• Title/Summary/Keyword: Dispersion property

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Uniform PMMA-CH3NH3PbBr3 Nanoparticle Composite Film for Optoelectronic Application

  • Kirakosyan, Artavazd;Yun, Seokjin;Choi, Jihoon
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.307-311
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    • 2017
  • Organometal halide perovskite materials, due to the tunability of their electronic and optical properties by control of composition and structure, have taken a position of significant importance in optoelectronic applications such as photovoltaic and lighting devices. Despite numerous studies on the structure - property relationship, however, practical application of these materials in electronic and optical devices is still limited by their processability during fabrication. Achieving nano-sized perovskite particles embedded in a polymer matrix with high loading density and outstanding photoluminescence performance is challenging. Here, we demonstrate that the careful control of nanoparticle formation and growth in the presence of poly(methyl methacrylate) results in perovskite nanoparticle - polymer nanocomposites with very good dispersion and photoluminescence. Furthermore, this approach is found to prevent further growth of perovskite nanoparticles, and thus results in a more uniform film, which enables fabrication using the perovskite nanoparticles.

Tribological Characteristics of Carbon Nanotube Aluminum Composites According to Fabrication Method and Content of Carbon Nanotube (알루미늄탄소나노튜브 복합재의 가공 방법과 탄소나노튜브 함량에 따른 트라이볼로지 특성)

  • Lee, Young-Ze;Lee, Jung-Hee;Kim, Il-Young;Lee, Gyu-Sun;Baik, Seung-Hyun;Youn, Jeong-Il;Kim, Young-Jig
    • Tribology and Lubricants
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    • v.24 no.5
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    • pp.269-274
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    • 2008
  • Carbon nanotube composite is considered to be a good candidate material for composite material because of its excellent mechanical property and low density under high temperature as well as good wear and frictional properties. In this study, tribological characteristics of carbon nanotube aluminum composite were evaluated using pin-on-disk wear tester. Spark Plasma Sintering method is more effective than Hot Pressing method in terms of wear and friction. The composite with 1% CNT has the lowest friction and wear characteristic.

A Study on the Wear Behavior of the Cu-TiB2 Composites (Cu-TiB2 복합재료의 마모거동에 관한 연구)

  • Kim Jung-Nam;Choi Jong-Un;Kang Kae-Myung
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.61-65
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    • 2005
  • The titanium $diboride(TiB_2)$ has high strength(750MPa), high melting point $(3225^{\circ}C)\;and\;10\%$ IACS electrical conductivity. On this account, the dispersion hardening $Cu-TiB_2$ composites(MMCs) are a promising candidate for applications as electrical contact materials. MMCs for electrical contact materials can reduce material cost and resource consumption caused by wear, due to its good mechanical and electrical property. In this study, we attempt to prepare MMCs with various volume fraction and particle size of $TiB_2$ by means of hot extruded and cold drawn process. Dry sliding wear tests were performed on a pin-on-disk type wear tester, sliding against SM45C under the different applied loads. After wear testing, the microstructures of the worn surfaces were observed by SEM and the microhardnesses of the subsurface zone were measured.

Evolution on Microstructures and Tensile Properties of 10Cr-1Mo ODS Steel with Different Lengths of Mechanical Alloying Process Times (10Cr-1Mo 산화물 분산강화 강의 미세조직과 인장특성에 미치는 기계적 합금화 공정시간의 영향)

  • Noh, Sanghoon;Kim, Tae Kyu
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.375-380
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    • 2021
  • In this study, we investigate the effect of the duration of mechanical alloying on the microstructures and mechanical properties of ODS ferritic/martensitic steel. The Fe(bal.)-10Cr-1Mo pre-alloyed powder and Y2O3 powder are mechanically alloyed for the different mechanical alloying duration (0 to 40 h) and then constantly fabricated using a uniaxial hot pressing process. Upon increasing the mechanical alloying time, the average powder diameter and crystallite size increased dramatically. In the initial stages within 5 h of mechanical alloying, inhomogeneous grain morphology is observed along with coarsened carbide and oxide distributions; thus, precipitate phases are temporarily observed between the two powders because of insufficient collision energy to get fragmented. After 40 h of the MA process, however, fine martensitic grains and uniformly distributed oxide particles are observed. This led to a favorable tensile strength and elongation at room temperature and 650℃.

