• Title/Summary/Keyword: E.A. property

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A Study on the Electrode Charcteristics of the Fluornated AB$_2$ Type Hydrogen Storage Alloys (불화 처리된 AB$_2$계 수소저장합금의 전극특성에 관한 연구)

  • 박호영;이명호;조원일;조병래;이성래;주재백;윤경석
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.262-271
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    • 1997
  • Nickel-matal hydride(Ni-MH) batteries are receiving attention as non-pollunting. high performance rehargeable energy stoage system. The performance of Ni-Mh is significantly influenced by the hydrogen storage alloy materiels used as an anode material. Recently, having discharge capacities higher than the $AB_5$-type hydrogen storage alloys, the Zr-based $AB_2$-Type hydrogen storage alloys has remaining problems regarding cycle life and self-dischareg. These problems need to be solved by improvements in the alloy design and/or surface treatment. This work investiggates the effects the effects of surface property by fluorination on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni{1.2}$ composittion $AB_2$-Type hydrogen storage alloys. EPMA, SEM and AES techniques were used for surface analysis, and the crystal structure was characterized by constant current cycling test and potential sweep methods. Fluorination was found to be effective when La-was incorporated into the alloy, and has unique morphology, higher reactivity, and at the same time formed a protective film. Through, fluorination, the cycle life of an electrode was found to increase significantly, charge/discharge characteristics of the electrode the potential difference between the charge/discharge plateau, i.e polarization(overpotential)were improved.

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Effects of Thermal Treatment on Structural Properties of DLC Films Deposited by FCVA Method (FCVA 방법으로 증착된 DLC 박막의 열처리에 따른 구조적 물성 분석)

  • 김영도;장석모;박창균;엄현석;박진석
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.8
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    • pp.325-329
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    • 2003
  • Effects of thermal treatment on the structural properties of diamond-like carbon (DU) films were examined. The DLC films were deposited by using a modified filtered cathodic vacuum arc (FCVA) deposition system and by varying the negative substrate bias voltage, deposition time, and nitrogen flow rate. Thermal treatment on DLC films was performed using a rapid thermal annealing (RTA) process at $600^{\circ}C$ for 2min. Raman spectroscopy, x-ray photoemission spectroscopy (XPS), atomic force microscope (AFM), and surface profiler were used to characterize the I$_{D}$I$_{G}$ intensity ratio, sp$^3$ hybrid carbon fraction, internal stress, and surface roughness. It was found for all the deposited DLC films that the RTA-treatment results in the release of internal compressive stress, while at the same time it leds to the decrease of sp$^3$ fraction and the increase of I$_{D}$I$_{G}$ intensity ratio. It was also suggested that the thermal treatment effect on the structural property of DLC films strongly depends on the diamond-like nature (i.e., sp$^3$ fraction) of as-deposited film.ed film.

Calculation of Changed Optical Path Length of Bi12SiO20Single Crystal by the Electric Field (전기장에 의한 Bi12SiO20 단결정의 변화된 광행로길이 계산)

  • Lee, Su-Dae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.11
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    • pp.1048-1055
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    • 2005
  • The formula to calculate a variation of optical path length of single crystal by the electric field was derived by this study. The formula was applied to $Bi_{12}SiO_{20}$ single crystal. The results are as follows. In case of the applied electric field in the body diagonal direction and the passing light along the same direction, the variation of optical path length had the largest value. The symmetry of the space distribution of optical path length satisfied $E3C_2\;8C_3$, the set of elements of the symmetry of $Bi_{12}SiO_{20}$ single crystal. The property which gave the largest influence to the variation of optical path length is the strain of length by the Inverse piezoelectric effect. The second influence, is the variation of the refractive index by the electro-optic effect. The variation of optical path length by the inverse piezoelectric effect and by the electro-optic effect have a reverse sign each other.

