• The Journal of the Convergence on Culture Technology
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• v.6 no.4
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• pp.761-766
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• 2020

Phenylamine derivatives are substances that have a biochemical action and are widely applied as psychotropic drugs. In particular, with regard to the quantitative analysis of substances such as ephedrine, amphetamine, pentermine, and dopamine, many previous studies such as electrochemical, vacuum ultraviolet method, and gas chromatography have been conducted. However, there have not been many studies on the structural characteristics of molecular units. Therefore, In this study, we used (HyperChem8.0's, HC) semi-empirical PM3 method to calculate the total energy, band gap, electrostatic potential, and net charge of ephedrine, amphetamine, pentamine and dopamine to investigate the chemical properties of each derivative according to the molecular structure change. The results showed that for total energy -43,171.8, -32,9538.3, -36,407.3 and -43,061.2 Kcal/mol, respectively, while for band gaps, 10.16379377, 9.9531666, 9.7878002 and 9.0589282 eV. Also, for electrostatic potentials, 1.301~-0.045, 1.694~0.299, 0.694~-0.158 and 1.587~-0.048 respectively. Finally, looking at the distribution of net charges, the oxygen atoms, nitrogen atoms and carbon atoms were -0.312~-0.242, -0.161~-0.051 and +0.13~-0.12 respectively. These results are expected to lead to chemical action centered on phenyl radicals and oxygen and nitrogen atoms common to phenethylamine derivatives.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.330-334
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• 2013

Mixtures of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) and silica nanoparticles are coated on the surface of a silk fabrics separator. The coated separators are finally prepared by injecting an electrolyte solution and then characterized for use of lithium-ion battery separator/electrolyte. In the preparation, various contents of dibutylphthalate (DBP) as a plasticizer are used to enhance the formation of micropores within the coated membrane. The coated silk fabrics separators are characterized in terms of ionic conductivity, drenching rate, and electrochemical stability, and the charge-discharge profiles of lithium-ion batteries adopting the coated separators are also examined. As a result, the coated silk fabrics separator prepared using DBP 40~50 wt% and silica shows the superior separator properties and high-rate capability. This is due to (i) high sustainability of silk fabrics, (ii) the formation of micropores with the coated layer membrane by DBP, (iii) increase in drenching rate by silica nanoparticles to involve great enhancements in specific surface area and ionic conductivity.

• Journal of Adhesion and Interface
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• v.22 no.1
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• pp.1-7
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• 2021

The importance of high capacity energy storage devices has recently emerged for stable power supply through renewable energy generation. From this point of view, the Na-air battery (NAB), which is a next-generation secondary battery, is receiving huge attention because it can realize a high capacity through abundant and inexpensive raw materials. In this study, activated carbon-based catalysts for hybrid type Na-air batteries were prepared and their characteristics were compared and analysed. In particular, from the viewpoint of resource recycling, activated carbon (Orange-C) was prepared using discarded orange peel, and performance was compared with Vulcan carbon, which is widely used. In addition, a Pt/C catalyst (homemade-Pt/C, HM-Pt/C) was synthesized using a modified polyol method to check whether the prepared activated carbon can be used as a supported catalyst, and a commercial Pt/C catalyst (Commercial Pt/C) and electrochemical performance were compared. The prepared Orange-C exhibited a typical H3 type BET isotherm, which is evidence that micropore and mesopore exist. In addition, in the case of HM-Pt/C, it was confirmed through TEM analysis that Pt particles were evenly distributed on the activated carbon supported catalyst. In particular, the HM-Pt/C-based NAB showed the smallest voltage gap (0.224V) and good voltage efficiency (92.34%) in the 1st galvanostatic charge-discharge test. In addition, the cycle performance test conducted for 20 cycles showed the most stable performance.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.361-370
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• 2021

Carbon fiber reinforced polymer (CFRP) is one of the composite materials, which has a unique property that is lightweight but strong. The CFRPs are widely used in various industries where their unique characteristics are required. In particular, electric and unmanned aerial vehicles critically need lightweight parts and bodies with sufficient mechanical strengths. Vehicles using the battery as a power source should simultaneously meet two requirements that the battery has to be safely protected. The vehicle should be light of increasing the mileage. The CFRP has considered as the one that satisfies the requirements and is widely used as battery housing and other vehicle parts. On the other hand, in the battery area, carbon fibers are intensively tested as battery components such as electrodes and/or current collectors. Furthermore, using carbon fibers as both structure reinforcements and battery components to build a structural battery is intensively investigated in Sweden and the USA. This mini-review encompasses recent research trends that cover the classification of structural batteries in terms of functionality of carbon fibers and issues and efforts in the battery and discusses the prospect of structural batteries.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.190-195
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• 2011

