• Title/Summary/Keyword: Electrical Resistivity & conductivity

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Electrical Transport Properties of LaNi1-xTixO3(x∼0.5) Ceramics (LaNi1-xTixO3(x∼0.5) 세라믹스의 전기전도 특성)

  • Jung, Woo-Hwan
    • Korean Journal of Materials Research
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    • v.19 no.4
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    • pp.186-191
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    • 2009
  • Thermoelectric power and resistivity are measured for the perovskite $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) in the temperature range 77 K - 300 K. The measured thermoelectric power of $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) increases linearly with temperature and is represented by A + BT. The x = 0.1 sample showed metallic behavior, the x = 0.3 showed metal and insulating transition around 150 K, and x = 0.5 showed insulating behavior the over the whole temperature range. The electrical resistivity of x = 0.1 shows linear temperature dependence over the whole temperature range and $T^2$ dependence. On the other hand, the electrical resistivity of x = 0.3 shows a linear relation between $ln{\rho}$ and $T^{-1/4}$ (variable range hopping mechanism) in the range of 77 K to 150 K. For x = 0.5, the temperature dependence of resistivity is characteristic of insulating materials; the resistivity data was fitted to an exponential law, such as ln(${\rho}/T$) and $T^{-1}$, which is usually attributed to a small polaron hopping mechanism. These experimental results are interpreted in terms of the spin polaron (x = 0.1) and variable range hopping (x = 0.3) or small polaron hopping (x = 0.5) of an almost localized $Ni^{3+}$ 3d polaron.

Interpretation of Electrical Resistivity Tomogram with Contents of Clay Minerals for the Land Creeping Area (점토광물 함유량을 고려한 땅밀림 산사태 지역의 전기비저항 자료의 해석)

  • Kim, Jeong-In;Kim, Ji-Soo;Lee, Sun-Joong;Cho, Kyoung-Seo;Kim, Jong-Woo
    • The Journal of Engineering Geology
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    • v.31 no.2
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    • pp.187-197
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    • 2021
  • Clay mineral content of weathered zone is a key parameter for landslide studies. Electrical resistivity tomography is usually performed to delineate the geometry of complex landslides and to identify the sliding surface. In clay-bearing weathered zone, parallel resistivity Archie equation is employed to investigate the effect of conductivity added (resistivity reduced) by clay minerals of kaolinite and montmorillonite, which is dependent on their specific surface area and cation exchange capacities (CEC). A decrease of overall resistivity and apparent formation factor is observed with increasing pore-water resistivity, significantly in montmorillonite. Formation factor is found decreased with increasing porosity and decreasing cementation factor. Parallel Archie equation was applied to the electrical resistivity data from the test area (Sinjindo-ri, Taean-gun, Chungcheongnam-do, Korea) which experienced land creeping in the year of 2014. A panel test with varying clay-mineral contents provides the best fit section when the theoretical section constructed with the assumed contents approaches the field section, from which the clay-mineral content of the weathered zone is estimated to be approximately 10%. Resistivity interpretation schemes including the clay mineral contents for land creeping studies explored in this paper can be challenged more when porosity, saturation, and pore-water resistivity are provided and they are included in the numerical resistivity modeling.

Characteristics of Photoresist-derived Carbon Nanofibers for Li-ion Full Cell Electrode

  • Kim, Hwan-Jun;Joo, Young-Hee;Lee, Sang-Min;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.5
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    • pp.265-269
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    • 2014
  • Carbon nanofiber electrode has been fabricated for energy storage systems by the electrospinning of SU-8 precursor and subsequent pyrolysis. Various parameters including the applied voltage, the distance between syringe tip and target collector and the flow rate of the polymer affect the diameter of SU-8 electrospun nanofibers. Shrinkage during pyrolysis decreases the fiber diameter. As the pyrolysis temperature increases, the resistivity decreases dramatically. Low resistivity is one of the important characteristics of the electrodes of an energy storage device. Given the advantages of carbon nanofibers having high external surface area, electrical conductivity, and lithium intercalation ability, SU-8 derived carbon nanofibers were applied to the anode of a full lithium ion cell. In this paper, we studied the physical properties of carbon fiber electrode by scanning transmission microscopy, thermal gravimetric analysis, and four-point probe. The electrochemical characteristics of the electrode were investigated by cyclic voltammogram and electrochemical impedance spectroscopy plots.

