• 제목/요약/키워드: Electrode interface

검색결과 491건 처리시간 0.026초

전기화학적 임피던스 Fitting 개선을 위한 전극/전해질 계면의 전기회로 모델 연구 (A Study on the Electrical Circuit Model of the Electrode/Electrolyte Interface for Improving Electrochemical Impedance Fitting)

  • 장종현;박정호
    • 전기학회논문지
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    • 제56권6호
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    • pp.1087-1091
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    • 2007
  • Exact impedance modeling of the electrode/electrolyte interface is important in bio-signal sensing electrode development. Therefore, the investigation of the equivalent circuit models for the interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. The proposed model consists of three resistors and two constant phase elements. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

적층형 세라믹 액츄에이터의 세라믹-전극간 계면이 전기적 특성에 미치는 영향에 대한 연구 (Effect of Ceramic-Electrode Interface on the Electrical Properties of Multilayer Ceramic Actuators)

  • 하문수;정순종;송재성;이재신
    • 한국전기전자재료학회논문지
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    • 제15권10호
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    • pp.896-901
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    • 2002
  • The polarization and strain behavior of multilayer ceramic actuators fabricated by tape casting using a PNN-PZT ceramics were investigated in association with electrode size and internal layer number. Spontaneous polarization and strain decreased with increasing electrode size. In addition, the increase of internal layer number brought reduced spontaneous polarization and increased the field-induced strain. Because the actuators structure is designed to stack ceramic layer and electrode layer alternatively, the ceramic-electrode interfaces may act as a resistance to motion of domain wall. To analyze the effect of ceramic-electrode interface, the diffraction intensity ratio of (002) to (200) planes was calculated from X-ray diffraction patterns of samples subjected to a voltage of 200 V. The diffraction intensity ratio of (002) to (200) planes was decreased with increasing electrode size and internal layer number. The diffraction intensity ratio and straining behavior analyses indicate that the Polarization and strain were affected by the amount of 90°domain decreasing with increasing electrode size and internal layer number. Consequently, the change of polarization and displacement with respect to electrode size and layer number is likely to be caused by readiness of the domain wall movement around the interface.

이동형 핵종 분석 장치용 CZT 반도체 검출기의 완충전극에 대한 연구 (A Study of Interface Layer on CdZnTe Radiation Sensor for Potable Isotope Identifier)

  • 조윤호;박세환;김용균;하장호
    • 방사선산업학회지
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    • 제5권1호
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    • pp.95-99
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    • 2011
  • The electrical and mechanical properties of electrode for radiation detection are very important. In general, Au electrode and CZT crystal are combined to form ohmic contacts, and the best energy resolution is shown at the Au electrode. The metal contacts are fabricated by electroless deposition method, sputtering deposition method and thermal evaporation method. The electrode fabrication is easy with use of the thermal evaporation method, while an adhesive strength is weak. Thus interface materials such as Ag, Al and Ni were investigated to overcome defects generated by the this method. The thickness of the interface material between the Au electrode and the CZT crystal was 100 Angstroms, the Au electrode with thickness of 400 Angstroms was deposited. The Al+Au electrode is shown that the results of current-voltage and radiation response are similar to results of Au electrode.

기준전극의 형상과 입력전극사이의 간격을 고려한 건식형 표면 근전위 센서 개발 (Development of Dry-type Surface Myoelectric Sensor for the Shape of the Reference Electrode and the Inter-Electrode Distance)

  • 최기원;최규하
    • 대한전기학회논문지:시스템및제어부문D
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    • 제55권12호
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    • pp.550-557
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    • 2006
  • This paper proposes a dry-type surface myoelectric sensor for the myoelectric hand prosthesis. The designed surface myoelectric sensor is composed of skin interface and processing circuits. The skin interface has one reference and two input electrodes, and the reference electrode is located in the center of two input electrodes. In this paper is proposed two types of sensors with the circle- and bar-shaped reference electrode, but all input electrodes are the bar-shaped. The metal material of the electrodes is the stainless steel (SUS440) that endures sweat and wet conditions. Considering the conduction velocity and the median frequency of the myoelectric signal, the inter-electrode distance (IED) between two input electrodes as 18mm, 20mm, and 22mm is selected. The signal processing circuit consists of a differential amplifier with a band pass filter, a band rejection filter for rejecting 60Hz power-line noise, amplifiers, and a mean absolute value(MAV) circuit. Using SUS440, six prototype skin interface with different reference electrode shape and IED is fabricated, and their output characteristics are evaluated by output signal obtained from the forearm of a healthy subject. The experimental results show that the skin interface with parallel bar shape and the 18mm IED has a good output characteristics. The fabricated dry-type surface myoelectric sensor is evaluated for the upper-limb amputee.

Characteristics and Fabrication of ZTO/Ag/ ZTO Multilayer Transparent Conducting Electrode

  • Cho, Se-Hee;Yang, Jeong-Do;Wei, Chang-Hwan;Pandeyd, Rina;Byun, Dong-Jin;Choia, Won-Kook
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.339-339
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    • 2013
  • We study on the optical and electrical properties of indium-free ZTO(ZnSnO)/Ag/ZTO (ZAZ) multilayer electrodes for the low-cost transparent electrode. In the first step, each single layer was deposited using rf magnetron in-line sputter with various working pressure based on $O_2$/$Ar+O_2$ ratio (0~3%) and power at room temperature. Secondly, we studied the optical and electrical properties by analyzing the refractive index, extinction coefficient, transmittance and resistivity of each layer. Finally, we optimized the thickness of each layer using macleod simulation program based on the analyzed optical properties and fabricated the multilayer electrode. As a result, We achieved a low sheet resistance of $11{\Omega}$/sq and anaverage transmittance of 80% in the visible region of light (380~780 nm). This indicates that indium-free ZAZ multilayer electrode is a promising low-cost and low-temperature processing electrode scheme.

