• Title/Summary/Keyword: Effect of alkalinity

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A Study on Denitrification by Sulfur-Oxidizing Bacteria for the Industrial Wastewater Contain Fluoride and Nitrogen (불소.질소 함유 폐수의 황산화탈질에 관한 연구)

  • Cho, Nam-Chan;Moon, Jong-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.774-781
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    • 2011
  • Nitric acid and hydrofluoric acid are used for acid pickling in zirconium alloy tubing manufacturing process. Nitrate and fluoride in the wastewater were treated by chemical coagulation and SOD (Sulfur Oxidation Denitrification) process. This study is investigated the effect of fluoride concentration and the optimal condition for SOD process. The limited fluoride concentration for SOD process was below 20 mg F-/L. The adjusted pH and alkalinity by NaOH and $NaHCO_3$ was shown to be more effective for removal of nitrate compared with using NaOH. Furthermore, the microbial activator mixed trace elements and ingredient for alkalinity did not only supplement with alkalinity but also enhance the growth and proliferation for sulfur-oxidizing bacteria. As a result, the inorganic industrial wastewater was successfully treated by the microbial activator in SOD process without continuous addition of seed sludge. Finally, SOD process was shown to remove nitrate in industrial wastewater and to contribute the microbial activator for activation of sulfur-oxidizing bacteria.

Some Factors Effect on the Detergency of Triglyceride (Triglyceride의 세척성에 영향을 미치는 몇가지 요인)

  • Lee Mee Sik;Kim Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.5 no.1
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    • pp.15-21
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    • 1981
  • The effect of fatty acid content in oily soil and conditions of washing on the removal of triglyceride have been studied. Cotton lawn was soiled with the four-component soil-tripalmitin, palmitic acid, dodecyl alcohol and dodecane-and washed in constant temperature waterbath shaker. The detergency was estimated by analysis of triglyceride labelled carbon-14 on fabrics before and after washing by means of liquid scintillation counting. It was shown that the detergency of triglyceride washed with the nonionic, nonylphenol poly (10)-ethylene oxide and soap was increased steadily with increasing temperature, whereas with the anionics Na-DBS and SLS, the detergency was rather decreased when the temperature was elevated above $40^{\circ}C$. To investigate the effects of free fatty acid content in soil on the removal of triglyceride, the fabrics were soiled altering palmitic acid content, and then washed. From the results, the detergency of triglyceride was developed with increasing free fatty acid content. With soils containing less than $30\%$ of free fatty acid, of the three detergents tested, the nonionic was by far the most effective soil removal. Soap was intermediate and the synthetic anionic was the poorest. With soil containing $45\%$ of free fatty acid, soap was the most effective soil removal. When NaOH was added to detergent solution. the detergency of triglyceride was improved without regard to detergents. The optimum alkalinity was obtained according to free fatty acid content. And the alkalinity changed to low NaOH concentration with increasing free fatty acid content. From the results mentioned above, it could be concluded that the major removal mechanisms of triglyceride containing oily soil were mesomorphic phase formation, solubilization and soap forma-tion when alkali was added in detergent solution.

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Effect of Basic Oxygen Furnace Slag used as Structural Filling Materials on the Subsurface Environment (성·복토용으로 사용된 전로제강슬래그가 주변 토양환경에 미치는 영향)

  • Lee, Hosub;Nam, Taekwoo;Jho, Eun Hea;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.6-13
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    • 2016
  • The effect of blast oxygen furnace (BOF) slag used as filling materials on the soil environment was studied using column tests that simulated the flow of the BOF slag leachate through the soil layer. The Cu, Mn, Zn, Ni, and F contents of the leachate affected soil were similar to that of the controls (i.e., soils that were not affected by the leachate). The As, Cd, and Pb contents were lower in the leachate affected soils than the controls. The changes in these contaminants contents can be attributed to the interactions between anions such as alkalinity generating anions (e.g., CO32−, HCO3, OH) or calcium ions with heavy metals or F, which consequently affected the fate of heavy metals and F in the leachate affected soils. The germination and growth of Spinapis alba in the soils affected by the leachate and the controls were also similar. However, the proportion of alkalophilic bacteria in the soils affected by the leachate significantly increased, and this can be explained by the increased soil pH due to the alkaline leachate. Overall, this study shows that the alkalinity of the BOF slag leachate, rather than the presence of heavy metals and F in the leachate, needs to be considered when the BOF slag is to be reused as structural filling materials.

