• Title/Summary/Keyword: Dispersion force

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Group Contribution Method for Group Contribution Method for Estimation of Vapor Liquid Equilibria in Polymer Solutions

  • Oh, Suk-Yung;Bae, Young-Chan
    • Macromolecular Research
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    • v.17 no.11
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    • pp.829-841
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    • 2009
  • This study introduces a specified group-contribution method for predicting the phase equilibria in polymer solutions. The method is based on a modified double lattice model developed previously. The proposed model includes a combinatorial energy contribution that is responsible for the revised Flory-Huggins entropy of mixing, the van der Waals energy contribution from dispersion, a polar force and specific energy contribution. Using the group-interaction parameters obtained from data reduction, the solvent activities for a large variety of mixtures of polymers and solvents over a wide range of temperatures can be predicted with good accuracy. This method is simple but provides improved predictions compared to those of the other group contribution methods.

Characterizations of Cr-P-PTFE composite coatings electroplated from trivalent chromium-based bath

  • Park, Jong-Kyu;Byoun, Young-Min;Seo, Sun-Kyo;Park, Su-Young;Choi, Sun-Woo
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.455-460
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    • 2018
  • Chromium plating is a common surface treatment technique extensively applied in industry due its excellent properties which include substantial hardness, abrasion resistance, corrosion resistance, surface color, and luster. In this study, the effect of PTFE on corrosion behavior of Cr-P plating, low carbon steel substrates are electroplated in Cr(III) baths without and with PTFE. Trivalent chromium carbon plating was electroplated from trivalent chromium sulfate-based baths with different PTFE dispersion contents. The study focused on the microstructure, PTFE content, roughness, and corrosion resistance of the Cr-P-PTFE composite plating. Scanning electron microscopy and atomic force microscopy images showed a smoother plating and a decrease in the surface roughness of the electrodeposited. The results demonstrate that PTFE eliminates the cracks within plating by reducing internal stress. Therefore, the corrosion resistance of Cr-P-PTFE composite platings were better than that of Cr-P alloy platings.

Mechanical Properties of Epoxy Paints Containing Oxidized Graphene Nanoplatelet (산화 그래핀 나노플레이트릿을 혼입한 에폭시 도료의 역학적 특성)

  • Seo, Won-Woo;Kim, Gyu-Yong;Yoon, Min-Ho;Hwang, Eui Chul;Baek, Jae Uk;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.153-154
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    • 2017
  • Graphene is a nanomaterial and is known to have very high mechanical strength, thermal and electrical properties. However, graphene is known to be difficult to disperse among carbon-based materials due to van der Waals force. In this study, to solve the dispersion problem of graphene nanoplatelet, oxidized graphene nanoplatelet was prepared by oxidizing GNP in nitric acid. The prepared GO was dispersed in ethanol and distilled water before incorporation into the epoxy paint to confirm dispersibility. In addition, GNP/Epoxy and GO/Epoxy tensile specimens were prepared by mixing GNP and GO at 0.1, 0.3, 0.5 and 1.0 wt.% In epoxy coatings and tensile stress-strain characteristics were investigated.

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The Preparation of NiCuZn Ferrite Slurry Using the Water Mixed Binder System (수계 바인더를 이용한 NiCuZn Ferrite의 슬러리 제조)

  • 류병환;이정민;고재천
    • Resources Recycling
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    • v.7 no.4
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    • pp.35-42
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    • 1998
  • Surface mount technology is the biggest theme in the area of deιIronic component. To miniatunze an electronic component, s such as ferrite chip inductor, the cer뼈lic wet process for green-sheet lamination and/or screen printing method through a s solvent medium system is widely used. The preparation and characterization of NiCuZn Ferrite (NCZF) shurry and the green s sheet using the water mixed binder system has been studied. The 21 vol% of NCZF slurry was prepared by a ball milling. The p polyacrylic vinyl copolymer (Mw; 60,000) was used as a binder. Th$\xi$ mixture of distilled water, isopropyl alcohol (IPA) and 2l butoxy ethanol was used as a dispersion medium. The water content of medium varied from about 40% to 80%. As the results. Thc disp$\xi$rston stability of the NCZF slurry was attributed to the free polymer rather than the electrostatic force of the particle. T The viscosity of the NCZF slurry was greatly depended on the ratio of water content in the medium.

