• KSCE Journal of Civil and Environmental Engineering Research
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• v.11 no.4
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• pp.189-200
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• 1991

The purpose of this study is to examine the cut-off effect in aquifer by chemical grouting. Moreover, injection tests using specially prepared injection equipment of 1.5 shot system which hydrauric condition can be controlled are attempted to investigate the cut-off effect by confirming the gelling condition of samples according to the variation of flow velosity. And the permeability is measured according to changing of time by falling head test in order to consider the durability of grouts. Therefore to increase the cut-off effect in groundwater flow, shortening the gel-time according to the increasement of flow velocity, increasing the concentration and quantity of grouts(grouting ratio) according to the increasement of that, and as another direct method, contracting the distance between grouting holes or enlarging the grouting line should be done. These coefficients should be designed by data based on injection test in laboratory and field.

• Journal of Korean Tunnelling and Underground Space Association
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• v.8 no.3
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• pp.237-247
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• 2006

The use of high-performance shotcrete lining is indispensable to improve long-term durability of a tunnel and to apply the single-shell tunnelling method. Among a lot of shotcrete admixtures, pozzolan materials such as silica fume have positive effects on increasing the strength and the durability of shotcrete. It is also well known that a cement-based accelerator is much faster in setting time and more eco-friendly than conventional accelerators. This study aimed to improve the properties of wet-mix shotcrete by incorporating with Metakaolin and the calcium aluminate based accelerator. To compare Metakaolin with silica fume, mixing ratios of each material were varied as 4% and 8% of cement weight. Moreover, Metakaolin was blended with silica fume, and their binder was also set to 4% and 8% of cement weight. At each mixing condition, setting time, compressive strength, flexural strength, permeability and freezing-thawing resistance were measured. From the experiments, it was revealed Metakaolin could be a substituting material for silica fume.

• International Journal of Highway Engineering
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• v.15 no.4
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• pp.65-73
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• 2013

PURPOSES : As a research to develop a cement treated base course for an airport pavement which can enhance its drainage, this paper investigated the strength, infiltration performance and durability of the pervious concrete with respect to maximum coarse aggregate sizes and compaction methods. METHODS : This study measured compressive strength, infiltration rate, continuous porosity and freeze-thaw resistance of pervious concrete specimens, which were fabricated with five different compaction methods and different maximum aggregate sizes. In addition, in order to reduce the usage of Portland cement content and to enhance environment-friendliness, a portion of the cement was replaced with Ground Granulated Blast Furnace Slag (GGBS). RESULTS: Compressive strength requirement, 5 MPa at 7 days, was met for all applied compaction methods and aggregate sizes, except for the case of self-compaction. Infiltration rate became increased as the size of aggregate increased. The measured continuous porosities varied with the different compaction methods but the variation was not significant. When GGBS was incorporated, the strength requirement was successfully satisfied and the resistance to freezing-thawing was also superior to the required limit. CONCLUSIONS: The infiltration rate increased as the maximum size of aggregate increased but considering construct ability and supply of course aggregate, its size is recommended to be 25mm. With the suggested mix proportions, the developed pervious concrete is expected to successfully meet requirements for strength, drainage and durability for cement treated base or subbase course of an airport pavement.

• Elastomers and Composites
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• v.46 no.2
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• pp.102-111
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• 2011

The innerliner for a tire has excellent impermeability, air retention and good flex properties. The innerliner offers a role to improve performance parameter, such as air retention and tire durability that is of praricular importance for commercial tires. In order to improve the gas barrier properties of a innerliner, most of the innerliner rubbers, such as a halogenated butyl rubber(HIIR), brominated poly(isobutylene-co-isoprene)(BIIR), brominated polyisobutylene-co-paramethylstyrene(BIMS) are used as nanocomposites with nano fillers such as silicates, graphite etc. Innerliners based on nanocomposites may allow gauge adjustments and permeability reductions with potential improvement in tire durability. This article discusses potential innerliner permeablity reduction and compounding parameters on the properties of nanocomposite based innerliners.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.4
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• pp.92-98
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• 2014

Spacer is a construction material for maintaining cover depth and steel installation, however several problems like staining, leakage, and cracking are currently issued due to performance degradation and unsatisfactory dimensional stability of spacer. Plastic composite is widely used for prevention of brittle failure in cement based material, which yields improvement of crack resistance and ductile failure. This study is for development and applicability evaluation of high strength spacer with slag cement for environmental load reduction and plastic composite like polypropylene fiber, nylon fiber, and glass fiber. For this work, unit weight of 4 different plastic fibers are evaluated through preliminary tests. Physical tests including compressive, flexural, and tensile strength and durability tests including absorption, permeability, length change, crack resistance, carbonation, and freezing and thawing are performed. Through various tests, optimum plastic fiber is selected and manufacturing system for high strength spacer with the selected fiber is developed. Dimensional stability of the developed spacer is evaluated through field applicability evaluation.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.59-63
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• 2020

