• Title/Summary/Keyword: Dissolved carbon

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A Study on the Reaction-Stoichiometry of Autotrophic Denitrification based on Growth Characteristic of Microorganism (미생물 성장 특성에 기초한 독립영양탈질의 화학양론식 연구)

  • Lee, Su-Won;Kim, Gyu-Dong;Choi, Young-Gyun;Kim, Dong-Han;Chung, Tai-Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.121-127
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    • 2004
  • It is necessary to supply external carbon source for enhancement of biological nitrogen removal from domestic wastewater with low influent C/N ratio. Sulfide was chosen as a cost effective electron donor and reaction stoichiometry for autotrophic denitrification was investigated by conducting bench-scale experiments in this study. Higher sulfur to nitrogen (S/N) ratio than the calculated value from theoretical reaction stoichiometry was required when the anoxic reactor was operated at open condition because dissolved oxygen introduced by surface aeration reacted with sulfide with ease. In addition, higher sulfate production and lower yield of microorganism could be observed under the same condition. It was possible to obtain reliable reaction stoichiometry for autotrophic denitrification by establishing pure anoxic condition. Linear relationship between bacterial growth and consumption of nitrate, sulfide, alkalinity, and sulfate production enabled to derive a relatively correct reaction stoichiometry for autotrophic denitrification when sulfide was used as an electron donor.

Removal of NOM in a Coagulation Process Enhanced by Modified Clay (개질 Clay를 첨가한 응집공정에서의 자연유기물 제거)

  • Park, Ji-Hye;Lee, Sang-Yoon;Park, Hung-Suck
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.37-46
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    • 2007
  • A feasibility test was conducted to evaluate the addition of turbidity substance in a coagulation process to remove natural organic matters (NOM), the precursor of disinfection by-products (DBPs). The experimental water sources were synthetic water containing 5 mg/L of humic acid and 50 mg/L of NaHCO3 and drinking water resource of Ulsan city (S Dam water, D Dam water and Nak-Dong raw water). The examined turbidity substances were kaolin, acid clay, and modified clay (0.38 meq $NH_4{^+}-N/g$ clay). In Jar tests at different concentrations of the turbidity substances (5, 10, 15, 20, 30 mg/L) using the synthetic water, the turbidity substances improved the removal of turbidity, UV-254 absorbance and dissolved organic carbon (DOC) by 23.8-38.1%, 17.0-24.5% and 2.5-44.5%, respectively. The modified clay showed higher removal efficiencies than other substances. In Jar tests using the drinking water, 10 and 20 mg/L of modified clay enhanced the removal efficiencies of turbidity, UV-254 absorbance, DOC, trihalomethane formation potential (THMFP), and haloacetic acid formation potential (HAAFP) by 3.0~4.3%, 19.1~29.0%, 12~34.9%, 4.9~36.7%, and 1.6~30.2%, respectively.

The effect of iron ions on the reducing of natural organic matter and THMFP in ozonation (오존 처리 시 철 2가 이온이 자연유기물질과 트리할로메탄 저감에 미치는 영향)

  • Kwak, Yeonwoo;Lee, Seulki;Jang, Gyuhwan;Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.6
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    • pp.447-456
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    • 2019
  • This study focused on natural organic matter and trihalomethane removal by ozonation with various ferrous concentration in surface water. Ozonation is more affected by injection concentration than reaction time. dissolved organic carbon removal rates in ozonation increased with the increase in ferrous concentration. The highest removal was obtained at 6 mg/L of ferrous concentration. When 1 mg/L of ferrous was added with 2 mg/L of ozone concentration, it was found to be a rapid decrease in specific ultraviolet absorbance at the beginning of the reaction because ferrous acts as a catalyst for producing hydroxyl radical in ozonation. As ozone concentration increased, trihalomethane formation potential decreased. When 2 mg/L of ozone was injected, trihalomethane formation potential was shown to decrease and then increase again with the increase in ferrous concentration.

13C-NMR Spectroscopy of Urea-Formaldehyde Resin Adhesives with Different Formaldehyde/Urea Mole Ratios

  • Park, Byung-Dae;Lee, Sang M.;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.2
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    • pp.63-72
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    • 2008
  • As a part of abating formaldehyde emission of urea-formaldehyde (UF) resin adhesive, this study was conducted to investigate chemical structures of UF resin adhesives with different formaldehyde/urea (F/U) mole ratios, using carbon-13 nuclear magnetic resonance ($^{13}C$-NMR) spectroscopy. UF resin adhesives were synthesized at four different F/U mole ratios such as 1.6, 1.4, 1.2, and 1.0 for the analysis. The analysis $^{13}C$-NMR spectroscopy showed that UF resin adhesives with higher F/U mole ratios (i.e., 1.6 and 1.4) had two distinctive peaks, indicating the presence of dimethylene ether linkages and methylene glycols, a dissolved form of free formaldehyde. But, these peaks were not detected at the UF resins with lower F/U mole ratios (i.e., 1.2 and 1.0). These chemical structures present at the UF resins with higher F/U mole ratios indicated that UF resin adhesive with higher F/U mole ratio had a greater contribution to the formaldehyde emission than that of lower F/U mole ratio. Uronic species were detected for all UF resins regardless of F/U mole ratios.

