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The Study of Composition Analysis of Natural Ghana Cacao Powder and Evaluation on its Skin Improvement Effect (Natural Ghana Cacao Powder의 Polyphenol 성분분석 및 피부개선효과 연구)

  • Shim, Seung-Bo;Oh, Seong-Geun;Chun, Yong-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.5
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    • pp.2434-2438
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    • 2011
  • Ghana is the country that produces world's biggest production of Cacao. Cacao is the main ingredient of chocolate, which has been widely used in a variety of food as its anti-oxidantal effect is well known to public. Moreover, Ghana-produced Cacao is known to have a bigger amount of polyphenol compared to the ones produced elsewhere, and as they are not processed with alkali Ghana-produced Cacoa is slightly acidic as it is. This project aimed at analysing this natural Ghana Cacao's polyphenol composition, developed cosmetic mask using it and don skin irritation tests in order to study skin improvement effect. As a result, it was found that Ghana-produced Cacao contains approximately 3.6% of tannin, showing 5.6 pH. From the result of the first skin irritation test, the result of experiment of the cometic masks which contain 15% of Ghana cacao powder showed that the irritation was not shown. After 120 minutes, in the experiment of skin improvement effect, it was proved to have skin improvement effect, appearing 20% increase in skin moisture, -17% decrease in skin moisture evaporation, convergence of 5.3pH, 24% increase in skin elasticity.

Recovery of Tungsten from WC-Co Hardmetal Sludge by Aqua regia Treatment (WC-Co 초경합금(超硬合金) 슬러지로부터 왕수처리(王水處理)를 이용한 텅스텐의 회수(回收))

  • Kim, Ji-Hye;Kim, Eun-Young;Kim, Won-Back;Kim, Byung-Su;Lee, Jae-Chun;Shin, Jae-Soo
    • Resources Recycling
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    • v.19 no.4
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    • pp.41-50
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    • 2010
  • A fundamental study was carried out to develop a process for recycling tungsten and cobalt from WC-Co hardmetal sludge generated in the manufacturing process of hardmetal tools. The complete extraction of cobalt and simultaneous formation of tungstic was achieved by treating the sludge using aqua regia. The effect of aqua regia concentration, reaction temperature and time, pulp density on cobalt leaching and tungstic acid formation was investigated. The complete leaching of cobalt was attained at the optimum conditions: 100 vol.% aqua regia concentration, $100^{\circ}C$ temperature, 60 min. reaction time and 400 g/L pulp density. A complete conversion of tungsten carbide of the sludge to tungstic acid was however, obtained at the pulp densities lower than 150 g/L under the above condition. The progress of reaction during the aqua regia treatment of the sludge was monitored through the XRD phase identification of the residue. The metallic impurities in the tungstic acid so produced could be further removed as insoluble residues by dissolving the tungsten values in ammonia solution. The ammonium paratungstate($(NH_4)_{10}{\cdot}H_2W_{12}O_{42}{\cdot}4H_2O$) of 99.85% purity was prepared from the ammonium polytungstate solution by the evaporation crystallization method.

Improved Radiochemical Yields, Reliability and Improvement of Domestic $^{18}F$-FDG Auto Synthesizer (국산 $^{18}F$-FDG Auto Sysnthesizer의 수율 향상과 성능 개선)

