• Title/Summary/Keyword: Dry-strength

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Research of Characterization of Covalently Cross-linked SPEEK/Cs-Substituted MoPA/Ceria 1wt% Composite Membrane for Water Electrolysis (Cs 치환에 따른 수전해용 공유가교 SPEEK/Cs(n)-MoPA/Ceria 1%(n = 1~3) 복합막의 특성 연구)

  • Park, Daeyoung;Hwang, Sungha;Oh, Seunghee;Yoon, Daejin;Kang, Ansoo;Moon, Sangbong;Chung, Janghoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.1-10
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    • 2014
  • Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted phophomolybdic acid(Cs-MoPA) with cross-linking agent contents of 0.01mL. In conclusion, CL-SPEEK/$Cs_{(2.5)}$-MoPA/ceria(1%) membrane showed the optimum results such as 0.1095S/cm of proton conductivity at $80^{\circ}C$, 2.906meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 49.73MPa of tensile strength which were better than Nafion 117 membrane.

Studies on Whole Cell Immobilized Glucose Isomerase - I. Preparation and Properties of Whole Cell Immobilized Glucose Isomerase - (포도당 이성화 효소의 세포 고정화에 관한 연구 - I. 세포 고정화 효소의 제조와 성질 -)

  • Ahn, Byung-Yoon;Byun, Si-Myung
    • Korean Journal of Food Science and Technology
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    • v.11 no.3
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    • pp.192-199
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    • 1979
  • With cells of Streptomyces spp K-45 isolated from soil, the immobilization of glucose isomerase by a series of treatments ; heat, carefully manipulated drying, extrusion with a thickening agent, and glutaraldehyde-induced crosslinking, was presented. This was aimed to obtain a mechanically stable form of whole cell containing glucose isomerase. The resulted pellet form had a good mechanical strength, compared with a commercial product, and showed 26 % of the activity recovery. The specific activity was 48.1 units per g of the dry material. The immobilized glucose isomerase generally showed properties similar to those of the soluble enzyme ; optimal pH at $7.5{\sim}9.0$, optimal temperature at $80{\sim}85^{\circ}C$, activation energy of 10.9 kcal/mole, and $K_m$ for glucose of 10.9M. The immobilized enzyme was very thermostable and pH stable.

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The Preparation and Characteristics of Covalently Cross-Linked SPEEK/Cs-TPA/Ceria Composite Membranes for Water Electrolysis (수전해용 공유가교 SPEEK/Cs-TPA/Ceria 복합막의 제조 및 특성 연구)

  • Song, Minah;Ha, Sungin;Park, Deayong;Ryu, Cheolhwi;Moon, Sangbong;Kang, Ansoo;Chung, Janghoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.437-447
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    • 2012
  • Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted tungstophosphoric acid (Cs-TPA) with cross-linking agent contents of 0.01 mL. In conclusion, CL-SPEEK/Cs-TPA/ceria (1%) membrane showed the optimum results such as 0.130 S/cm of proton conductivity at $80^{\circ}C$, 2.324 meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 65.03 MPa of tensile strength which were better than Nafion 117 membrane.

Manufacturing of Sintered Lightweight Aggregate using Paper Mill Sludge Ash (제지 슬러지 소각재를 이용한 소성 경량골재의 제조)

  • 문경주;김재신;소양섭
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.114-122
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    • 2001
  • The purpose of this study was to manufacture sintered lightweight aggregate using paper sludge ash and to evaluate the qualities of the aggregate according to various mix proportions, conditions of pelletization and sintering. The paper sludge ash alone, due to its mineral and chemical compositions could not gain suitable expansion and strength. Hence, it was essential to add mineral additives such as clay, fly ash etc. The optimum muting ratio range determined in this study is as follows , paper sludge ash 30∼50 %, clay 30∼50 %, fay ash 0∼40 %, Paper sludge 0∼10% and hematite 2∼3 %(for manufacturing lightweight aggregate both for non-structural and structural concrete). It was possible to manufacture various lightweight aggregate whose dry specific gravity ranged about from 0.6 to 1.4 by using this optimum mixing ratio. From the test results of the qualities of aggregate, it showed that the 10% granules crushing value test and water absorption percentage ranged about 5∼10 ton and 10∼20%. Thus, it was favorably comparable to those of the imported aggregate. The manufactured lightweight aggregate could be used for structural concrete and non-structural concrete.