Application of Electrical Resistivity Measurement to an Evaluation of Saline Soil in Cropping Field (염류집적 농경지에서 전기비저항 탐사기법의 활용성)

  • Yoon, Sung-Won;Park, Sam-Gyu;Chun, Hyen-Jung;Han, Keung-Hwa;Kang, Seong-Soo;Kim, Myung-Suk;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1035-1041
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    • 2011
  • Salinity of soil under the plastic film houses in Korea is known as a significant factor to lower the crop production and to hamper the sustainable agricultural land management. In this study we propose a field monitoring technique to examine the methods applied to minimize the adverse effect of salts in soil based on the relationship between soil electrical characteristics and soil properties. Field experiments for 4 different treatments (water only, fertilizer only, DTPA only, and DTPA and fertilizer together) were conducted on soils at the plastic film house built for cultivating a cucumber plant located at Chunan-si, Chungchungnam-do in Korea. The electrical resistivity was measured by both a dipole-dipole and wenner multi-electrodes array method. After the electrical resistivity measurement we also measured the soil water content, temperature, and electrical conductivity on surface soil. The resulted image of the interpreted resistivity by the inversion technique presented a unique spatial distribution depending on the treatment, implying the effect of the different chemical components. It was also highly suspected that resistivity response changed with the nutrients level, suggesting that our proposed technique could be the effective tool for the monitoring soil water as well as nutrient during the cropping period. Especially, subsoils under DTPA treatment at 40 to 60 cm depth typically presented lower soil water accumulation comparing to subsoils under non-DTPA treatment. It is considered that DTPA resulted in increase of a root water uptake. However, our demonstrated results were mainly based on qualitative comparison. Further experiments need to be conducted to monitor temporal changes of electrical resistivity using time lapse analysis, providing that a plant root activity difference based on changes of soil water and nutrients level in time.

Geomagnetic Depth Sounding to Investigate the Trend of Electrical Conductivity in and around the Korean Peninsula (지자기 수직 탐사에 의한 한반도 주변의 전기전도도 구조)

  • 오석훈;양준모;이덕기;남재철
    • Economic and Environmental Geology
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    • v.35 no.5
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    • pp.437-444
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    • 2002
  • Geomagnetic depth sounding (GDS) was performed to analyze the characteristics of deep resistivity structure in and around the Korean Peninsula. The data that have 0.01 nT precision were collected from 5 geomagnetic observatories and measured every one or five second. In this study, amount of 16 days of geomagnetic data were used for analyzing. Generally the sea affects the GDS data seriously due to its high conductivity. However, though the Korean peninsula is surrounded by seas in three sides, the results given by induction arrow strongly show that the trend of electrical conductivity at neighborhood of the Korean Peninsula is reigned by some geological features. Also it is believed that observation in Jeju island is related with the electrical structure around the East China Sea.

Microstructure and Conductivity of Cu-Nb Microcomposites Fabricated by Bundling and Drawing Process (다발체형성과 인발공정에 의해 제조된 Cu-Nb 미세복합재료의 미세조직과 전도도)

  • Kwon, Hoi-Joon;Hong, Sun-Ig;Jee, Kwang-Koo
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.115-119
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    • 2001
  • The electrical properties of heavily drawn bundled Cu- Nb filamentary microcomposite wires were examined and correlated with the microstructural changes caused by thermomechanical treatments. The cross sectional shape of Nb filaments in wires fabricated by bundling and drawing appear straight or slightly curved. The different shape of Nb filaments is attributed to the break- up and cylinderization of Nb filaments during the bundling process at high temperatures. The resistivity of Cu-Nb microcomposites is predominantly controlled by electron scattering at Cu-Nb interfaces. The decrease of the conductivity below the annealing temperature of $400^{\circ}C$ is due to the increasing contribution of the scattering associated with coherency strains of needle- shaped precipitates. The slight decrease of the resistivity ratio (${\rho}_{295K}/{\rho}_{75K}$) is also due to the precipitation of Nb atoms. The increase in conductivity in Cu-Nb microcomposites at an annealing temperature of 50$0^{\circ}C$ is due to the coarsening and spheroidization of Nb filaments.

