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http://dx.doi.org/10.7316/KHNES.2014.25.1.001

Research of Characterization of Covalently Cross-linked SPEEK/Cs-Substituted MoPA/Ceria 1wt% Composite Membrane for Water Electrolysis  

Park, Daeyoung (Department of chemistry, Myongji Univ.)
Hwang, Sungha (Department of chemistry, Myongji Univ.)
Oh, Seunghee (Department of chemistry, Myongji Univ.)
Yoon, Daejin (Department of chemistry, Myongji Univ.)
Kang, Ansoo (Department of engineering chemistry, Myongji Univ. Yongin Campus)
Moon, Sangbong (Elchem Tech Co., Ltd.)
Chung, Janghoon (Department of chemistry, Myongji Univ.)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.25, no.1, 2014 , pp. 1-10 More about this Journal
Abstract
Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted phophomolybdic acid(Cs-MoPA) with cross-linking agent contents of 0.01mL. In conclusion, CL-SPEEK/$Cs_{(2.5)}$-MoPA/ceria(1%) membrane showed the optimum results such as 0.1095S/cm of proton conductivity at $80^{\circ}C$, 2.906meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 49.73MPa of tensile strength which were better than Nafion 117 membrane.
Keywords
Ceria (Cerium(IV) oxide); Cs-MoPA(Cs-substituted MoPA); Oxidative durability; radical scavenger; SPEEK; PEMWE;
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Times Cited By KSCI : 1  (Citation Analysis)
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