• Title/Summary/Keyword: E.A. property

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Synthesis and Characterization of Bandgap-modulated Organic Lead Halide Single Crystals

  • Park, Dae Young;Byun, Hye Ryung;Lee, A Young;Choi, Ho Min;Lim, Seong Chu;Jeong, Mun Seok
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1716-1724
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    • 2018
  • Single crystal of organic lead halide ($CH_3NH_3PbX_3$; $CH_3NH^+_3$ = methylammonium (MA), $X=Cl^-$, $Br^-$, $I^-$) is the best candidate for material intrinsic property studies due to no grain boundary and high crystal quality than the film having a lot of grain boundary and surface defects. The representative crystallization methods are inverse temperature crystallization (ITC) and anti-solvent vapor assisted crystallization (AVC). Herein, we report bandgap modulated organic lead halide single crystals having a bandgap ranging from ~ 2.1 eV to ~ 3 eV with ITC and AVC methods. The bandgap modulation was achieved by controlling the solvents and chloride-to-bromide ratio. Structural, optical and compositional properties of prepared crystals were characterized. The results show that the crystals synthesized by the two crystallization methods have similar properties, but the halide ratios in the crystals synthesized by the AVC method are controlled more quantitatively than the crystals synthesized by ITC.

Nitric Oxide Sensing Property of Gas Sensor Based on Activated Carbon Fiber Radiated by Electron-beam (전자빔이 조사된 활성탄소섬유 기반 가스센서의 일산화질소 감지 특성)

  • Lee, Sangmin;Jung, Min-Jung;Lee, Kyeong Min;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.299-305
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    • 2017
  • Activated carbon fibers (ACFs) were surface-modified by electron beam (E-beam) irradiation and used as a gas sensor electrode to investigate the effect of E-beam on nitric oxide (NO) gas sensing performance. XPS results showed that the oxygen component of ACFs surface treated by E-beam decreased and $sp^2$ bonded carbon of ACFs surface increased. These results were attributed to the structural transformation of ACFs surface irradiated by E-beam. NO gas sensitivity of the electrode composed of ACFs irradiated by100 kGy increased from about 4% to 8%, and the response time was also meaningfully enhanced from 360 s to 120 s. This is due to the fact that the $sp^2$ carbon bond increased by E-beam irradiation of activated carbon fibers, which significantly affects the resistance change of the electrode in NO gas sensing.

Growth and Opoelectrical property for $AgGaSe_2$ single crystal thin film by hot wall epitaxy (Hot Wall Epitaxy(HWE)법에 의한 $AgGaSe_2$ 단결정 박막 성장과 광전기적 특성)

  • Yun, Seuk-Jin;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.122-123
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    • 2007
  • Single crystal $AgGaSe_2$ layers were grown on thoroughly etched semi-insulating GaAs(100) substrate at $420^{\circ}C$ with hot wall epitaxy (HWE) system by evaporating $AgGaSe_2$ source at $630^{\circ}C$. The temperature dependence of the energy band gap of the $AgGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g$(T)=1.9501 eV - $(8.79{\times}10^{-4}\;eV/K)T^2$/(T+250 K). The crystal field and the spin-orbit splitting energies for the valence band of the $AgGaSe_2$ have been estimated to be 0.3132 eV and 0.3725 eV at 10 K, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_5$ states of the valence band of the $AgGaSe_2$. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1^-},\;B_{1^-},\;and\;C_{1^-}$exciton peaks for n=1.

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Fracture Pattern and Physical Property of the Granodiorite for Stone Resources in the Nangsan Area (낭산일대에 분포하는 화강섬록암 암석자원의 열극체계 및 물리적 특성)

