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http://dx.doi.org/10.4491/KSEE.2011.33.10.774

A Study on Denitrification by Sulfur-Oxidizing Bacteria for the Industrial Wastewater Contain Fluoride and Nitrogen  

Cho, Nam-Chan (KEPCO Nuclear Fuel Company, Ltd.)
Moon, Jong-Han (KEPCO Nuclear Fuel Company, Ltd.)
Publication Information
Abstract
Nitric acid and hydrofluoric acid are used for acid pickling in zirconium alloy tubing manufacturing process. Nitrate and fluoride in the wastewater were treated by chemical coagulation and SOD (Sulfur Oxidation Denitrification) process. This study is investigated the effect of fluoride concentration and the optimal condition for SOD process. The limited fluoride concentration for SOD process was below 20 mg F-/L. The adjusted pH and alkalinity by NaOH and $NaHCO_3$ was shown to be more effective for removal of nitrate compared with using NaOH. Furthermore, the microbial activator mixed trace elements and ingredient for alkalinity did not only supplement with alkalinity but also enhance the growth and proliferation for sulfur-oxidizing bacteria. As a result, the inorganic industrial wastewater was successfully treated by the microbial activator in SOD process without continuous addition of seed sludge. Finally, SOD process was shown to remove nitrate in industrial wastewater and to contribute the microbial activator for activation of sulfur-oxidizing bacteria.
Keywords
SOD (Sulfur Oxidation Denitrification) Process; Wastewater Containing Hydrofluoric Acid and Nitric Acid; Alkalinity; Microbial Activator;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Covino, BS, Scalea, JV, "Dissolution behavior of 304 stainlee steel in $HNO_3/HF$ mixtures," Metall. Trasaction A, 17(A), pp.137-148(1986).   DOI
2 박성국 외, "스테인레스강의 청정 산세기술," 대한환경공학회 추계학술연구 발표회 논문초록집, 대한환경공학회, 대구영남대학교, pp.372-375(1995).
3 Cullivan, B. M., "Zero Dischange Wire Pickling through Evaporative Recovery," Co731B Wire J. int. U.S.A., 30(2), pp. 250-253(1997).
4 대일개발, "불산, 초산이 함유된 다성분계 폐혼산의 환경친화적 재활용 기술 개발," 유해폐기물 처리.처분 기술 연구 최종보고서, 환경부(2008).
5 (주)전테크, "폐수처리방법," 특허등록번호 제0503134호, 대한민국(2005).
6 Koenig, A. and Liu, LH., "Autotrophic denitrification of nitrified landfill leachate using elemental sulphate" Water Sci. Technol., 34(5-6), 469-476(1996).   DOI
7 Koenig, A. and Liu, LH., "Asvances in water and wastewater treatment technology Moleclar technology, nutrient removal, sludge reduction, and environment health" Elsevier, 217-226(2001).
8 Zhang, TC. and Lampe, DG., "Sulphur: limestone autotrophic denitrification processes for treatment of nitrate-contaminated water: batch experiment," Water Res. Technol., 33(3), 599-608(1999).   DOI   ScienceOn
9 L. H. Liu., ane Koenig, A., "Use of limestone for pH control in autotrophic denitrification: batch experiments," Biochem., 885-893(2001).
10 Hiroaki Furumai, Hideki Tagui, and Kenji Fujita, "Effects of pH and alkalinity on sulfur-denitrification in a biological granular filter," Water Sci. Technol., 34(1-2), 335-362(1996).
11 Chang-suk JIN, and Yasuo Tanaka. "Decoloration and nitrogen removal of swine wastewater after anaerobic treatment using the sulfur filling up reactor," J. Journal of Water Treatment Biol., 37(3), 93-98(2001).   DOI
12 新日鉄化学(株), "硫黄カルシウム剤による脱窒法", 化学工業日報社, pp.45-46(2004).
13 Bisogni, J. J.r., Driscoll, and C. T. Jr., "Denitrification using thiosulfate and sulfide," J. Environ. Eng. Div. Proc. ASCE, 103, pp.593-604(1977).
14 심동민, 진창숙 외, "담체의 종류와 배열에 따른 회분식 황산화 탈질공정의 고농도 질산성질소를 함유한 인공폐수의 탈질효율 평가," 대한환경공학회지, 28(3), 231-239(2006).
15 Chang-suk JIN, and Yasuo Tanaka, "Decoloration and the nitrogen removal of swine wastewater by sulfur oxidation reaction," J. Water and Waste, 43(12), 1-7(2001).