  • Park, Jun-Hyung;Im, Ki-Seop;Lee, Hong-Jin;Jeong, Kyung-Il;Lee, Byung-Chul;Lee, In-Won
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.3
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    • pp.147-151
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    • 2009
  • Purpose: 2-[$^{18}F$]Fluoro-2-deoxy-D-glucose ([$^{18}F$]FDG) particularly plays as a important role in Positron Emission Tomography (PET) imaging in nuclear medicine. Domestic [$^{18}F$]FDG auto synthesizers are installed in Seoul National University Bundang Hospital (SNUBH) at June 2008, these modules were known that it's synthetic yields were guaranteed in average $45{\pm}5%$ so far. To improve yields and convenience of domestic [$^{18}F$]FDG auto synthesizer, numerous trials in reaction time, base concentration, pressure and temperature were performed to increase [$^{18}F$]FDG yields. Materials and Methods: Several synthetic factors (temperature, time and pressure) and shortcoming were corrected based on many evaporation test. Syringe dispensing of tetra-butylammonium bicarbonate (TBAB) was replaced with micro pipette to prepare tetrabutyl ammonium fluoride salt ([$^{18}F$]TBAF). Troublesome refill of liquid nitrogen every 2 hours which was used to protect vacuum system was changed to charcoal cartridge, base guard filter. To monitor the volume of delivered $[^{18}O]OH_2$ from cyclotron by surveillance camera, we set up the volumetric vial on the cover of the module. In addition to, the recovery vial was added in [$^{18}F$]FDG production system to recover [$^{18}F$]FDG loss due to the leak of valve ($V_{13,14}$) in [$^{18}F$]FDG purification process. Results: When we used micro pipette for adding TBAB ($30\;{\mu}L$ in 12% $H_2O$ in acetonitrile), this quantitative dispensation has enabled to improve $5.5{\pm}1.7%$ residual fluorine-18 activity in fluorine separation cartridge compared to syringe adding. Besides, the synthetic yields of [$^{18}F$]FDG has increased $58{\pm}2.6%$ (n=19), $58{\pm}2.9%$ (n=14), $60%{\pm}2.5%$ (n=17) for 3 months. The life cycle of charcoal cartridge and base vacuum was 3 months prior to filling liquid nitrogen every 2 hours and additional side separator can prevent pump corrosion by organic solvent. After setting of volumetric indicator vial, the operator can easily monitor the total volume of irradiated $[^{18}O]OH_2$ from cyclotron. The recovery vial can be used for the stabilizer when an irregular [$^{18}F$]FDG loss was generated by the leak of valves ($V_{13,14}$). Conclusions: We has optimized appropriate synthetic conditions (temperature, time, pressure) in domestic [$^{18}F$]FDG auto synthesizer. In addition to, the remodeling with several accessories improve yields of domestic [$^{18}F$]FDG auto synthesizer with reliable reproducibility.

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Evapotranspirations of Lettuce and Cucumber by Cropping Systems in Greenhouse (시설재배 상추 및 오이의 재배방식별 증발산량)

  • 남상운;이남호;전우정;황한철;홍성구;허연정
    • Journal of Bio-Environment Control
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    • v.6 no.3
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    • pp.168-175
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    • 1997
  • In greenhouse, data on evapotranspiration or water consumption is important for the rational water management, irrigation planning, thermal environment analysis, and watering automation. But little investigations have been attempted to make clear the characteristics of water consumption in greenhouse. In this paper, evapotransplrations of lettuce and cucumber by cropping systems were investigated. And the correlations among evapotranspiration, pan evaporation, solar radiation, mean air temperature, and minimum relative humidity were analyzed. Experimental cropping systems of lettuce were soil culture and NFT system. Those of cucumber were soil culture, perlite culture, and rockwool culture. Total water consumption of lettuce was 2.62$\ell$/plant in soil culture and 1.71$\ell$/plant in NFT system. That of cucumber was 45.22$\ell$/plant in soil culture, 27.45$\ell$/plant in rockwool culture and 29.06$\ell$/plant in perlite culture. Therefore total water consumption of soil culture showed higher than soilless culture.

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A Study on PIXE Spectrum Analysis for the Determination of Elemental Contents (원소별 함량결정을 위한 PIXE 스펙트럼 분석에 관한 연구)

