• Analytical Science and Technology
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• v.18 no.1
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• pp.43-50
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• 2005

A number of carbonyl compounds including formaldehyde and acetaldehyde are well known for their toxicity and irritancy. Hence, acquisition of both qualitative and quantitative tool for their analysis is essential to resolve issues associated with malodor or indoor pollution. Using HPLC/UV method, we examined various aspects involved in the measurements of formaldehyde in environmental samples. The results of our analysis indicated that its detection was made as low as 0.5 ppb (assuming 5 L of sample volume), while its precision was maintained near 2% in terms of relative standard error (RSE). When the stability of calibration was checked by variability of slope values obtained over long-term period (e.g., one month), its values were found to remain constantly with RSE values of 3%. It was also found that liquid-phase reaction between formaldehyde and DNPH proceed very slowly to attain equilibrium (one and half hour), while requiring adequate amount of DNPH to form their derivatives. The overall results of our study thus suggest that there are a number of factors to consider for the accurate analysis of formaldehyde in ambient air.

• Korean Journal of Materials Research
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• v.12 no.8
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• pp.624-633
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• 2002

In order to improve the hydrogen storage capacity and the activation properties of the hydrogen storage alloys, the rare-earth metal alloy series, MmN $i_{4.5}$M $n_{0.5}$Z $r_{x}$(x=0, 0.025, 0.05, 0.1), are prepared by adding excess Zr in MmN $i_{4.5}$M $n_{0.5}$ alloy. The various parts in hydrogen storage vessel consisted of copper pipes reached the setting temperature within 4~5 minutes after heat addition, which indicated that storage vessel had a good heat conductivity required in application. The performance test on storage vessel filled with rare-earth metal alloys of 1000 gr was also conducted after hydrogen charging for 10 min at $18^{\circ}C$ under 10 atm. It showed that the average capacity of discharged hydrogen volume was found to be for $MmNi_{4.5}$ $Mn_{0.5}$ and $MmNi_{4.5}$ $Mn_{x}$ 0.5/$Zr_{samples}$ indicated that the released amount of hydrogen for this $AB_{5}$ type alloys was more than 92 % of theoretic value, and also it was found that the optimum discharging temperature for obtaining an appropriate pressure of 3 atm was determined to be $V^{\circ}C$ for $MmNi_{4.5}$ $Mn_{0.5}$$Zr_{x}$(x=0, 0.025, 0.05, 0.1) hydrogen storage alloys. The released amount of these hydrogen storage samples was 125 $\ell$ , 122.4 $\ell$ and 108.15 $\ell$/kg for $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{0.025}$ $MmNi_{4.5}$M $n_{0.5}$Z $r_{0.05}$, and MmN $i_{4.5}$ Mn_0.5$Zr_{0}$, at $70^{\circ}C$ respectively. Amount of the 2nd phases increase with increase on Zr contents in $MmNi_{4.5}$$Mn_{0.5}$ $Zr_{ 0.1}$/ alloy. This phenomenon indicates that$ ZrNi_3$ in $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{x}$ / phase, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage. As the Zr contents increase, the activation time and the plateau pressure decreases and sloping of the plateau pressure increases.creases.eases.s.

• Journal of the Korean Geosynthetics Society
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• v.17 no.2
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• pp.33-40
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• 2018

Characteristics of interface friction between cohesionless soils and geotechnical structure surfaces play an important role in the analysis of earth load and resistance on the structure. In general, geotechnical structures are mainly composed of either steel or concrete, and their surface roughnesses with respect to soil particle sizes influence the interface characteristics between soils and the structures. Accurate assessment of the interface friction characteristics between soils and structures is important to ensure the safety of geotechnical structures, such as mechanically stabilized earth walls reinforced with inextensible reinforcements, piles embedded into soils, retaining wall backfilled with soils. In this study, based on the database of high quality interface friction tests between frictional soils and solid surfaces from literature, equation representing peak interface friction angle is proposed. The influential factors of the peak interface friction angle are relative roughness between soil and solid surface, relative density of frictional soil, and residual (constant volume) interface friction angle. Futhermore, for the developed equation of the interface friction angle, its uncertainty was assessed statistically based on Goodness-of-fit test results.