Proposals for Revision of Lightweight Aggregate Concrete Specifications Based on In-situ Quality Control on Concrete (현장 품질관리를 고려한 경량골재 콘크리트의 시방서 개정안에 대한 고찰)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.211-218
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    • 2018
  • This study examined the reliability and revision necessity of concrete standard specifications based on the comparisons with test data obtained by using domestic artificial lightweight aggregates and the contents specified in different foreign specifications including ACI 211.2, ACI 213, ACI 301, JASS 5 and CEB-FIP. To achieve the continuous particle distribution of domestic fine lightweight aggregates, the partial addition of natural sand with the maximum size of 2.5mm was required. To control the segregation and excessive bleeding in the fresh lightweight concrete, the current limitations on the water-to-binder ratio and unit water content need to be modified using lower values. In particular, a rational mixture proportion approach of lightweight concrete needs to be established for the targeted requirements of initial slump, 28-day compressive strength, air content and dry unit weight. Ultimately, significant revision of the concrete standard specifications is required considering the characteristics of domestic artificial lightweight aggregates.

Investigation of Reclamation for Waste $CO_2$ Mold Sand of Steel Foundries in Busan and Gyeong Area (부산 ${\cdot}$ 경남지역 주강 공장의 $CO_2$ 주형 고사의 발생실태와 재생에 관한 연구)

  • Choi, Jun-Oh;Kim, Min-Seop;Choi, In-Seok;Cheon, Byung-Wook;Choi, Chang-Ock
    • Journal of Korea Foundry Society
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    • v.22 no.3
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    • pp.121-129
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    • 2002
  • According to the investigation of waste $CO_2$ molding sand in the 15 steel foundries in Busan and Gyeong area, about 1 ton of waste $CO_2$ molding sand per ton of steel castings production was produced In order to reduce amount of $Na_2O$, Loss of Boiling (L.O.B), Loss of Ignition (L.O.I), Conductivity and PH which are present in the waste $CO_2$ molding sand below the reclamation effect, more than 50% of elimination for reclamation was required. It was found that the waste $CO_2$ molding sand does not contain a harmful component designated by industrial waste materials. Reclamation of the waste $CO_2$ molding sand was practically achieved by an abrasive-dry reclamation process. According to bench time of the sodium silicate-bonded $CO_2$ molding sand, reduction of compressive strength and surface stability index(S.S.I) become slowdown. Therefore, the reclaimed sand could be allowed the reuse of molding sand in $CO_2$ molding process including core sand.

Preparation and Properties of Poly(vinyl alcohol)/Chitosan Blend Films (폴리(비닐 알코올)/키토산 블렌드 필름의 제조 및 특성)

  • 정민기;김대선;최용혁;손태원;권오경;임학상
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.253-262
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    • 2004
  • Poly(vinyl alcohol)(PVA)/chitosan blend films with non-toxicity, biodegradability, and biocom-patibility were prepared by solution casting. Variation of the physicochemical properties of the blend films was investigated through to several analysis methods. Examination of antibacterial properties revealed that bacterio-static ratios of all blend samples containing chitosan more than 10 wt% were greater than 99.9%. Moisture regain was increased with increasing chitosan content but the degree of swelling was decreased. Up to chitosan content 15 wt%t, the melting and crystallization temperature of blend films was increased with chitosan content. The blends containing chitosan content 10 and 15 wt% gave melting temperature 229 and 228$^{\circ}C$, respectively. However, the melting temperature was decreased if chitosan content exceeded 20 wt%. The mechanical properties of the blend films were increased with increasing chitosan content in both dry and wet states. The blend film including 15 wt% chitosan exhibited unusually high tensile strength.

