong, Kwang-Joon;Kim, Jang-Bok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.5
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    • pp.189-197
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    • 2006
  • A stoichiometric mixture of evaporating materials for $AgGaSe_2$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $AgGaSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy(HWE) system. The source and substrate temperatures were $630^{\circ}C\;and\;420^{\circ}C$, respectively. The temperature dependence of the energy band gap of the $AgGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=1.9501eV-(8.79x10^{-4}eV/K)T^2(T+250K)$. After the as-grown $AgGaSe_2$ single crystal thin films was annealed in Ag-, Se-, and Ga-atmospheres, the origin of point defects of $AgGaSe_2$ single crystal thin films has been investigated by the photoluminescence (PL) at 10K. The native defects of $V_{Ag},\;V_{Se},\;Ag_{int},\;and\;Se_{int}$ obtained by PL measurements were classified as a donors or accepters type. And we concluded that the heat-treatment in the Ag-atmosphere converted $AgGaSe_2$ single crystal thin films to an optical p-type. Also, we confirmed that Ga in $AgGaSe_2$/GaAs did not form the native defects because Ga in $AgGaSe_2$ single crystal thin films existed in the form of stable bonds.

Sedimentary Environments in the Coastal areas of Imja to Nakweol Islands (임자도-낙월도간 해역의 퇴적환경)

  • 유환수;고영구
    • 한국해양학회지
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    • v.28 no.3
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    • pp.241-258
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    • 1993
  • To investigate the sedimentary environments on the coastal areas of Imja to Nakweol islands which show very complex shorelines and several zonal sand ridges in NE-SW direction, southwestern coast of Korea, a total of forty samples were taken by a grab sampler and sedimentological and micropaleontological studies on those samples were carried out. The present study area are classified into muddy sandy gravel, sand, city sand, sandy silt and silt facies. With statistical moment parameters such as mean, sorting, skewness and ketosis for the sediments in the study area, the sediments are generally categorized as shallow sedimentary facies. The characters that are observed in quartz grains among the sandy sediments of the study area imply the existence of high energy environments, temporal exposures in atmosphere and the mixing of clastic sediments of the several different origins. In the sediments of the study area, one genera belonging to six silicoflagellata species and five genera belonging to five nannoplankton species were detected. On the basis of the micro-organism assemblage, the study area seems to be influenced by active reworking dominantly under warm water masses. In addition, organic matter ad carbonate contents in the sediments did not show a definite relation with the occurrences of the micro-organisms in the study area.

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The Estimation of Annual Net Ecosystem Exchange of CO2 in an Apple Orchard Ecosystem of South Korea (국내 사과원 생태계에서 CO2의 연간 순생태 교환량 추정)

  • Shim, Kyo-Moon;Min, Sung-Hyun;Kim, Yong-Seok;Jung, Myung-Pyo;Choi, In-Tae;Kang, Kee-Kyung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.18 no.4
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    • pp.348-356
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    • 2016
  • Carbon dioxide ($CO_2$) gases concentration in atmosphere has been growing since preindustrial times. By sequestering a large amount of atmospheric carbon (C), terrestrial ecosystems are thought to offer a mitigation strategy for reducing global warming. Woody agro-ecosystems such as fruit tree are among the least quantified and most uncertain elements in the terrestrial carbon cycle. $CO_2$ and energy fluxes were measured by the eddy covariance method on a 15-year old apple orchard of South Korea in 2006. Environmental parameters (net radiation, precipitation, etc.) were measured along with fluxes. The results showed that during late June, the ability to sequestrate C was significant at an apple orchard ecosystem and it reached on the peak of $-6.5g\;C\;m^{-2}\;d^{-1}$. We found that in the apple orchard, the daily average of net ecosystem exchange of $CO_2$ (NEE) and cumulative NEE on a yearly basis were $-1.1g\;C\;m^{-2}$ and $-396.9g\;C\;m^{-2}$, respectively. These results reveal that there is high carbon sequestration in the apple orchard of South Korea, which is the same magnitude with repect to that of a natural forested ecosystem of the same biome rank (temperate-humid deciduous forest).

Experimental Study on Fuel Consumptions of LPG Vehicle Depending on the Atmospheric Temperature, Vaporizer Gas Leakage, Engine Oil and Engine Loads (대기온도, 증발기 누출, 엔진오일 및 엔진부하에 따른 LPG 차량의 연비실험에 관한 연구)

  • Kim, Chung-Kyun;Lee, Il-Kwon
    • Journal of the Korean Institute of Gas
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    • v.13 no.5
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    • pp.1-6
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    • 2009
  • This paper presents the fuel consumption effects of LPG vehicle depending on the atmospheric temperature, LP gas leakage of vaporizer, viscosity of engine oil and engine load conditions. The fuel consumption test results show that when the temperature of engine temperature rises, the fuel consumption efficiency increases in general. The fuel consumption efficiency for an atmosphere temperature of $24.2^{\circ}C$ is 13.6% high compared to that of $1^{\circ}C$. No leak vaporizer on fuel consumption efficiency is 5.3% high compared to that of the LP gas leak vaporizer. The fuel economy of new engine oils is just 1.1% high compared to that of used oils with a LPG vehicle mileage of 9,500km. This is not an influential factor compared with an atmospheric temperature and a LP gas leakage. The more important factors on the fuel consumption efficiency are driving conditions such as a rapid braking, abrupt start and fast acceleration. The test results indicate that the normal start is 32.3% high compared to that of an abrupt start and the fast acceleration is 10.8% high compared with that of an abrupt start. And the fuel consumption efficiency for a rapid braking is 18.3% higher than that of an abrupt start. These indicate that the driving condition is very important to reduce the fuel consumption rate.

