• Title/Summary/Keyword: Energy Materials

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Development and Evaluation of the Bender Type Piezoelectric Energy Harvester According to Installation Methods and Vehicle Weight (매설방법과 차량하중에 따른 벤더형 압전에너지 하베스터의 설계 및 평가)

  • Kim, Chang-Il;Jeong, Young-Hun;Yun, Ji-Sun;Cho, Jeong-Ho;Paik, Jong-Hoo;Jang, Yong-Ho;Choi, Beom-Jin;Park, Shin-Seo;Cho, Young-Bong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.5
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    • pp.274-278
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    • 2016
  • A road energy harvester was designed and fabricated to convert mechanical energy from the vehicle load to electrical energy. The road energy harvester is composed of 20 piezoelectric materials. This study attempted to evaluate output depending on pavement materials when paving road piezoelectric energy harvester in the road. Harvester is the bender type and is the method of supporting the both ends of piezoelectric material and applying the load in the middle part. Harvester was paved in the type paved with asphalt, type paved with cement and in the exposed type not covering the top of harvester. The output characteristics were compared and evaluated depending on changes in vehicle load and vehicle speed changes. As vehicles, truck (11.9 ton), SUV(1.6 ton) and sedan (1.5 ton) were used and the output characteristics when driving at the interval of 10 km/h from 10 km/h to 100 km/h were evaluated.

SiOC Anode Material Derived from Poly(phenyl carbosilane) for Lithium Ion Batteries

  • Lee, Yoon Joo;Ryu, Ji Yeon;Roh, Kwang Chul;Kim, Soo Ryong;Kwon, Woo Teck;Shin, Dong-Geun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.480-484
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    • 2013
  • Since SiOC was introduced as an anode material for lithium ion batteries, it has been studied with different chemical compositions and microstructures using various silicon based inorganic polymers. Poly(phenyl carbosilane) is a SiOC precursor with a high carbon supply in the form of the phenyl unit, and it has been investigated for film applications. Unlike any other siloxane-based polymers, oxygen atoms must be utilized in an oxidation process, and the amount of oxygen is controllable. In this study, SiOC anodes were prepared using poly(phenyl carbosilane) with different heat treatment conditions, and their electrochemical properties as an anode material for lithium ion batteries were studied. In detail, cyclic voltammetry and charge-discharge cycling behavior were evaluated using a half-cell. A SiOC anode which was prepared under a heat treatment condition at $1200^{\circ}C$ after an oxidation step showed stable cyclic performance with a reversible capacity of 360 mAh/g.

Photovoltaic Performance of Crystalline Silicon Recovered from Solar Cell Using Various Chemical Concentrations in a Multi-Stage Process (습식 화학 공정에 의한 태양전지로부터 고순도 실리콘 회수 및 이를 이용한 태양전지 재제조)

  • Noh, Min-Ho;Lee, Jun-Kyu;Ahn, Young-Soo;Yeo, Jeong-Gu;Lee, Jin-Seok;Kang, Gi-Hwan;Cho, Churl-Hee
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.697-702
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    • 2019
  • In this study, using a wet chemical process, we evaluate the effectiveness of different solution concentrations in removing layers from a solar cell, which is necessary for recovery of high-purity silicon. A 4-step wet etching process is applied to a 6-inch back surface field(BSF) solar cell. The metal electrode is removed in the first and second steps of the process, and the anti-reflection coating(ARC) is removed in the third step. In the fourth step, high purity silicon is recovered by simultaneously removing the emitter and the BSF layer from the solar cell. It is confirmed by inductively coupled plasma mass spectroscopy(ICP-MS) and secondary ion mass spectroscopy(SIMS) analyses that the effectiveness of layer removal increases with increasing chemical concentrations. The purity of silicon recovered through the process, using the optimal concentration for each process, is analyzed using inductively coupled plasma atomic emission spectroscopy(ICP-AES). In addition, the silicon wafer is recovered through optimum etching conditions for silicon recovery, and the solar cell is remanufactured using this recovered silicon wafer. The efficiency of the remanufactured solar cell is very similar to that of a commercial wafer-based solar cell, and sufficient for use in the PV industry.