A study on Natural Disaster Prediction Using Multi-Class Decision Forest

  • Eom, Tae-Hyuk;Kim, Kyung-A
    • Korean Journal of Artificial Intelligence
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    • v.10 no.1
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    • pp.1-7
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    • 2022
  • In this paper, a study was conducted to predict natural disasters in Afghanistan based on machine learning. Natural disasters need to be prepared not only in Korea but also in other vulnerable countries. Every year in Afghanistan, natural disasters(snow, earthquake, drought, flood) cause property and casualties. We decided to conduct research on this phenomenon because we thought that the damage would be small if we were to prepare for it. The Azure Machine Learning Studio used in the study has the advantage of being more visible and easier to use than other Machine Learning tools. Decision Forest is a model for classifying into decision tree types. Decision forest enables intuitive analysis as a model that is easy to analyze results and presents key variables and separation criteria. Also, since it is a nonparametric model, it is free to assume (normality, independence, equal dispersion) required by the statistical model. Finally, linear/non-linear relationships can be searched considering interactions between variables. Therefore, the study used decision forest. The study found that overall accuracy was 89 percent and average accuracy was 97 percent. Although the results of the experiment showed a little high accuracy, items with low natural disaster frequency were less accurate due to lack of learning. By learning and complementing more data, overall accuracy can be improved, and damage can be reduced by predicting natural disasters.

Artificial neural fuzzy system and monitoring the process via IoT for optimization synthesis of nano-size polymeric chains

  • Hou, Shihao;Qiao, Luyu;Xing, Lumin
    • Advances in nano research
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    • v.12 no.4
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    • pp.375-386
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    • 2022
  • Synthesis of acrylate-based dispersion resins involves many parameters including temperature, ingredients concentrations, and rate of adding ingredients. Proper controlling of these parameters results in a uniform nano-size chain of polymer on one side and elimination of hazardous residual monomer on the other side. In this study, we aim to screen the process parameters via Internet of Things (IoT) to ensure that, first, the nano-size polymeric chains are in an acceptable range to acquire high adhesion property and second, the remaining hazardous substance concentration is under the minimum value for safety of public and personnel health. In this regard, a set of experiments is conducted to observe the influences of the process parameters on the size and dispersity of polymer chain and residual monomer concentration. The obtained dataset is further used to train an Adaptive Neural network Fuzzy Inference System (ANFIS) to achieve a model that predicts these two output parameters based on the input parameters. Finally, the ANFIS will return values to the automation system for further decisions on parameter adjustment or halting the process to preserve the health of the personnel and final product consumers as well.

Performance Characteristics of Organic Electroluminescence Diode Using a Carbon Nanotube-Doped Hole Injection Layer (탄소 나노튜브가 도입된 정공 주입층에 의한 유기발광다이오드의 성능 특성 연구)

  • Kang, Hak-Su;Park, Dae-Won;Choe, Youngson
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.418-423
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    • 2009
  • MWCNT(multi-wall carbon nanotube)-doped PEDOT:PSS(poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)), used as a HIL(hole injection layer) material in OLEDs(organic light emitting diodes), was spin-coated on to the ITO glass to form PEDOT:PSS-MWCNT nano composite thin film. Morphology and transparency characteristics of nano composite thin films with respect to the loading percent of MWCNT have been investigated using FT-IR, UV-Vis and SEM. Furthermore, ITO/PEDOT:PSS-MWCNT/NPD/$Alq_3$/Al devices were fabricated, and then J-V and L-V characteristics were investigated. Functional group-incorporated MWCNT was prepared by acid treatment and showed good dispersion property in PEDOT:PSS solution. PEDOT:PSS-MWCNT thin films possessed good transparency property. For multi-layered devices, it was shown that as the loading percent of MWCNT increased, the current density increased but the luminance dramatically decreased. It might be conclusively suggested that the enhanced charge mobility by MWCNT could increase the current density but the hole trapping property of MWCNT could dramatically decrease the hole mobility in the current devices.