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Spatio-temporal Variability of Soil Moisture within Remote Sensing Footprints in Semi-arid Area (건조지역 원격탐사 footprint 내 토양수분의 시공간적 변동성 분석)

  • Hwang, Kyotaek;Cho, Hun Sik;Lee, Seung Oh;Choi, Minha
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.3B
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    • pp.285-293
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    • 2010
  • Soil moisture is a key factor to control the exchange of water and energy between the surface and the atmosphere. In recent, many researches for spatial and temporal variability analyses of soil moisture have been conducted. In this study, we analyzed the spatio-temporal variability of soil moisture in Walnut Gulch Experimental Watershed, Arizona, U.S. during the Soil Moisture Experiment 2004 (SMEX04). The spatio-temporal variability analyses were performed to understand sensitivity of five observation sites with precipitation and relationship between mean soil moisture, and its standard deviation and coefficient of variation at the sites, respectively. It was identified that log-normal distribution was superior to replicate soil moisture spatial patterns. In addition, precipitation was identified as a key physical factor to understand spatio-temporal variability of soil moisure based on the temporal stability analysis. Based on current results, higher spatial variability was also observed which was agreed with the results of previous studies. The results from this study should be essential for improvement of the remotely sensed soil moisture retrieval algorithm.

Preparation of Nanocomposite Metal Powders in Metal-Carbon System by Mechanical Alloying Process (기계적 합금화 방법에 의한 금속-카본계에서의 나노복합금속분말의 제조)

  • Kim, Hyun-Seung;Lee, Kwang-Min
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.328-336
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    • 1998
  • In metal-carbon system with no mutual solubility between matrix and alloying elements as solid or liquid phases, Cu-C-X nanocomposite metal powders were prepared by high energy ball milling for solid-lubricating bronze bearings. Elemental powder mixtures of Cu-lOwt.%C- 5wt. %Fe and Cu- lOwt. %C- 5wt. %Al were mechanically alloyed with an attritor in an argon atmosphere, and then microstructural evolution of the Cu-C-X nanocomposite metal powders was examined. It has been found that after 10 hours of MA, the approximately 10$\mu\textrm{m}$ sized Cu-C- X nanocomposite metal powders can be produced in both compositions. Morphological characteristics and microstructural evolution of the Cu-C-X powders have shown a similar MA procedure compared to those of metal-metal system. As a result of X - ray diffraction analysis, diffraction peaks of Cu and C were broaden and peak intensities were decreased as a function of MA time. Especially, the gradual disappearance of C peaks in the X- ray spectra is proved to be due to the lower atomic scattering factor of C. The calculated Cu crystallite sizes in Cu- C- X nanocomposite metal powders by Williamson- Hall equation were about lOnm size, on the other hand, the observed ones by TEM were in the range of 10 to 30nm.

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Evaluation of Concrete Materials for Desulfurization Process By-products (황부산물의 콘크리트 원료 활용 가능성 평가)

  • Park, Hye-Ok;Kwon, Gi-Woon;Lee, Kyeong-Ho;Kim, Moon-Jeong;Lee, Woo-Weon;Ryu, Don-Sik;Lee, Jong-Gyu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.15-22
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    • 2020
  • The landfill gas produced in landfill is generally made up of methane(CH4) and carbon dioxide(CO2) of more than 90%, with the remainder made up of hydrogen sulfide(H2S). However, separate pre-treatment facilities are essential as hydrogen sulfide contained in landfill gas is combined with oxygen during the combustion process to generate sulfur oxides and acid rain combined with moisture in the atmosphere. Various desulfurization technologies have been used in Korea to desulfurize landfill gas. Although general desulfurization processes apply various physical and chemical methods, such as treatment of sediment generation according to the CaCO3 generation reaction and treatment through adsorbent, there is a problem of secondary wastes such as wastewater. As a way to solve this problem, a biological treatment process is used to generate and treat it with sludge-type sulfide (S°) using a biological treatment process.In this study, as a basic study of technology for utilizing the biological treatment by-products of hydrogen sulfide in landfill gas, an experiment was conducted to use the by-product as a mixture of concrete. According to the analysis of the mixture concrete strength of sulfur products, the mixture of sulfur by-products affects the strength of concrete and shows the highest strength value when mixing 10%.