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Relations between Electrical and Hydraulic Properties of Aquifer in the Ganam Area (가남지역 대수층의 전기적, 수리적 특성 사이의 관계)

  • 이기화;최병수;한원석
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.2
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    • pp.78-84
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    • 1995
  • In 1983, 83 Wenner vertical electrical sounding(VES)s and 22 pumping tests had been carried out by Korea Agricultural Development Corporation(KADC) in Guam Myun, Yeoju Gun, Kyounggi Province. Also, 10 boreholes had been constructed in the area. Using these data electrical and hydraulic properties of aquifer in the Ganam area are investigated in this study. Assuming that the underground is 1-D, VES data are analyzed. Data analysis shows that the subsurface of study area can be interpreted as 4-layer structure and the 3rd layer which is regarded as aquifer has mean thickness of 10 m and mean resistivity of 506 ohm-m and rests on resistive bedrock. Under the circumstances, as most part of electric current flows parallel to the bedding, longitudinal unit conductance is an important parameter controlling VES curves and very closely correlates with transmissivity of aquifer in the study area. Thus, relation between longitudinal unit conductance and transmissivity is investigated in this study. Since resistivity and thickness of each layer are obtained from interpretation of VES data, the relations between transmissivity and resistivity, and between hydraulic conductivity and resistivity are also studied. Studies of such relations show that longitudinal conductance is proportional to transmissivity, and resistivity is inversely proportional to transmissivity and hydraulic conductivity.

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Predictions of Phonon and Electron Contributions to Thermal Conductivity in Silicon Films with Varying Doping Density (박막 실리콘 내 도핑 농도 변화에 따른 포논과 전자의 열전도율 기여도에 대한 수치해석)

  • Jin, Jae-Sik;Lee, Joon-Sik
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2182-2187
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    • 2007
  • The relative contributions of phonon and electron to the thermal conductivity of silicon film with varying doping density are evaluated from the modified electron-phonon interaction model, which is applicable to the micro/nanoscale simulation of energy transport between energy carriers. The thermal conductivities of intrinsic silicon layer thicknesses from 20 nm to 500 nm are calculated and extended to the variation in n-type doping densities from 1.0 ${\times}$ $10^{18}$ to 5.0 ${\times}$ $10^{20}$ $cm^{-3}$, which agree well with the experimental data and theoretical model. From simulation results, the phonon and electron contributions to thermal conductivity are extracted. The electron contribution in the silicon is found to be not negligible above $10^{19}$ $cm^{-3}$, which can be classified as semimetal or metal by the value of its electrical resistivity at room temperature. The thermal conductivity due to electron is about 57.2% of the total thermal conductivity at doping concentration 5.0 ${\times}$ $10^{20}$ $cm^{-3}$ and silicon film thickness 100 nm.

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Fabrication and Characterizations of ITO Film as a Transparent Conducting Electrode for PDP Application (PDP 투명전극의 응용을 위한 ITO 박막의 제작평가)

  • Park, Kang-Il;Lim, Dong-Gun;Kwak, Dong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.788-791
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    • 2002
  • Tin doped indium oxide(ITO) films are highly conductive and transparent in the visible region whose property leads to the applications in solar cell, liquid crystal display, thermal heater, and other sensors. This paper investigated ITO films as a transparent conducting films for application of PDP. ITO films were grown on glass substrate by RF magnetron sputtering method. To achieve high transmittance and low resistivity, we examined the various film deposition such as substrate temperature, gas pressure, annealing temperature, and deposition time. We recommend the substrate temperature of $500^{\circ}C$ and post annealing of $200^{\circ}C$ in $O_2$ atmosphere for good conductivity and transmittance. From XRD examination, ITO films showed a preferred(222) orientation. As substrate temperature increased from RT to $500^{\circ}C$, the intensity of the (222) peak increased. The highest peak intensity was observed at a substrate temperature of $500^{\circ}C$. with the optimum growth conditions, ITO films showed resistivity of $1.04{\times}10^{-4}{\Omega}-cm$ and transmittance of 81.2% for a film 300nm thick in the wavelength range of the visible spectrum.

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PET Fabric/Poly(3,4-ethylenedioxythiophene) Composite as Polymer Electrode in Redox Supercapacitor

  • Cho, Seung-Hyun;Joo, Jin-Soo;Jung, Bo-Ram;Ha, Tae-Min;Lee, Jun-Young
    • Macromolecular Research
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    • v.17 no.10
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    • pp.746-749
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    • 2009
  • Poly(ethylene terephthalate) (PET) fabric/poly(3,4-ethylenedioxythiophene) (PEDOT) composite with stable and high electrochemical activity was fabricated by chemical and electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) on a PET fabric in sequence. Effects of polymerization conditions on the following characteristics of the composite were studied: electrical conductivity and surface morphology. The electrochemical properties were also investigated by cyclic voltammetry and cyclic charge/discharge experiments. The specific volume resistivity, electrical conductivity and specific discharge capacitance of the composite were 0.034 $\Omega-cm$ and 25 S/cm, and 54.5 F/g, respectively.