Quantitative Analysis of Roughness of Powder Surface Using Three-Dimensional Laser Profiler and its Effect on Green Strength of Powder Compacts (분말 표면 조도의 3차원 레이저 분석기를 이용한 정량화와 압분성형체 강도에 미치는 영향 분석)

  • Lee, Dong-Jun;Yoon, Eun-Yoo;Kim, Ha-Neul;Kang, Hee-Soo;Lee, Eon-Sik;Kim, Hyoung-Seop
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.406-410
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    • 2011
  • Green strength is an important property of powders since high green strength guarantees easy and safe handling before sintering. The green strength of a powder compact is related to mainly mechanical and surface characters, governed by interlocking of the particles. In this study, the effect of powder surface roughness on the green strength of iron powders was investigated using a transverse rupture test. Three-dimensional laser profiler was employed for quantitative analyses of the surface roughness. Two different surface conditions, i.e. surface roughness, of powders were compared. The powders having rough surfaces show higher green strength than the round surface powders since higher roughness leads increasing interlocked area between the contacting powders.

Fabrication of Ti/Ir-Ru electrode by spin coating method for electrochemical removal of copper

  • Kim, Joohyun;Bae, Sungjun
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.646-653
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    • 2019
  • Recovery of valuable metals in the industrial wastewater and sludge has attracted an attention owing to limited metallic resources in the earth. In this study, we firstly fabricated Ti/Ir-Ru electrodes by spin coating technique for effective recovery of Cu in electrowinning process. Two different Ti/Ir-Ru electrodes were fabricated using 100 and 500 mM of precursors (i.e., Ir-Ru). SEM-EDX and AFM revealed that Ir and Ru were homogenously distributed on the surface of Ti plate by the spin coating, in particular the electrode prepared by 500 mM showed distinct boundary line between Ir-Ru layer and Ti substrate. XRD, XPS, and cyclic voltammetry also revealed that characteristics of IrO2, RuO2, and TiO2 and its electrocatalytic property increased as the concentration of coating precursor increased. Finally, we carried out Cu recovery experiments using two Ti/Ir-Ru as anodes in electrowinning process, showing that both anodes showed a complete removal of Cu (1 and 10 g/L) within 6 h reaction, but much higher kinetic rate constant was obtained by the anode prepared by 500 mM. The findings in this study can provide a fundamental knowledge for surface characteristics of Ti/Ir-Ru electrode prepared by spin coating method and its potential feasibility for effective electrowinning process.

Displacement Charateristics of Caisson-Type Breakwater under Earthquake Loadings (지진하중을 받는 케이슨 방파제의 변위 특성분석)

  • Shin, Eun-Chul;Jeon, Jae-Ku;Lee, Joong-Hwa;Lee, Chung-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1258-1270
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    • 2009
  • Recently, the earthquakes activities are more of frequency occurred in the country. In case of nomal or large magnitude earthquakes, which cause a rising number of life loss or widespread loss of property. It must be considered how to cope with the situperty of dpmage in the country ty account of ay earthquake. Consequently, the public works have currently ensured against a lot of risk about seismism not only on large scale structures but also relatively small structures. Therefore, in this study, in order to make the seismic stability safe, it has been evaluated by the seismic performance for caisson-type breakwater. The seismic response analyses have conducted on the caisson-type breaker under long-period, short-period and artificial seismic wave. The liquefaction potential of the foundation, which is caisson-type, is also estimated by using the simplified assessment method. Finally, the result of the numerical analysis by PENTAGON 2D finite element method(FEM) program are presented for 3 cases with time-history seismic analysis under the seismic load.