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전극 표면의 거칠기가 펜터신/전극 경계면의 전류-전압 특성에 주는 영향 (Effect of the Surface Roughness of Electrode on the Charge Injection at the Pentacene/Electrode Interface)

  • 김우영;전동렬
    • 한국진공학회지
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    • 제20권2호
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    • pp.93-99
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    • 2011
  • 금속 전극 위에 유기물 채널을 증착하여 만드는 바닥 전극 구조의 유기물 박막 트랜지스터에서 전극 표면이 거친 정도에 따라 전하 주입이 어떻게 달라지는지 조사했다. 금 전극을 실리콘 기판에 증착하고, 가열하여 금 전극 표면을 거칠게 만들었다. 그리고 펜터신과 상부 전극으로 사용할 금 전극을 차례대로 증착하여 금 전극/펜터신/금 전극 구조를 만들었다. 펜터신 증착 초기에는 거친 금 전극 위에서 펜터신 증착핵이 더 많이 보였지만, 막이 두꺼워지면 가열되지 않은 전극과 가열로 거칠어진 전극에서 펜터신 표면 모양에 차이가 거의 없었다. 온도를 바꾸면서 측정한 전류-전압 곡선은 바닥 전극의 표면이 거칠수록 바닥계면의 전위장벽이 높음을 보여주었다. 이 현상은 금속 표면이 거칠수록 일함수가 낮아지며 펜터신과 거친 전극 표면의 경계에 전하 트랩이 더 많기 때문으로 생각된다.

Bi 계열 Glass Frit 조성이 계면저항에 미치는 영향 (The Effects of Composition on the Interface Resistance in Bi-System Glass Frit)

  • 김인애;신효순;여동훈;정대용
    • 한국전기전자재료학회논문지
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    • 제26권12호
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    • pp.858-862
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    • 2013
  • The front electrode should be used to make solar cell panel so as to collect electron. The front electrode is used by paste type, printed on the Si-solar cell wafer and sintered at about $800^{\circ}C$. The paste is composed Ag powder and glass frit which make the ohmic contact between Ag electrode and n-type semiconductor layer. From the previous study, the Ag electrodes which used two commercial glass frit of Bi-system were so different on the interface resistance. The main composition of them was Bi-Zn-B-Si-O and few additives added in one of them. In this study, glass frit was made with the ratio of $Bi_2O_3$ and ZnO on the main composition, and then paste using glass frit was prepared respectively. And, also, the paste using the glass frit added oxide additives were prepared. The change of interface resistance was not large with the ratio of $Bi_2O_3$ and ZnO. In the case of G6 glass frit, 78 wt% $Bi_2O_3$ addition, the interface resistance was $190{\Omega}$ and most low. In the glass frit added oxide, the case of Ca increased over 10 times than it of G6 glass frit on the interface resistance. It was thaught that after sintering, Ca added glass frit was not flowed to the interface between Ag electrode and wafer but was in the Ag electrode.

가압력 변화에 따른 표면조도처리 강판의 저항 점 용접성 비교 (A Comparison of Spot Weldability with Electrode Force Changes in Surface Roughness Textured Steel)

  • 박상순;박영도;김기홍;최영민;임영목;강남현
    • Journal of Welding and Joining
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    • 제26권2호
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    • pp.75-84
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    • 2008
  • With the development of surface roughness textured steel for automotive body-in-white assemble, one of key issues is to understand the role of the surface roughness in textured steel sheets. To investigate effect of surface roughness on weldability in prepared steels, electrode force was varied. Steel sheets (T-H) with high surface roughness ($Ra\;=\;1.94\;{\mu}m$) reduced electrode life. It was attributed to the higher contact resistance at the electrode-sheet interface in the presence of the high surface roughness. The increased electrode diameter decreased current density, therefore reducing weld electrode life due to small weld button size. When an increased electrode force was used, a significant increase in the electrode life was observed in welding of high surface roughness steel sheet. This study suggested that contact resistance at the electrode-sheet interface was the dominant factor, as compared to the sheet-sheet interface for determining electrode life in welding of surface roughness textured steel.

구형파를 이용한 전극계면 분석용 고속 임피던스 분석기의 설계변수 확정을 위한 컴퓨터 시뮬레이션 (Computer simulation to determine system parameters of the square-wave adapted fast impedance analyzer for the electrode - electrolyte interface analysis)

  • 김기련;김광년;심윤보;전계록;정동근
    • 한국시뮬레이션학회논문지
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    • 제14권2호
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    • pp.45-55
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    • 2005
  • There are electric double layer capacitance, polarization resistance and solution resistance in the interface between electrode and solution. Electrode process could be evaluated by the electrical impedance analysis. The necessities of the electrochemical cell analysis with high speed impedance analyzer are followings: minimization of the effects of electric stimulation on electrochemical cell and the concentration of reactive materials, and optimization of impedance signal resolution. This paper represents the design criteria for the selection and stimulation to develop fast impedance analyzer prototype for a electrochemical cell. It was suggested that the design of 470k sample/s sampling rate, 13 bit ABC resolution, and 140ms recording time is required for high speed impedance analysis system in frequency range between dc and 10kHz.

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전극/전해질 계면의 전기화학적 임피던스 측정 및 전기회로 모델 연구 (A Study on the Electrochemical Impedance Spectroscopy and the Electrical Circuit Model for the Electrode/Electrolyte Interface)

  • 장종현;홍장원;박정호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.274-275
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    • 2007
  • The investigation of the equivalent circuit models for the electrode/electrolyte interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

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