Effect of Fluorination of Carbon Nanotubes on Physico-chemical and EMI Shielding Properties of Polymer Composites (고분자 복합재의 물리화학적 및 전자파차폐 특성에 미치는 탄소나노튜브의 불소화 영향)

  • Lee, Si-Eun;Kim, Doyoung;Lee, Man Young;Lee, Min-Kyung;Jeong, Euigyung;Lee, Young-Seak
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.114-121
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    • 2015
  • Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.

Emulsifying Properties of Concentrated Red Ginseng Extract: Influence of Concentration, pH, NaCl (홍삼농축액 함유 유화액의 유화특성에 관한연구)

  • You, Kawn-Mo;Jang, Hyeon-Ho;Lee, Eui-Seok;Lee, Ki-Teak;Hong, Soon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.504-514
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    • 2017
  • This study was carried out to investigate the emulsifying properties of concentrated red ginseng extract (CRGE). First, we determined the interfacial tension of CRGE at the oil-water interface. Second, oil-in-water emulsions were prepared with CRGE and then their physicochemical properties such as fat globule size, zeta-potential, dispersion stability, and microscopic characteristics were determined. It was found that interfacial tension gradually decreased with increasing CRGE concentration, indicative of some surface activity. In emulsions, fat globule size was decreased as CRGE concentration increased, showing a critical value ($d_{43}$$0.39{\mu}m$) at ${\geq}3.5wt%$ of CRGE. In addition, pH and NaCl also influenced on fat globule sizes; they were increased in acidic conditions ($pH{\leq}3$) or in higher NaCl concentration (${\geq}0.4M$) and these results were interpreted in view of the change in zeta potentials. The dispersion stability by separation analyzer ($LUMiFuge^{(R)}$) showed that it was more stable in emulsions with higher CRGE concentration (i.e., ${\geq}3.5wt%$). In conclusion, CRGE was surface-active and it could be used as an emulsifier in preparation of food emulsions.

Enhancement for Magnetic Property of Ba-ferrite for Perpendicular Magnetic Recording Using Ultrasonic Dispersion (초음파 분산에 의한 수직자기기록용 Ba-ferrite의 자기적 특성 향상)

  • Choi, Hyun-Seung;Kim, Chang-Gon;Jang, Hak-Jin;Jung, Ji-Hyung;Yoon, Seog-Young;Kim, Tae-Ok
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.758-763
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    • 2002
  • The various ultrasonic energies (28 kHz, 40 kHz, 70 kHz) were used to improve the magnetic properties of Ba-ferrite as the perpendicular magnetic recording materials. In the sheet formation process, the different orientation hars were used to orientate perpendicularly the dispersed Ba-ferrite to sheet. Throughout these experiments, we have obtained relatively higher value of S. Q. (Squreness Ratio : 0.783) and O. R. (Orientation Ratio : 2.87) magnetic properties at 2 h ultrasonic treatment of 40 kHz ultrasonic energy. With aid of SEM(Scanning Electron Microscopy) images, the obtained sheet with dispersed of Ba-ferrite could be used for perpendicular magnetic recording due to orientated to easy magnetization axis, c-axis. In addition, the value of S. Q. of sheet decreased with increasing applied magnetic field angle during measuring of S. Q. value with changing applied magnetic field angle by VSM (Vibrating Sample Magnetrometer). This result also induced the probability for prependicular magnetic recording.