Peeling Behavior of Backsheet according to Surface Temperature of Photovoltaic Module (태양광 모듈 표면 온도 제어에 따른 백시트 박리 거동)

  • Kim, Jeong-Hun;Lee, Jun-Kyu;Ahn, Young-Soo;Yeo, Jeong-Gu;Lee, Jin-Seok;Kang, Gi-Hwan;Cho, Churl-Hee
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.703-708
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    • 2019
  • In this study, we investigate the relationship between the peeling behavior of the backsheet of a photovoltaic(PV) module and its surface temperature in order facilitate removal of the backsheet from the PV module. At low temperatures, the backsheet does not peel off whereas, at high temperatures, part of the backsheet remains on the surface of the PV module after the peeling process. The backsheet material remaining on the surface of the PV module is confirmed by X-ray diffraction(XRD) analysis to be poly-ethylene(PE). Differential scanning calorimetry(DSC) is also performed to investigate the interfacial characteristics of the layers of the PV module. In particular, DSC provides the melting temperature($T_m$) of laminated ethylene vinyl acetate(EVA) and of the backsheet on the PV module. It is found that the backsheet does not peel off below the $T_m$ of ethylene of EVA, while the PE layer of the backsheet remains on the surface of the PV module above the $T_m$ of the PE. Thus, the backsheet is best removed at a temperature between the $T_m$ of ethylene and that of PE layer.

High-Temperature Corrosion Behavior of Alloy 617 in Helium Environment of Very High Temperature Gas Reactor (초고온가스로 헬륨 분위기에서 Alloy 617의 고온 부식 거동)

  • Lee, Gyeong-Geun;Jung, Sujin;Kim, Daejong;Jeong, Yong-Whan;Kim, Dong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.659-667
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    • 2012
  • Alloy 617 is a Ni-base superalloy and a candidate material for the intermediate heat exchanger (IHX) of a very high temperature gas reactor (VHTR) which is one of the next generation nuclear reactors under development. The high operating temperature of VHTR enables various applications such as mass production of hydrogen with high energy efficiency. Alloy 617 has good creep resistance and phase stability at high temperatures in an air environment. However, it was reported that the mechanical properties decreased at a high temperature in an impure helium environment. In this study, high-temperature corrosion tests were carried out at $850^{\circ}C-950^{\circ}C$ in a helium environment containing the impurity gases $H_2$, CO, and $CH_4$, in order to examine the corrosion behavior of Alloy 617. Until 250 h, Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures. The activation energy for oxidation in helium environment was 154 kJ/mol. The SEM and EDS results elucidated a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbides. The thickness and depths of degraded layers also showed a parabolic relationship with time. A normal grain growth was observed in the Cr-rich surface oxide layer. When corrosion tests were conducted in a pure helium environment, the oxidation was suppressed drastically. It was elucidated that minor impurity gases in the helium would have detrimental effects on the high-temperature corrosion behavior of Alloy 617 for the VHTR application.

Influence of Winding Patterns and Infiltration Parameters on Chemical Vapor Infiltration Behaviors of SiCf/SiC Composites (SiCf/SiC 복합체의 화학기상침착 거동에 미치는 권선 구조와 침착 변수의 영향)

  • Kim, Daejong;Ko, Myoungjin;Lee, Hyeon-Geun;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.453-458
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    • 2014
  • SiC and its composites have been considered for use as nuclear fuel cladding materials of pressurized light water reactors. In this study, a $SiC_f$/SiC composite as a constituent layer of SiC triplex fuel cladding was fabricated using a chemical vapor infiltration (CVI) process in which tubular SiC fiber preforms were prepared using a filament winding method. To enhance the matrix density of the composite layer, winding patterns, deposition temperature, and gas input ratio were controlled. Fiber arrangement and porosity were the main parameters influencing densification behaviors. Final density of the composites decreased as the SiC fiber volume fraction increased. The CVI process was optimized to densify the tubular preforms with high fiber volume fraction at a high $H_2$/MTS ratio of 20 at $1000^{\circ}C$; in this process, surface canning of the composites was effectively retarded.