• Journal of the Korean earth science society
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• v.41 no.5
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• pp.459-468
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• 2020

In this study, the selection criteria for the occurrence of sea breezes in the Boseong area during the spring season (March-May) of 2016-2017 were prepared for the analysis of vertical weather characteristics. For this purpose, wind speed values were determined using the measured precipitation, cloud volume, wind direction, the difference between the ground and sea temperature, a wind Profiler at an altitude of 1 km, and numerical model data. The dates of the sea breezes in Boseong were classified according to the selection criteria, and the spatial and temporal characteristics of the sea breezes were identified by analyzing the time and altitude of the sea breeze and the size of the wind speed. Sea breezes occurred 23 out of 183 days (12%), and in Boseong, at least 1.2 out of 10 spring days exhibited sea breezes. Sea winds ranged from 1200 to 1800 LST, mainly from ground to 700 m altitude during the day. In addition, the maximum wind speed averaged 4.9 m s^-1, at an altitude of 40 m at 1600 LST, showing relatively lower values than those in a preceding study. This seems to be owing to the reduction in wind speed due to the complexity of the coastal terrain.

• Korean Journal of Remote Sensing
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• v.31 no.5
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• pp.409-419
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• 2015

The Atmospheric Emitted Radiance Interferometer (AERI) which is the Fourier Transform InfraRed (FTIR) spectrometer has been operated by the National Institute of Meteorological Research (NIMR) in Anmyeon island, South Korea since June 2010. The ground-based AERI with similar hyper-spectral infrared sensor to satellite could be an alternative way to validate satellite-based remote sensing. In this regard, the NIMR has focused on the improvement of Cloud data Filtering Method (CFM) which employed only one reference spectrum of clear sky in winter season. This study suggests Seasonal-Cloud data Filtering Method (S-CFM) which applied seasonal AERI reference spectra. For the comparison of applied S-CFM and CFM, the methane retrievals (surface volume mixing ratio) from AERI spectra are used. The quality of AERI methane retrieval applied S-CFM was significantly more improved than that of CFM. The positive result of S-CFM is similar pattern with the seasonal variation of methane from ground-based in-situ measurement, even if the summer season's methane is retrieved over-estimation. In addition, the comparison of vertical total column of methane from AERI and GOSAT shows good result except for the summer season.

• Journal of the Korean earth science society
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• v.24 no.4
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• pp.315-324
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• 2003

The characteristics of particles were evaluated through the measurement data of PM$_{2.5}$, PM$_{10}$ and TSP instruments located in air quality monitoring stations installed and operated by Seoul Metropolitan city. The data of particulate mass on the filter was collected bv a high volume air sampler during the sand storm period. The number of days of sand storm in Seoul showed a different pattern from 1990 to November 2002, We can see a trend of increased occurrence and duration of sand storms. The ratio of PM$_{10}$ to TSP was shown as 52.9% and 59.4% during the sand storm period in 2000 and 2001. respectively. It was indicated that the particles larger than 10${\mu}$m increased by approximately 10% in sand storm periods compared to no sand storm period. While PM$_{10}$ size fraction reached 71.4% in 2002, the contribution of sand storm to total particulate concentration was estimated to be 11.9% for PM$_{2.5}$, 23.1% for PM$_{10}$, 19% for TSP in 2002, respectively and sand storms highly correlated with annual total particulate concentration.