Radical scavenger is used to improve the durability of PEMFC polymer membrane. In this study, we investigated whether fucoidan extracted from seaweed as a radical scavenger prevents electrochemical degradation through Fenton and OCV Holding experiments. Fucoidan has an antioxidant effect, protecting the polymer membrane from hydrogen peroxide and oxygen radicals, reducing the degradation rate to 1/10. Fucoidan has been shown to be more effective than MnO₂, which is used as a radical scavenger. In the PEMFC cell, the accelerated durability evaluation method (OCV Holding) showed that fucoidan reduced the hydrogen permeability of the polymer membrane by 12% and enhanced the performance by 29.1% compared to without radical scavenger. And fucoidan was found to be more effective in the cathode side ionomer than the anode side.

• Composites Research
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• v.34 no.3
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• pp.148-154
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• 2021

Carbon/epoxy composite bipolar plate (BP) is a BP that is likely to replace existing graphite bipolar plate of vanadium redox flow cell (VRFB) due to its high mechanical properties and productivity. Multi-functional carbon/epoxy composite BP requires graphite coating or additional surface treatment to reduce interfacial contact resistance (ICR). However, the expanded graphite coating has the disadvantage of having low durability under VRFB operating conditions, and the surface treatments incur additional costs. In this work, an excessive resin absorption method is developed, which uniformly removes the resin rich area on the surface of the BP to expose carbon fibers by applying polyester fabric. This method not only reduces ICR by exposing carbon fibers to BP surfaces, but also forms a unique ditch pattern that can effectively hold carbon felt electrodes in place. The acidic environmental durability, mechanical properties, and gas permeability of the developed carbon/epoxy composite BP are experimentally verified.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.4
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• pp.99-106
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• 2011

This study performed research for improvement on basic concept of PBD applying suitable design method before and after LB-DECK composition. According to study, in this case, before composition, it can reduce minuteness cracks by increasing bending tensile strength utilizing polymer concrete, can expect sensuous effect, improve durability as to low permeability, and was evaluated that can reduce covering depth according as it. Also, because LB-DECK baseplate that apply the empirical design method composite is superior load resistance ability than general baseplate, safety is increased, it is expected to secure constructibility and economic performance at the same time because reinforcement arrangement method and reinforcement amount are fixed even if span effective span is increased at ultimate strength design method application.

• International Journal of Highway Engineering
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• v.3 no.4 s.10
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• pp.93-103
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• 2001

This study focused on the field applicability evaluation of SB latex-modified concrete (LMC) for concrete bridge deck overlay using mobile mixer. The main experimental factors were water-cement ratio(31, 33, 35 37%), latex contents(0, 5, 10, 15, 20%), and fine aggregate ratio(55, 56, 57, 58%) in order to evaluate the workability, mechanical properties, and durability property of LMC. The slump loss, air content, compressive and flexible strength tests were used to evaluate LMC workability and strength properties. Also, the rapid chloride permeability test was used to evaluate the relative permeability of LMC. As a results, the LMC with enough workability and good quality was produced when it was mixed in field using mobile mixer, satisfying the target compressive strength and flexural strength. The required water-cement ratio of LMC for same workability when mixing with mobile mixer was less than that when mixing in laboratory. Increasing the amount of latex produced concrete with increased flexural strength by mobile mixer. The required cement-water ratios for same initial $19{\pm}3cm$ slump were 37% and 33% at laboratory and mobile mixer, respectively. The mobile mixer was accurately calibrated satisfying the required specification.

• Membrane Journal
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• v.33 no.6
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• pp.325-343
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• 2023

Direct methanol fuel cells (DMFCs) have been attracting attention as energy conversion devices that can directly supply methanol liquid fuel without a fuel reforming process. The commercial polymer electrolyte membranes (PEMs) currently applied to DMFC are perfluorosulfonic acid ionomer-based PEMs, which exhibit high proton conductivity and physicochemical stability during the operation. However, problems such as high methanol permeability and environmental pollutants generated during decomposition require the development of PEMs for DMFCs using novel ionomers. Recently, studies have been reported to develop PEMs using hydrocarbon-based ionomers that exhibit low fuel permeability and high physicochemical stability. This review introduces the following studies on hydrocarbon-based PEMs for DMFC applications: 1) synthesis of grafting copolymers that exhibit distinct hydrophilic/hydrophobic phase-separated structure to improve both proton conductivity and methanol selectivity, 2) introduction of cross-linked structure during PEM fabrication to reduce the methanol permeability and improve dimensional stability, and 3) incorporation of organic/inorganic composites or reinforcing substrates to develop reinforced composite membranes showing improved PEM performances and durability.