Effect of Moisture on Stabilization of Municipal Solid Wastes in Anaerobic Landfill (혐기성 폐기물매립지에 있어서 수분이 매립폐기물의 안정화에 미치는 영향)

  • Kim, Hye-Jin;Kim, Joung-Ho;Oh, Dong-Ik;Kim, Seok-Chan;Lee, Nam-Hoon;Kim, Nack-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.13 no.1
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    • pp.124-130
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    • 2005
  • Landfilling is most widely used as the final disposal tool of solid wastes. Solid wastes landfilled are stabilized by microbial degradation which is affected by several factors such as moisture, oxygen, pH, alkalinity, sulphate, nutrient, inhibitor, hydrogen, and temperature. Especially moisture plays a major role in microbial degradation. In this study, the effects of moisture on the degradation of municipal solids waste (MSW) were investigated. Four lysimeters with four different levels of moisture content i.e., 20, 30, 40, and 50% were operated; lysimeters were packed with MSW, and anaerobically operated. Anaerobic lysimeters with higher moisture content produced more $CO_2$ and landfill gases (LFG). It means that the moisture has a positive effect on the microbial degradation.

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Determination of the Chemical Constituents to Affect the Health and Taste in Bottled Drinking Waters (먹는샘물 중의 건강과 맛에 영향을 미치는 화학성분의 분석)

  • Lee, Nam-Rae;Kim, Young-Man;Choi, Beom-Suk
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.459-467
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    • 1997
  • Due to the growing demand for bottled mineral waters, a study was undertaken to determine the quality of the twenty six brands of domestic and imported drinking waters. The quality of water was evaluated by analyzing the twenty four elements including minerals, essential and/or toxic trace elements, and the analytical items to affect the taste of water. The contribution of drinking water to the mineral nutrition of human was calculated in order to investigate the health effect of drinking water. The taste of water was evaluated in terms of minerals, anions, TDS, alkalinity, hardness and pH.

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A Study on the Reusability of Incinerated Paper Mill Sludge Ash as Cement Additive (시멘트 혼화재로서 제지슬러지 소각재의 재활용 특성)

  • 주소영;연익준;이민희;박준규;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.34-41
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    • 2003
  • The purpose of this study is to examine the effect of stabilization disposal and recycling on incinerated paper mill sludge ash as cement additives. It was investigated chemical(pH, ICP, TGA XRD) and physical(PDA, SEM) characteristics of the incineration ash. And the pozzolanic characteristics of incineration ash was applied to cement as additive to increase the compressive strength. The results were that the pH characteristic of incineration ash was strong alkalinity, the content of silica and alumina as a pozzolanic material was 50.97%, and the average particle size was $5.03{\mu}m$ respectively. When the ash contents as cement additive were varied in 0~15%(wt) of cement weight to explore the effect of the compressive strength on the solidified cement mortar, the proper amount of the incineration ash substituted was about 5~l0%(wt). Therefore we found that using the incineration ash as cement additive obtains the recycling of waste material, the stabilization disposal, the reduction of waste disposal expense, and the protection of environmental problem, too.

Effect of Lime application on Yield and Chemical composition of Burley tobacco (Nicotiana tabacum L.) in pot experiment. (석회 시용이 Burley종 담배의 수량과 화학성분에 미치는 영향)

  • Kim, Yong-Ok;Choi, Jyung
    • Journal of the Korean Society of Tobacco Science
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    • v.10 no.2
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    • pp.99-107
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    • 1988
  • Pot experiment was conducted to find out the effect of lime application on yield and chemical composition of burley tobacco in 1986, Lime increased exchangeable calcium and pH of soil, but decreased Al, Fe and Mn concentrations. Yield was increased by lime application, however lime could not be caused to yield increasing in the soil with high calcium contents. Cored leaves of limed Plot contained higher Mg. K, total nitrogen, NO3-nitrogen, water soluble and insoluble ash, alkalinity number of water soluble and insoluble ash, citric and malic acid, but lower Fe, Mn, protein-nitrogen, NH3-nitrogen, nicotine petroleum ether extract, palmitic and linolenic acid concentrations than those of unlined plot. The linoleic acid and volatile neutral constituents of cured leaves were not affected by liming. Lime increased yield, however it did not affect leaf duality in respect to chemical characteristics, suggesting that liming should be necessary for tobacco cultivation.