Impact of Future Air Quality in East Asia under SSP Scenarios (SSP 시나리오에 따른 동아시아 대기질 미래 전망)

  • Shim, Sungbo;Seo, Jeongbyn;Kwon, Sang-Hoon;Lee, Jae-Hee;Sung, Hyun Min;Boo, Kyung-On;Byun, Young-Hwa;Lim, Yoon-Jin;Kim, Yeon-Hee
    • Atmosphere
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    • v.30 no.4
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    • pp.439-454
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    • 2020
  • This study investigates the change in the fine particulate matter (PM2.5) concentration and World Health Organization (WHO) air quality index (AQI) in East Asia (EA) under Shared Socioeconomic Pathways (SSPs). AQI is an indicator of increasing levels about health concern, divided into six categories based on PM2.5 annual concentrations. Here, we utilized the ensemble results of UKESM1, the climate model operated in Met Office, UK, for the analysis of long-term variation during the historical (1950~2014) and future (2015~2100) period. The results show that the spatial distributions of simulated PM2.5 concentrations in present-day (1995~2014) are comparable to observations. It is found that most regions in EA exceeded the WHO air quality guideline except for Japan, Mongolia regions, and the far seas during the historical period. In future scenarios containing strong air quality (SSP1-2.6, SSP5-8.5) and medium air quality (SSP2-4.5) controls, PM2.5 concentrations are substantially reduced, resulting in significant improvement in AQI until the mid-21st century. On the other hand, the mild air pollution controls in SSP3-7.0 tend to lead poor AQI in China and Korea. This study also examines impact of increased in PM2.5 concentrations on downward shortwave energy at the surface. As a result, strong air pollution controls can improve air quality through reduced PM2.5 concentrations, but lead to an additional warming in both the near and mid-term future climate over EA.

Effects of the Subgrid-Scale Orography Parameterization and High-Resolution Surface Data on the Simulated Wind Fields in the WRF Model under the Different Synoptic-Scale Environment (종관 환경 변화에 따른 아격자 산악모수화와 고해상도 지면 자료가 WRF 모델의 바람장 모의에 미치는 영향)

  • Lee, Hyeon-Ji;Kim, Ki-Byung;Lee, Junhong;Shin, Hyeyum Hailey;Chang, Eun-Chul;Lim, Jong-Myoung;Lim, Kyo-Sun Sunny
    • Atmosphere
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    • v.32 no.2
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    • pp.103-118
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    • 2022
  • This study evaluates the simulated meteorological fields with a particular focus on the low-level wind, which plays an important role in air pollutants dispersion, under the varying synoptic environment. Additionally, the effects of subgrid-scale orography parameterization and improved topography/land-use data on the simulated low-level wind is investigated. The WRF model version 4.1.3 is utilized to simulate two cases that were affected by different synoptic environments. One case from 2 to 6 April 2012 presents the substantial low-level wind speed over the Korean peninsula where the synoptic environment is characterized by the baroclinic instability. The other case from 14 to 18 April 2012 presents the relatively weak low-level wind speed and distinct diurnal cycle of low-level meteorological fields. The control simulations of both cases represent the systematic overestimation of the low-level wind speed. The positive bias for the case under the baroclinic instability is considerably alleviated by applying the subgrid-scale orography parameterization. However, the improvement of wind speed for the other case showing relatively weak low-level wind speed is not significant. Applying the high-resolution topography and land-use data also improves the simulated wind speed by reducing the positive bias. Our analysis shows that the increased roughness length in the high-resolution topography and land-use data is the key contributor that reduces the simulated wind speed. The simulated wind direction is also improved with the high-resolution data for both cases. Overall, our study indicates that wind forecasts can be improved through the application of the subgrid-scale orography parameterization and high-resolution topography/land-use data.

Characteristics of Precipitation over the East Coast of Korea Based on the Special Observation during the Winter Season of 2012 (2012년 특별관측 자료를 이용한 동해안 겨울철 강수 특성 분석)

  • Jung, Sueng-Pil;Lim, Yun-Kyu;Kim, Ki-Hoon;Han, Sang-Ok;Kwon, Tae-Yong
    • Journal of the Korean earth science society
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    • v.35 no.1
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    • pp.41-53
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    • 2014
  • The special observation using Radiosonde was performed to investigate precipitation events over the east coast of Korea during the winter season from 5 January to 29 February 2012. This analysis focused on the various indices to describe the characteristics of the atmospheric instability. Equivalent Potential Temperature (EPT) from surface (1000 hPa) to middle level (near 750 hPa) was increased when the precipitation occurred and these levels (1000~750 hPa) had moisture enough to cause the instability of atmosphere. The temporal evolution of Convective Available Potential Energy (CAPE) appeared to be enhanced when the precipitation fell. Similar behavior was also observed for the temporal evolution of Storm Relative Helicity (SRH), indicating that it had a higher value during the precipitation events. To understand a detailed structure of atmospheric condition for the formation of precipitation, the surface remote sensing data and Automatic Weather System (AWS) data were analyzed. We calculated the Total Precipitable Water FLUX (TPWFLUX) using TPW and wind vector. TPWFLUX and precipitation amount showed a statistically significant relationship in the north easterly winds. The result suggested that understanding of the dynamical processes such as wind direction be important to comprehend precipitation phenomenon in the east coast of Korea.