Study of Cytotoxicity of an Actinomycete Isolated in Korea (토양에서 분리한 방선균의 세포 독성에 관한 연구)

  • Park, Joon-Koo;Choi, Boung-Don;Kim, Seung-Chul;Ryeom, Kon
    • Environmental Analysis Health and Toxicology
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    • v.8 no.3_4
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    • pp.7-12
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    • 1993
  • An Actinomycete strain isolated from Mt. Dea-Dun had a strong antifungal activity. The culture brith produced by isolated strain showed only antifungal activity against fungi with the exception of yeast and bacteria. It was heat stable, dissolved in ehtylacetate. The concentrated antifungal agent showed cytotoxicity against HEP-2 and HeLa as tumor cell line, and showed weak cytotoxicity against VERO 36 as normal cell line. Morphological and physiological characteristics were tested with isolated strain. The spore color of isolated strain was gray. It had a short chain and produced brown colored lytic substance in yeast extract-malt agar. The cell wall of isolated strain was composed of meso-DAP, and we suggested it as genus Actinomadura. In the existing of chemical inhibitor, isolated strain grew on the condition of 0.0001% crystal violet, 0.1% phenol, 0.01% sodium azide and 10% sodium chloride. Carbon utilization of isolated strain was shown that glucose, sucrose, manitol and sodium citrate were well utilized.

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Oxidation of Cr2AlC Carbides at 700-1000℃ in Air (Cr2AlC 탄화물의 700-1000℃에서의 대기중 산화)

  • Won, Sung Bin;Hwang, Yeon Sang;Lee, Dong Bok
    • Journal of Surface Science and Engineering
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    • v.47 no.2
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    • pp.93-98
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    • 2014
  • The $Cr_2AlC$ carbides oxidized at 700, 850 and $1000^{\circ}C$ in air from 70 hours up to 360 days. They oxidized according to the reaction; $Cr_2AlC+O_2{\rightarrow}{\alpha}-Al_2O_3+CO(g)$. The scales consisted primarily of the thin, essentially pure $Al_2O_3$ layer and the underlying Al-dissolved $Cr_7C_3$ layer. They grew via the outward diffusion of Al and carbon, and the inward diffusion of oxygen. The oxidation resistance of $Cr_2AlC$ was excellent due to the formation of the protective $Al_2O_3$ layer. Even when $Cr_2AlC$ oxidized at $1000^{\circ}C$ for 360 days, the ${\alpha}-Al_2O_3$ layer was only about 4 ${\mu}m$-thick.

Production of Antifungal Lipopeptide Iturin by Bacillus subtilis (Bacillus subtilis로부터 항진균 리포펩타이드 물질 Iturin의 생산)

  • 손광현;이항우
    • KSBB Journal
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    • v.9 no.2
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    • pp.224-229
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    • 1994
  • Iturin, an antifungal lipopeptide, fermentation by Bacillus subtilis was investigated focusing on the effeats of nutrients aeration and specific cell growth rate on iturin production. Cell growth and product formation were not affected by different kinds of carbon sources such as sucrose, glucose and fructose. Soytone concentration above 20g/$\ell$ did not influence iturin production. Diauxic growth pattern appeared when only soytone was used as a sole nitrogen source probably due to the shortage of amino acids and/or peptides in soytone which could be favorably assimilated by the cells. The composition of three major components in iturin was not changed significantly by the variation of dissolved oxygen concentration of the culture broth but changed substantially by the change of specific growth rate of the cells.

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A Study on the Stream Pollution Analysis (하천오염분석에 관한 연구)

  • 김건흥
    • Water for future
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    • v.19 no.4
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    • pp.321-328
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    • 1986
  • Bottom sediment-river water samples were studied to determine the extent of biodegradable matter and to examine the reduction of COD, TKN and TOC by using of warburg and aerated batch reactor. Warburg studies were conducted to study the Oxygen Uptake Rates, Reaction Rate Constants and CBOD. Bacth reator studies were conducted to determine the reduction of COD, TKN and TOC. Results from the batch recator study indicate high concentration of COD in samples. Less than 10 precent of the Organic Carbon was found to be biodegradable in 48 hours of Warburg experiment. Appreciable Immediate Oxygen Demand of sediments suggests that dredging of the river bottom is likely to deplete dissolved significantly in the river water.

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Enhanced Production of Maltotetraose-producing Amylase by Recombinant Bacillus subtilis LKS88 in Fed-batch Cultivation

  • KIM, DAE-OK;KYUNGMOON PARK;JAE-WOOK SONG;JIN-HO SEO
    • Journal of Microbiology and Biotechnology
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    • v.7 no.6
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    • pp.417-422
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    • 1997
  • Recombinant Bacillus subtilis LKS88[pASA240] containing the amylase gene from Streptomyces albus KSM-35 was exploited in fed-batch cultivation for mass production of maltotetraose-producing amylase. The effects of dissolved oxygen, additional organic nutrients (peptone and yeast extract) and mixed carbon sources (glucose plus soluble starch) on amylase production were examined in fed-batch operations in an effort to determine the optimum conditions for a maximum amylase productivity. Under the optimum conditions, maximum amylase activity was about 4.2 times higher than that obtained in batch cultivations, indicating that mass production of maltotetraose-producing amylase could be accomplished in fed-batch cultivation of the recombinant B. subtilis strain.

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Fabrication and Characterization of Cf/SiC Composite with BN Interphase Coated by Wet Chemical Process (습식법으로 제조된 BN 중간층을 가진 Cf/SiC 복합재의 제조 및 물성 평가)

  • Koo, Jun-mo;Kim, Kyung Ho;Han, Yoonsoo
    • Journal of Surface Science and Engineering
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    • v.50 no.6
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    • pp.523-530
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    • 2017
  • In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.