  • Yun, Hyun-Soo;Hong, Sei-Sun;Park, Deok-Won
    • The Journal of the Petrological Society of Korea
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    • v.16 no.3
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    • pp.144-161
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    • 2007
  • The studied Nangsan area is widely covered by the Jurassic biotite granodiorite, which is mainly light grey in color and medium-grained in texture. Results of the regional fracture pattern analysis for the granodiorite body are as follows. Strike directions of fractures show three dominant sets in terms of frequency order. The sets are in an order of a (1) $N80^{\circ}{\sim}90^{\circ}E$ (1st-order)>(2) $N70^{\circ}{\sim}80^{\circ}E$ (2nd-order)>(3) $NS{\sim}N10^{\circ}E$ (3rd-order). Spacings of the fractures are mostly predominant in less than 200 cm. Therefore, the granodiorite of the area has more potential for non-dimensional stones than dimension ones. And orientations of vertical quarrying planes can be also divided into two groups in terms of frequency $N14^{\circ}W{\sim}N16^{\circ}E$ (1st-order) and (2) $N78^{\circ}E{\sim}N88^{\circ}E$ (2nd-order). The orientations of the two groups are more or less different from those of the regional fracture patterns. These can be mainly attributed to the preferred orientations of microcrack developed in the quarries. Of physical properties, specific gravity, absorption ratio, porosity, compressive strength, tensile strength and abrasive hardness are 2.65, 0.28%, 0.73%, $1,628kg/cm^2,\;100kg/cm^2$ and 31, respectively. Contrary to the porosity, both granites of the Nangsan and Sogrisan areas show almost similar values of the abrasive hardness. These can be explained by the differences of Qz+Af modes, which can be regarded as an index for abrasive resistance. Meanwhile, it is anticipated that comprehensive understanding of the orientations of vertical quarrying planes and characteristics of various physical properties will be utilized as an important information for stone resources.

Analysis of Economic Effects and Basic Theoretical Frameworks of ITQ Fishery Management - Focusing on the Red Crab Trap Fishery - (ITQ 어업관리의 기본이론과 경제적 효과분석 - 붉은대게어업을 중심으로 -)

  • Lee Sang-Go;Lee Yong-Soo
    • The Journal of Fisheries Business Administration
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    • v.36 no.3 s.69
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    • pp.119-139
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    • 2005
  • The purpose of this paper is to provide information that will help both fishing industry and fisheries authority understand the principals of individual transferable quota(ITQ) fishery management. Theoretical frameworks and primary features of ITQ fishery managemenet are the assignment of exclusive property rights for harvest of common - property fisheries resources. An ITQ fishery management is fundamentally different from the conventional fishery management and it gives an individual fisherman the right to catch a specified quantity of fish, his quota. With ITQ, fisherman's quotas are transferable, in whole or in part. An ITQ is a property with certain rights of use, namely, the right to catch a given quantity and species of fish in a specific location during a specific period of time. The right is exclusive in the sense that no one else has the right to use the quota without the owner's permission. The property may be assigned, traded, and exchanged; i.e., the owner has the right to transfer an ownership to others. An ITQ fishery management leads to both economic efficiency and resource conservation. Motivations to overexploit stocks and to overcapitalize should be lessened because fishermen no longer have to compete for limited resources. There are significant positive net benefits and advantages with ITQ fishery management than without. The potential benefits and advantages of ITQ fishery management include increased profits, economic stability, improved product quality, safer working conditions, less gear conflict, elimination of the race - to - fish phenomenon, less by - catch, less gear loss, improved investment climate, mitigation of market gluts, waste reduction, addition to fisherman's wealth, and compensation for fisherman exiting the fishery. As an independent observe to Red Crab Trap Fishery some of the benefits, problems, and effects, an ITQ fishery management in Red Crab Trap Fishery is still far from to be implemented. Many different and difficult aspects (biological, socioeconomics, administrative) are involved considering the implementation of ITQ fishery management in Red Crab Trap Fishery. Among other fishery management tools, the implementation of ITQ fishery management in Red Crab Trap Fishery is considered to be the best in achieving the better conservation of fisheries resources and their more economic and rational exploitation. Korean fisheries authority should pay great attention to the experience of the economic effects of the ITQ fishery management in Red Crab Trap Fishery in the hope of being able to implement at least some of those experiences into the Korean fishery management.

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Ferroelectric Properties of Ti-Doped and W-Doped SBT Ceramics (Ti와 W이 첨가된 SBT 세라믹스의 강유전 특성)

  • 천채일;김정석
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.401-405
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    • 2004
  • Undoped SrB $i_2$T $a_2$O$_{9}$, donor-doped Sr$_{0.99}$B $i_2$(Ta$_{0.99}$W$_{0.01}$)$_2$O$_{9}$ and acceptor-doped SrB $i_2$(Ta$_{0.99}$Ti$_{0.01}$)$_2$O$_{8.99$ ceramics were prepared and their microstructure, ferroelectric P-E hysteresis and Curie temperature were investigated. Grain size did not influence P-E hysteresis curve in undoped SrB $i_2$T $a_2$O$_{9}$ ceramics. Donor-Doped Sr$_{0.99}$B $i_2$(Ta$_{0.99}$W$_{0.01}$)$_2$O$_{9}$ ceramics showed more saturated P-E hysteresis curve with larger remanent polarization (P$_{r}$) than undoped SrB $i_2$T $a_2$O$_{9}$ ceramics while acceptor-doped SrB $i_2$(Ta$_{0.99}$Ti$_{0.01}$)$_2$O$_{8.99}$ ceramics led to a pinched P-E hysteresis loop. Larger polarization in donor-doped Sr$_{0.99}$B $i_2$(Ta$_{0.99}$W$_{0.01}$)$_2$O$_{9}$ ceramics resulted from easier domain wall motion by Sr-vacancies.