Effect of Dissolved Hydrogen on Fuel Crud Deposition (핵연료 피복관 부식생성물 부착에 대한 용존수소의 영향)

  • Baek, S.H.;Kim, U.C.;Shim, H.S.;Lim, K.S.;Won, C.H.;Hur, D.H.
    • Corrosion Science and Technology
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    • v.13 no.2
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    • pp.56-61
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    • 2014
  • The purpose of this work is to investigate the effect of dissolved hydrogen concentration on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the dissolved hydrogen concentration range of 5~70 cc/kg at $325^{\circ}C$ for 14 days. Needle-shaped NiO deposits were formed in the hydrogen range of 5~25 cc/kg, while polygonal nickel ferrite deposits were observed at a hydrogen concentration above 35 cc/kg. However, the dissolved hydrogen content seems to have little effect on the amount of crud deposits.

Nitrogen and Fluorine Co-doped Activated Carbon for Supercapacitors

  • Kim, Juyeon;Chun, Jinyoung;Kim, Sang-Gil;Ahn, Hyojun;Roh, Kwang Chul
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.338-343
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    • 2017
  • Activated carbon has lower electrical conductivity and reliability than other carbonaceous materials because of the oxygen functional groups that form during the activation process. This problem can be overcome by doping the material with heteroatoms to reduce the number of oxygen functional groups. In the present study, N, F co-doped activated carbon (AC-NF) was successfully prepared by a microwave-assisted hydrothermal method, utilizing commercial activated carbon (AC-R) as the precursor and ammonium tetrafluoroborate as the single source for the co-doping of N and F. AC-NF showed improved electrical conductivity ($3.8\;S\;cm^{-1}$) with N and F contents of 0.6 and 0.1 at%, respectively. The introduction of N and F improved the performance of the pertinent supercapacitor: AC-NF exhibited an improved rate capability at current densities of $0.5-50mA\;cm^{-2}$. The rate capability was higher compared to that of raw activated carbon because N and F codoping increased the electrical conductivity of AC-NF. The developed method for the co-doping of N and F using a single source is cost-effective and yields AC-NF with excellent electrochemical properties; thus, it has promising applications in the commercialization of energy storage devices.

Frequency Tuning of Unimorph Cantilever for Piezoelectric Energy Harvesting (주파수 조정에 따른 에너지 하베스팅용 압전 캔틸레버의 특성)

  • Kim, Hyung-Chan;Song, Hyun-Cheol;Jeong, Dae-Yong;Kim, Hyun-Jai;Yoon, Seok-Jin;Ju, Byeong-Kwon
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.660-663
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    • 2007
  • Piezoelectric energy harvesting from our surrounding vibration has been studied for driving the wireless sensor node. To change the vibration energy into the electric-energy efficiently, the natural frequency of cantilever needs to be adjusted to that of a vibration source. When adding 6.80g mass on the end of the fabricated cantilever, a natural frequency shifts from 136 Hz into 49.5 Hz. In addition, electro-mechanical coupling factor increased from 10.20% to 11.90% and resulted in the 1.18 times increase of maximum output power.

Force Control of 6-DOF Pneumatic Joystick

  • Tanaka, Yoshito;Hitaka, Yasunobu;Yun, So-Nam;Kim, Ji-U;Jeong, Eun-A;Park, Jung-Ho;Ham, Young-Bog
    • Journal of Power System Engineering
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    • v.19 no.1
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    • pp.31-37
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    • 2015
  • In this paper, it is presented the development of a new type force feedback system. It is based on a 6-DOF Stewart parallel mechanism which has six pneumatic actuated cylinders. The thrust force of each cylinder is controlled by PWM control for the solenoid valve and it is actualized by PIC controller. When the pneumatic actuator is controlled, it must be considered the influence on the compressibility of air. For this problem, we guarantee the control characteristics by the effect of the accumulator. It is confirmed that the thrust force of the cylinder can be applied to the pneumatic parallel mechanism, and is presented the experimental result of force control for vertical direction.