To investigate the photon-trapping effect and scattering layer effect of $TiO_2$ multi-layer in dye-sensitized solar cell (DSSC) and the degree of recombination of electrons at the electrode treated $TiCl_4$, we formed electrodes of different conditions and obtained the most optimal electrode conditions. To estimate characteristics of the cell, IV curve, UV-Vis spectrophotometer, electrochemical impedance spectroscopy (EIS) and incident photon-to-current conversion efficiency (IPCE) were measured. As a result, we confirmed that the multi-layer's efficiency was higher than that of monolayer in the IV curve and the performance of $TiCl_4$ treated electrode was increased according to decreasing the impedance of EIS. Among several conditions, the efficiency of the cell with scattering layer is higher than that of a layer with the base electrode about 19%. Because the light scattering layer enhances the efficiency of the transmission wavelength and has long electron transfer path. Therefore, the value of the short circuit current increases approximately 10% and IPCE in the maximum peak also increases about 12%.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.290-298
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• 2021

A purification process was performed for the application of natural graphite as an anode material. The influence of the structural change and impurity content of graphite according to the process on the anode electrochemical characteristics was investigated. Natural graphite was chemically/physically purified by acid-treatment which used different amounts of solution of ammonium fluoride/sulfuric acid in the same ratio and thermal treatment used different temperatures (800~2500 ℃). Acid-treatment had limitation to remove impurities, and identified that all impurity contents was removed except some traces of atom such as Si by after progressed thermal-treatment until 2500 ℃. The anode materials characteristic of graphite treated by purification process was improved, and changes in the structure and impurity contents affected dominantly the capacity, rate property and initial Coulombic efficiency. Consequently, the complex purification process improved the graphite structure and also the performance of lithium ion battery by controlling the excessive formation of solid electrolyte interphase and expanding Li⁺ insertion space originated from the effective removal of impurities.

• Journal of the Microelectronics and Packaging Society
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• v.28 no.1
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• pp.47-54
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• 2021

For the bonding of smaller PCB solder bumps of less than 100 microns, an experiment was performed to make up a tin plating solution and find plating conditions in order to produce a bump pattern through tin electroplating, replacing the previous PCB solder bumps process by microballs. After SR patterning, a Cu seed layer was formed, and then, through DFR patterning, a pattern in which Sn can be selectively plated only within the SR pattern was formed on the PCB substrate. The tin plating solution was made based on methanesulfonic acid, and hydroquinone was used as an antioxidant to prevent oxidation of divalent tin ions. Triton X-100 was used as a surfactant, and gelatin was used as a grain refiner. By measuring the electrochemical polarization curve, the characteristics of organic additives in Triton X-100 and gelatin were compared. It was confirmed that the addition of Triton X-100 suppressed hydrogen generation up to -1 V vs. NHE, whereas gelatin inhibited hydrogen generation up to -0.7 V vs. NHE. As the current density increased, there was a general tendency that the grain size became finer, and it was observed that it became finer when gelatin was added.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.184-192
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• 2022

Porous NiO synthesized via hydrothermal synthesis was used in the electrodes of lithium-sulfur batteries to inhibit the elution of lithium polysulfide. The electrode of the lithium-sulfur battery was manufactured as a freestanding flexible electrode using an economical and simple vacuum filtration method without a current collector and a binder. The porous NiO-added S/CNT/NiO electrode exhibited a high initial discharge capacity of 877 mA h g^-1 (0.2 C), which was 125 mA h g^-1 higher than that of S/CNT, and also showed excellent retention of 84% (S/CNT: 66%). This is the result of suppressing the dissolution of lithium polysulfide into the electrolyte by the strong chemical bond between NiO and lithium polysulfide during the charging and discharging process. In addition, for the flexibility test of the S/CNT/NiO electrode, the 1.6 × 4 cm² pouch cell was prepared and exhibited stable cycle characteristics of 620 mA h g^-1 in both the unfolded and folded state.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.442-454
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• 2021

The porous transport layer (PTL) is essential to effectively remove oxygen and hydrogen gas from the electrode surface at high current density operation conditions. In this study, the effect of PTL with different characteristics such as pore size, pore gradient, interfacial coating was investigated by multi-layered sintered mesh. A water electrolysis single cell of active area of the 34.56 cm² was constructed, and IV performance and impedance analysis were conducted in the range of 0 to 2.0 A/cm². It was confirmed that the multi-layered sintered mesh PTL, which have an average pore size of 25 to 57 ㎛ and a larger pore gradient, removed bubbles effectively and thus seemed to improve IV performance. Also, it was confirmed that the catalytic metals such as Ni, NiMo coating on the PTL reduced activation overpotential, but increased mass transport overpotential.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.515-521
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• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.