A Study on the Power System Control and Monitoring Technique Using CAN (CAN을 이용한 발전계통의 제어 및 모니터링 기법 연구)

  • Jung, Joon-Hong;Choi, Soo-Young;Park, Ki-Heon
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.52 no.5
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    • pp.268-276
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    • 2003
  • In this paper, we present a new control and monitoring technique for a power system using CAN(Controller Area Network). Feedback control systems having co'ntrol loops closed through a network(i.e. Ethernet, ControlNet, CAN) are called NCSs(Networked Control Systems). The major problem of NCSs is the variation of stability property according to time delay including network-induced delay and computation delay in nodes. We present a new stability analysis method of NCSs with time delay exploiting a state-space model of LTI(Linear Time Invariant) interconnected systems. The proposed method can determine a proper sampling period of NCSs that preserves stability performance even in NCSs with a dynamic controller. We design CAN nodes which can transmit control and monitoring data through CAN bus and apply these to NCSs for a power system. The results of the experiment validate effectiveness of our control and monitoring technique for a power system.

A Construction of an Ontology Server based Intelligent Retrieval using XMDR (XMDR을 이용한 지능형 검색 온톨로지 서버 구축)

  • Hwang Chi-Gon;Jung Gye-Dong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.8B
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    • pp.549-561
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    • 2005
  • As Internet and network technologies have been developed, e-commerces are getting more complex and more various. This paper, for meta-data and data exchange between heterogeneous database systems, uses XML schema proposed in W3C, and XML schema can present meta-data and data of relational database system as XML document format which is structural. It supports various primitive data formats, so that it uses the structure which reflects adequately data formats which relational database system offered. However, current e-commerces use heterogeneous platforms, so difficulties that is mutual interchange and management exist. For the solution for these problems, a standard ontology which defines relations of product classifications and the standard of property expression and the location ontology which offers e-commerce's information about products are constructed. Applying these ontology information to search system, by offering information which customers need efficient search is performed. Combining these ontologies and product classification category information, called XMDR, this XMDR is introduced into product search system, so this paper proposes to construct ontology server method for efficient search.

Studies of Methane Oxidation Catalyst on H2-CNG Mixed Fuel Vehicles (수소-CNG 혼소연료 차량에서의 메탄 저감을 위한 산화촉매에 관한 연구)

  • Lee, Ung-Jae;Shim, Kyung-Sil;Yang, Jaechun;Kim, Tae-Min
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.22-27
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    • 2013
  • HCNG engine is performed as a future engine because of high combustion efficiency and eco-friendly property, and is predicted to a brdge of hydrogen vehicles. As EURO-6 regulagion is due to be applied in 2014, consolidated regulations of methane gas that is exhausted from CNG and HCNG vehicles will come into effect. In this studies, methane oxidation catalyst is introduced to remove methane gas from HCNG emissions. Methane oxidation efficiency on catalyst was studied when it is driven long time. And characterization like metal dispersion, surface area was performed to investigate the correlation of catalyst efficiency and characteristics.

Complexity Issues of Perfect Roman Domination in Graphs

  • Chakradhar, Padamutham;Reddy, Palagiri Venkata Subba
    • Kyungpook Mathematical Journal
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    • v.61 no.3
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    • pp.661-669
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    • 2021
  • For a simple, undirected graph G = (V, E), a perfect Roman dominating function (PRDF) f : V → {0, 1, 2} has the property that, every vertex u with f(u) = 0 is adjacent to exactly one vertex v for which f(v) = 2. The weight of a PRDF is the sum f(V) = ∑v∈V f(v). The minimum weight of a PRDF is called the perfect Roman domination number, denoted by γRP(G). Given a graph G and a positive integer k, the PRDF problem is to check whether G has a perfect Roman dominating function of weight at most k. In this paper, we first investigate the complexity of PRDF problem for some subclasses of bipartite graphs namely, star convex bipartite graphs and comb convex bipartite graphs. Then we show that PRDF problem is linear time solvable for bounded tree-width graphs, chain graphs and threshold graphs, a subclass of split graphs.