  • Jong-Seok OH;;Hae-ILL Bak
    • Nuclear Engineering and Technology
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    • v.22 no.2
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    • pp.101-107
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    • 1990
  • The PIXE (Proton Induced X-ray Emission) method is applied to the quantitative analysis of trace elements in tap water, red wine, urine and old black powder samples. Sample irradiations are performed with a 1.202 MeV proton beam from the SNU 1.5-MV Tandem Van de Graaff accelerator, and measurements of X-ray spectra are made by the Si(Li) spectrometer To increase the sensitivity of analysis tap water is preconcentrated by evaporation method. As an internal standard, Ni powder is mixed with black powder sample and yttrium solution is added to the other samples. The analyses of the PIXE spectra are carried out by using the AXIL (Analytical X-ray Analysis by Iterative Least-squares) computer code, in which the routine for least-squares method is based on the Marquardt algorithm. The elements such as Mg, Al, Si, Ti, Fe and Zn are analyzed at sub-ppm levels in the tap water sample. In the red wine sample prepared without preconcentration. the element Ti is detected in the amount of 3ppm. In conclusion, the PIXE method is proved to be appropriate for the analysis of liquid samples by relative measurements using the internal standard. and is expected to be improved by the use of evaluated X-ray production cross-sections and the development of sample preparation techniques.

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Analysis of Vertical Structure of Atmosphere on the Middle Part of the Yellow Sea (서해 중부 해상 대기의 연직구조 분석)

  • Yun, Yong Hun;Im, Ju Yeon;Kim, Baek Jo;Kim, Tae Hui;Seo, Jang Won;Jo, Ha Man
    • Journal of the Korean earth science society
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    • v.21 no.1
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    • pp.22-22
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    • 2000
  • To search out the characteristics of the lower and the upper atmospheric vertical structure, we selected the island(Oeyoundori Ochun-myen Poryeng city Chung-Nam) as an observation site, which is thought to represent the characteristics of ocean well, and observed the vertical structure of the atmosphere by Radiosonde. By using the results of the observation, we analyzed the changes of relative humidity(RH), temperature and wind when the cyclone and the anticyclone passed and compared the results in case of each event. To compare the vertical structure of the ocean atmosphere with those of the continent, we analyzed the values observed with using Radiosonde at Osan site.Through this study, we found that relative humidity changed as the cyclone and the anticyclone passed. That is, when the cyclone came, RH increased first in the upper atmosphere than in the lower and when the high came, RH in the upper decreased sharply to 10%. And the variations of relative humidity in ocean are bigger than those in continent. In the future, we plan to find out the relation between the vapor water in ocean and continent seasonally and daily through the observation in ocean and continent at same time.

Analysis of Vertical Structure of Atmosphere on the Middle Part of the Yellow Sea (서해 중부 해상 대기의 연직구조 분척)

  • Youn, Yong-Hoon;Lim, Joo-Yun;Kim, Baek-Jo;Kim, Tae-Hee;Seo, Jang-Won;Cho, Ha-Man
    • Journal of the Korean earth science society
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    • v.21 no.1
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    • pp.23-39
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    • 2000
  • To search out the characteristics of the lower and the upper atmospheric vertical structure, we selected the island(Oeyoundori Ochun-myen Poryeng city Chung-Nam) as an observation site, which is thought to represent the characteristics of ocean well, and observed the vertical structure of the atmosphere by Radiosonde. By using the results of the observation, we analyzed the changes of relative humidity(RH), temperature and wind when the cyclone and the anticyclone passed and compared the results in case of each event. To compare the vertical structure of the ocean atmosphere with those of the continent we analyzed the values observed with using Radiosonde at Osan site. Through this study, we found that relative humidity changed as the cyclone and the anticyclone passed. That is, when the cyclone came, RH increased first in the upper atmosphere than in the lower and when the high came, RH in the upper decreased sharply to 10%. And the variations of relative humidity in ocean are bigger than those in continent. In the future, we plan to f d out the relation between the vapor water in ocean and continent seasonally and daily through the observation in ocean and continent at same time.