• Journal of the Korean earth science society
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• v.26 no.8
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• pp.790-799
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• 2005

We investigate the optical properties of aerosols over Gongju by an indirect method using the pound measurement, Sky-radiometer. The analysis period is from January to December, 2004. Skyrad. pack.3 is used to estimate the optical properties, such as the aerosol optical thickness (AOT), single scattering albedo (SSA), ${\AA}ngstron$ exponent $({\alpha})$ and size distribution, of aerosols from the ground measured radiance data. And qualify control is applied to minimize the cloud-contaminated data and improve the quality of analysis results. The 12-month average of AOT, ${\alpha}$, and SSA are 0.46, 1.14, and 0.91, respectively. The average volume spectra of aerosols shows a bi-modal distribution, the first peak at fine mode and the second peak at coarse mode. AOT and coarse particles clearly increases while SSA decreases during the Asian dust events. The optical properties of aerosols at Gongju vary with?seasons, but those are not influenced by the wind direction.

• Geophysics and Geophysical Exploration
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• v.21 no.3
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• pp.198-206
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• 2018

In this preliminary study, dehydration of the subducting slab and behavior of the expelled water are numerically modeled using 2-dimensional model scheme. The hydrated minerals in the oceanic crust of the subducting slab experience dehydration by increases in temperature and pressure and expel their water into the overlying mantle wedge. Behavior of the expelled water is governed by both the corner flow in the mantle wedge and porous flow of the expelled water through the pores of the mantle minerals. The effects of convergence rate and age of the subducting slab as well as grain size of the minerals on the dehydration of the subducting slab and behavior of the expelled water are evaluated. The water solubility of the oceanic crust measured from the laboratory experiments is considered for modeling dehydration of the oceanic crust. The model calculations show most of the hydrated minerals in the oceanic crust is dehydrated by a depth of 100 km and the effects of the convergence rate and age of the subducting slab on the dehydration of the subducting slab and behavior of the expelled water are not significant. The larger grain size allows faster porous flow of the expelled water through the oceanic crust, mantle wedge and overlying continental crust and reduces the volume fraction of the expelled water there. The developed technique will be used for future studies on arc volcanism and has a potential implication for the other fields such as seismic tomographic study.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.6
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• pp.580-585
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• 2009

Thermal analysis and design of FPA(Focal Plane Assembly)-CU(Cooling Unit) for Earth observation camera is performed. FPA-CU is the first cooling device for a spacecraft which is designed and manufactured by its own technology in Korea. FPA-CU has a special feature, TBM(Thermal Buffer Mass) which is discriminated from typical cooling devices using heat pipes and radiator. TBM can be regarded as a thermal energy reservoir and it shows thermally transient characteristics, which make it difficult to design the size and shape of TBM. In current study, a method to determine the volume and the size of TBM is proposed and validated. The transient thermal analysis for FPA-CU for 5 operational scenarios is performed and validates the final design of FPA-CU (Radiator,TBM, Heat pipe I/F). In case of an abnormal operation of a heat pipe among three radiator heat pipes, the temperature of FPA can be increased $3{\sim}4^{\circ}C$ according to the numerical simulation.

• Ecology and Resilient Infrastructure
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• v.8 no.4
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• pp.165-178
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• 2021

We studied driftwood behaviors including generation and deposition in a tsunami using a numerical simulation. We used an integrated two-dimensional numerical model, which included a driftwood dynamics model. The study area was Sendai, Japan. Observation data collected by Inagaki et al. (2012) were used to verify the simulation results by comparing them with driftwood deposition patterns. A simplified model was developed to consider the threshold of driftwood generation by the drag force of water flows. To consider the volume of driftwood generated, we estimated the total wood number in the study area using Google Earth. Therefore, we simulated more than 13,000 pieces of driftwood that were generated and transported inland from approximately 300,000 trees that were growing in the forest. The final distribution of the driftwood was similar to the observation data. The reproducibility of the generation and deposition patterns of driftwood showed good agreement in terms of longitudinal deposition pattern. In the future, a sensitivity analysis on driftwood parameters, such as the size of the wood, boundary conditions, and grid size, will be implemented to predict the travel patterns of driftwood. Such modeling will be a useful methodology for disaster prediction based on water flow and driftwood.