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Magnetic Properties of Ni-Cu-Zn Ferrite with varying Ni, Cu (Ni, Cu 변화에 따른 Ni-Cu-Zn Ferrite의 자기적 특성)

  • 백승철;정승우;김태원;김성수;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.259-262
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    • 1999
  • In this study, we investigated magnetic Properties of N $i_{0.2-x}$C $u_{x}$Z $n_{0.305}$F $e_{0.495}$ (x=0 ~0.2) ferrites. As the increased, the density and shrinkage increased until 5.3g/㎤, 20% respects, but the absorption decreased rate until 0.01%. As a results of the density, absorption rate, and shrinkage rate, the grain growth progressed rapidly in x=0.125 at 105$0^{\circ}C$, x=0.075 at 115$0^{\circ}C$, and x=0.025 at 115$0^{\circ}C$ for 3hours. As the CuO concentration increased, initial permeability increased at sintered 105$0^{\circ}C$ and 115$0^{\circ}C$ for 3 hours, but decreased at 125$0^{\circ}C$ for 3 hoers. The complex permeability as a function of frequency were high values at sintered 105$0^{\circ}C$ for 3 hours in x=0.005, 0.075.5.5.5.

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A Method to Accelerate Convergence of Hessenberg process for Small Signal Stability Analysis of Large Scale Power Systems (대규모 전력계통의 미소신호 안정도 해석을 위한 Hessenberg Process의 수렴특성 가속화 방법)

  • Song, Sung-Geun;Nam, Ha-Kon;Shim, Kwan-Shik;Moon, Chae-Ju;Kim, Yong-Gu
    • Proceedings of the KIEE Conference
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    • 1998.07c
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    • pp.871-874
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    • 1998
  • It is most important in small signal stability analysis of large scale power systems to compute only the dominant eigenvalues selectively with numerical stability and efficiency. Hessenberg process is numerically very stable and identifies the largest eigenvalues in magnitude. Hence, transformed system matrix must be used with the process. Inverse transformation with complex shift provides high selectivity centered on the shift, but does not possess the desired property of computing the dominant mode first. Thus, advantage of high selectivity of the transformation can be fully utilized only when the complex shift is given close to the dominant eigenvalues. In this paper, complex shift is determined by Fourier transforming the results of dynamic simulation with PTI's PSS/E transient simulation program. The convergence in Hessenberg process is accelerated using the iterative scheme. Overall, a numerically stable and very efficient small signal stability program is obtained. The stability and efficiency of the program has been validated against New England 10-machines 39-bus system and KEPCO system.

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The Function Concept in Korean Engineering Freshmen and Some Suggestions on the Curriculum in the Function Area (공과대학 신입생들의 함수개념 연구와 함수 영역의 교육과정에 대한 제안)

  • Kim, Yeon-Mi
    • Communications of Mathematical Education
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    • v.22 no.4
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    • pp.417-444
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    • 2008
  • Many research papers on the college students' functional concept show they have poor understanding on this topic. To compare the results with that of Korean students, four interrelated topics are chosen: How do they understand the concept of function?; what are their misconceptions including epistemological obstacles?; How do the function concepts develop and are acquired? For this a survey has been conducted to 95 engineering students just before they start Calculus course. We have done research on other major areas including psychology, economics and statistics to see how function is defined in these areas. Function definitions from US math text books are also introduced. Based on the these and the survey, some suggestions are made on the new curriculum which treat function as a correspondence relation. Vertical line test should be added to the Algebra II/Pre calculus course to check the univalent property.

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Photocatalytic Properties of TiO2 According to Manufacturing Method (제조방법에 따른 TiO2의 광촉매 특성 분석)

  • Lee, Hong Joo;Park, Yu Gang;Lee, Seung Hwan;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.156-161
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    • 2018
  • $TiO_2$ photocatalyst powders were prepared by chlorination method and sol-gel method. Specific surface area and crystalline (i.e., anatase and rutile) of the catalyst varied depending on manufacture conditions and method. TTIP-sol photocatalyst had higher methylene blue (MB) decomposition characteristics than photocatalyst from chlorination method and TBOT-sol. MB removal efficiency from aqueous solution with TTIP-sol photocatalyst was over 90%. Experimental results showed that the $TiO_2$ photocatalyst with a single anatase phase and a large specific surface area had high decomposition characteristics of organic materials.