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Structure and Evolution of a Numerically Simulated Thunderstorm Outflow (수치 모사된 뇌우 유출의 구조와 진화)

  • Kim, Yeon-Hee;Baik, Jong-Jin
    • Journal of the Korean earth science society
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    • v.28 no.7
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    • pp.857-870
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    • 2007
  • The structure and evolution of a thunderstorm outflow in two dimensions with no environmental wind are investigated using a cloud-resolving model with explicit liquid-ice phase microphysical processes (ARPS: Advanced Regional Prediction System). The turbulence structure of the outflow is explicitly resolved with a high-resolution grid size of 50m. The simulated single-cell storm and its associated Kelvin-Helmholtz (KH) billows are found to have the lift stages of development maturity, and decay. The secondary pulsation and splitting of convective cells resulted from interactions between cloud dynamics and microphysics are observed. The cooled downdrafts caused by the evaporation of rain and hail in the relatively dry lower atmosphere result in thunderstorm cold-air outflow. The outflow head propagates with almost constant speed. The KH billows formed by the KH instability cause turbulence mixing from the top of the outflow and control the structure of the outflow. Ihe KH billows are initiated at the outflow head, and pow and decay as moving rearward relative to the gust front. The numerical simulation results of the ratio of the horizontal wavelength of the fastest growing perturbation to the critical shear-layer depth and the ratio of the horizontal wavelength of the billow to its maximum amplitude are matched well with the results of other studies.

Earth Science Prospective Teachers' Perceptions on the Relationship between Absolute Humidity and Dew Point Temperature (절대 습도와 이슬점 온도의 관계에 대한 지구과학 예비 교사들의 인식)

  • Kang, So Ra;Seo, Eun-Kyoung;Kim, Dong Young
    • Journal of the Korean earth science society
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    • v.40 no.6
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    • pp.624-638
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    • 2019
  • A questionnaire was administered, and all responses were analyzed to examine prospective teachers' conceptual understanding of the relationship between dew point temperature and absolute humidity in air parcels. The responses revealed that many prospective teachers have substantial misconceptions about the relationship. For example, some thought that the absolute humidity and the dew point temperature are proportional to each other, and that the dew point temperature is proportional to the water vapor mass in the parcel. The misconceptions seemingly stemmed from inadequate descriptions on the relationship in middle-school science textbooks of the 7th and 2007 revised curricula. The study notes that the first year students' textbook of the 2015 revised curriculum introduced the concepts of evaporation, condensation, and volume changes as a function of gaseous pressure and temperature, from a perspective of molecular motion. It is suggested that keeping this perspective in the middle school curriculum, while introducing water vapor pressure as the measure of water vapor amount and dew point temperature, should help prevent middle school teachers and students from having misconceptions. There should be a concerted effort to make the science curriculum more consistent and coherent across the grade levels.

Synthesis of Hydroxyapatite as the Artificial Bone Materials from Phosphate Wastewater Simulating Human Body Fluid (체액 모사 인산폐수로부터 인공뼈 재료로서의 수산아파타이트 합성에 관한 연구)

  • 이진숙;김동수
    • Resources Recycling
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    • v.13 no.3
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    • pp.3-11
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    • 2004
  • Basic studies have been conducted regarding the crystal formation of hydroxyapatite which was produced in the treatment process of phosphate-containing wastewater using calcium ions as the precipitating agent for its employment as the material for artificial bones. The precipitation of hydroxyapatite were conducted in the synthetic solution which simulating human body fluid for its increased applicability. Ca($NO_3$)$_2$$.$$4H_2$O and ($NH_4$)$_2$$HPO_4$ were employed for the precipitation of hydroxyapatite and its composition was analyzed after drying at 80oC. The thermal behavior of precipitate was investigated by examining the change in its crystalline structure according to the sintering temperature. DTA/TG analysis showed that the escape of moisture from the precipitate occurred at ca. $100^{\circ}C$ and the decomposition of ammonia and the evaporation of lattice water were brought about at around $250^{\circ}C$. X-ray diffraction analysis indicated that the thermally treated precipitate consisted mainly of hydroxyapatite. For dried precipitate, the bonds in the component materials which used for the precipitate formation were observed by FT-IR, and after thermal treatment the major bonds in the precipitate were shown to be $OH^{-}$, $PO_4^{3-}$ , and $CO_3^{ 2-}$ , which were main comprising bonds of hydroxyapatite.