Effects of Replacing Corn with Rice or Brown Rice on Laying Performance, Egg Quality, and Apparent Fecal Digestibility of Nutrient in Hy-Line Brown Laying Hens

  • Kim, Chan Ho;Park, Seong Bok;Kang, Hwan Ku
    • Korean Journal of Poultry Science
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    • v.43 no.2
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    • pp.97-103
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    • 2016
  • This study aimed of effects of replacing maize with rice or brown rice on laying performance, egg quality, and apparent fecal digestibility of nutrient in Hy-Line Brown laying hens. A total of 200, 25-week old Hy-Line Brown laying hens were randomly assigned to one of 5 treatments, each of which was replicated 4 times. Four experimental diets that were formulated two different grains (brown rice or rice) with two inclusion levels of (15 and 30%) as a replacement of maize. The experimental period was 8 weeks. During the experiment, hens were provided with feed and water ad libitum and were exposed to a 16:8=L:D lighting schedule. There were no differences in feed intake, egg weight, and egg mass during the 8 weeks of the feeding trial among groups. However, hen-day egg production was greater (P<0.05) for Brown rice treatment groups than that for basal and rice treatment groups. In addition, the supplementation of brown rice or rice did not have an effect on eggshell strength, eggshell thickness, and HU during of the feeding trial (Table 4). However, egg yolk color was less (P<0.05) for basal treatment groups than that for among treatment group. ATTD of dry matter (DM) and crude fat were greater (P<0.05) for brown rice 15 treatment than for rice 30 treatment. Crude protein (CP) was greater (P<0.05) for brown rice 15 treatment than for basal treatment. In conclusion, brown rice or rice grains is a good alternative energy feedstuff and can be used in laying hens, totally replacing maize, without any negative effect on the laying performance, egg quality, and nutrient digestibility.

Fundamental Study of Manufacture Possibility and Composition Ratio of Sludge-Particle Board (슬러지-파티클 보드의 제조(製造) 가능성(可能性) 및 구성비율(構成比率)에 관한 기초연구(基礎硏究))

  • Lee, Phil-Woo;Yoon, Hyoung-Un;Kim, Dae-Jun;Son, Jung-Il
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.57-65
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    • 1993
  • The aim of this research was to manufacture sludge-particle board using paper sludge with wood particle and to investigate physical and mechanical properties of various sludge-particle boards, fabricated with ratios of sludge to particle of 10 to 90, 20 to 80, 30 to 70, 40 to 60 and 50 to 50(oven dry weight based). Sludge-particle boards were manufactured by urea-formaldehyde resin, 0.8 target specific gravity, and 10mm thickness. It was possible to manufacture sludge-particle board as the same processing in the present particleboard manufacturing system. This sludge-particle board have different properties as composition ratios of sludge and particle. And sludge-particle board made from 10 percent to 20 percent of sludge mixing ratio have similar mechanical properties compared with control particleboard. Especially, the sludge-particle board made from 10 percent to 40 percent mixing ratios of sludge have superior to control particleboard in internal bond, screw withdrawal holding strength and modulus of elasticity. In the case of dimensional stability, water absorption was increased and thickness swelling was decreased as increased with sludge mixing proportion. The sludge-particle board made of different mixing ratios of our laboratory design was able to concluded that there is possibility of partial substitution of wood particle materials.

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Covalent Coupling of ${\beta}-Fructofuranosidase$ on Microbial Cells (미생물 세포에 공유결합으로 고정화시킨 ${\beta}-Fructofuranosidase$에 관한 연구)

  • Uhm, Tai-Boong;Byun, Si-Myung
    • Korean Journal of Food Science and Technology
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    • v.16 no.3
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    • pp.267-272
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    • 1984
  • ${\beta}-Fructofuranosidase$ was immobilized covalently on the oxidized microbial wall of a Penicillium spp. 'PS-8', which is totally different from the conventional whole cell immobilization in concept. The immobilization of ${\beta}-fructofuranosidase$ by a series of treatments; oxidation of microbial cells with sodium metaperiodate, enzyme loading on the oxidized cells, extrusion, and crosslinking induced by glutaradehyde, were carried out. The final product had a good mechanical strength and showed 26% of the applied enzyme activity. The specific activity was 750 units per g of the dry cell product. The immobilized enzyme showed the kinetic parameters as follows; optimum pH at 5, optimum temperature at $55^{\circ}C$, activation energy of 19 kJ $mol^{-1}$, and apparent Km of 55 mM.

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