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Effective Coagulation and Fenton Reagent Oxidation of Effluent from Biological Landfill Leachate Treatment (생물학적 처리 침출수의 응집 및 펜톤산화 처리)

  • Won, Jong-Choul;Namkoong, Wan;Park, Ki-Hyuk;Cho, Joon-Ho;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.811-817
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    • 2000
  • The objectives of this study are to determine optimal operation condition of chemical coagulation with ferric chloride($FeCl_3$) and fenton reagent oxidation for effluents of a biological denitrification treatment and an existing lagoon treatment of landfill leachate, and to investigate the effect of alkalinity on fenton oxidation. In jar-tester, optimum dosage of ferric chloride for removal of COD was $1,500mgFe^{3+}/L$, removal efficiencies of $COD_{Cr}$ and $COD_{Mn}$ under this condition were about 55% and 64%, respectively. After chemical precipitation($1,500mgFe^{3+}/L$) of biological treatment effluent, optimum $Fe^{2+}/H_2O_2$ ratio of fenton oxidation was 1.5, the maximum removal efficiency of COD was about 80%, and optimum dosages of ferrous sulfate and hydrogen peroxide were $600mgFe^{2+}/L$ and $400mgH_2O_2/L$, respectively. The removal efficiency of COD was decreased as alkalinity was increased.

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Response of Burley Tobacco (Nicotiana tabacum L.) to Application of Lime Materials (석회물질 시용이 Burley종 연초의 수량과 화학성분에 미치는 영향)

  • 이철환;김용옥;박수준
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.2
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    • pp.198-203
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    • 1989
  • Field experiment was conducted to find out the effect of lime materials application on yield, and chemical composition of Burley 21 in 1986. Lime materials and application rate were CaSO$_4$ : Ca 35kg/l0a. CaCO$_3$ : Ca 35kg/l0a and Liming: pH6.5. Contents of Ca and Mg in fresh or cured leaves were increased, but AI, Fe and Mn were decreased by applying lime materials. Yield were increased by applying lime materials. Among lime materials treatment, yield of limed and CaCO$_3$ plot were higher than that of CaSO$_4$ plot. Value per kg of cured leaves was not affected by applying lime materials. Cured leaves of CaSO$_4$ plot contained higher NH$_3$-nitrogen and alkalinity number of water insoluble ash than those of unlimed plot. Cured leaves of CaCO$_3$, plot contained higher alkalinity number of water soluble ash, insoluble ash and volatile neutral constituent, but lower protein-nitrogen and petroleum ether extracts than those of unlimed plot. Cured leaves of limed plot contained higher alkalinity number of water soluble and insoluble ash, NO$_3$-nitrogen and volatile neutral constituents, but lower protein -nitrogen, nicotine and petroleum ether extracts than those unlimed plot. Yield was increased, however leaf Quality in respect to chemical and organoleptic characteristics were not affected considerably by applying lime materials. Therefore, it suggests that controlling the soil pH about 6.5 by liming might be necessary for tobacco cultivation.

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Development of La(III)-zeolite Composite for the Simultaneous Removal of Ammonium Nitrogen and Phosphate in Confined Water Bodies (호소수내 암모니아성 질소 및 인 동시 제거를 위한 란탄-제올라이트 복합체 개발)

  • Paek, Joo-Heon;Kim, Keum-Yong;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.761-766
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    • 2010
  • This study was aimed to propose La(III)-zeolite composite which can effectively and simultaneously remove ammonia and phosphate in confined water bodies such as lakes and ponds. The optimum ratio of La(III):zeolite for the simultaneous removal of ammonia and phosphate was 0.0048 La(III) g:1 zeolite g. The drying temperature of La(III)-zeolite composite severely affected phosphate adsorption showing optimum condition at room temperature. It was revealed that the optimum dosage of La(III)-zeolite composite was 4.052 g/L at adsorption time of 90 min. The presence of alkalinity in aqueous solution brought positive effect on phosphate adsorption. Detachment of La(III) from La(III)-zeolite composite, which was dried at room temperature, was not observed in aquous solution. It indicates that La(III)-zeolite composite could effectively block phosphate released from sediment.