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Effect of Nanomesh Structure Variation on the Friction and Wear Characteristics of Carbon Nanotube Coatings (탄소나노튜브 코팅의 마찰/마모 특성에 대한 나노메쉬 구조의 영향)

  • Kim, Hae-Jin;Kim, Chang-Lae
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.315-319
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    • 2020
  • In various fields, several studies based on carbon nanotubes (CNTs) have been conducted. The results of previous studies, wherein CNT coatings have been incorporated as solid lubricants, demonstrate that the friction and wear characteristics of CNT coatings can be improved through the absorption/dispersion of the contact pressure by controlling the stiffness of the nanomesh structure comprising CNT strands. In this study, the friction and wear characteristics of the following are compared: CNT coating formed by spin coating of CNT solution, compressed CNT coating, and compressed/heated CNT coating (wherein CNT strands are squeezed through compression and/or heating). It is observed that the friction coefficient of the CNT coating having the largest number of voids between the CNT strands is significantly lower than those of the compressed CNT coating and the compressed/heated CNT coating. The wear tracks of the compressed CNT coating and the compressed/heated CNT coating indicate that some parts become torn or adhere into a lump. However, in the case of the CNT coating, a smooth wear surface is formed by rubbing. Furthermore, as the void space between the squeezed and adhered CNT strands decreases, the resistance to structural deformation increases, thereby resulting in an increased frictional force and a wear pattern that becomes torn or forms a lump. Hence, the results obtained from this study corroborate that the friction and wear characteristics of CNT coatings can be enhanced through the absorption/dispersion of the contact pressure by controlling the stiffness of the nanomesh structure of CNT coatings.

THREE DIMENSIONAL FINITE ELEMENT STRESS ANALYSIS OF IMPLANT PROSTHESIS ACCORDING TO THE DIFFERENT FIXTURE LOCATIONS AND ANGULATIONS (임플랜트 지지 보철물에서 고정체의 식립위치와 각도에 따른 삼차원 유한요소법적 응력분석에 관한 연구)

  • Park Won-Hee;Lee Young-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.43 no.1
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    • pp.61-77
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    • 2005
  • Statement of problem. The implant prosthesis has been utilized in various clinical cases thanks to its increase in scientific effective application. The relevant implant therapy should have the high success rate in osseointegration, and the implant prosthesis should last for a long period of time without failure. Resorption of the peri-implant alveolar bone is the most frequent and serious problem in implant prosthesis. Excessive concentration of stress from the occlusal force and biopressure around the implant has been known to be the main cause of the bone destruction. Therefore, to decide the location and angulation of the implant is one of the major considering factors for the stress around the implant fixture to be dispersed in the limit of bio-capacity of load support for the successful and long-lasting clinical result. Yet, the detailed mechanism of this phenomenon is not well understood. To some extent, this is related to the paucity of basic science research. Purpose. The purpose of this study is to perform the stress analysis of the implant prosthesis in the partially edentulous mandible according to the different nature locations and angulations using three dimensional finite element method. Material and methods, Three 3.75mm standard implants were placed in the area of first and second bicuspids, and first molar in the mandible Thereafter, implant prostheses were fabricated using UCLA abutments. Five experimental groups were designed as follows : 1) straight placement of three implants, 2) 5$^{\circ}$ buccal and lingual angulation of straightly aligned three implants, 3) 10$^{\circ}$ buccal and lingual angulation of straightly aligned three implants. 4) lingual offset placement of three implants, and 5) buccal offset placement of three implants. Average occlusal force with a variation of perpendicular and 30$^{\circ}$ angulation was applied on the buccal cusp of each implant prosthesis, followed by the measurement of alteration and amount of stress on each configurational implant part and peri-implant bio-structures. The results of this study are extracted from the comparison between the distribution of Von mises stress and the maximum Von mises stress using three dimensional finite element stress analysis for each experimental group. Conclusion. The conclusions were as follows : 1. Providing angulations of the fixture did not help in stress dispersion in the restoration of partially edentulous mandible. 2. It is beneficial to place the fixture in a straight vertical direction, since bio-pressure in the peri-implant bone increases when the fixture is implanted in an angle. 3. It is important to select an appropriate prosthodontic material that prevents fractures, since the bio-pressure is concentrated on the prosthodontic structures when the fixture is implanted in an angle. 4. Offset placement of the fixtures is effective in stress dispersion in the restoration of partially edentulous mandible.

Test Methods for Evaluation of Slip-Resistance Force of Clamp for Plastic Greenhouse (플라스틱 온실 죔쇠의 미끄럼 저항력 평가를 위한 실험 방법)

  • Choi, Man-Kwon;Song, Ho-Sung;Cho, Myeong-Whan;Yu, In-Ho;Shin, Young-An;Lim, Seong-Yoon;Ryu, Hee-Ryong
    • Journal of Bio-Environment Control
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    • v.25 no.3
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    • pp.193-199
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    • 2016
  • The research discussed experimental results on slip resistance force of rafter-purlin connection of plastic greenhouse and suggested a test method for evaluating slip resistance performance of the connection. Slip resistance forces were measured by four kinds of constraint conditions for specimens, for example, fixing or rolling the end of specimen. According to tests, it is noticed that constraint condition is able to significantly affect the slip resistance force. From a post-hoc comparison result, slip resistance force of test under fixing ends condition was larger than those under the other three constraint conditions. But the slip resistance force results in the fixing ends condition had greater measure of dispersion and three times of standard deviation than those from other constraint conditions. Based on the results obtained, effect of constraint condition for specimen on the slip test should be studied to enhance reliability of evaluation test of the slip resistance performance.

Study on GO Dispersion of PC/GO Composites according to In-situ Polymerization Method (In-situ 중합방법에 따른 폴리카보네이트(PC)/그래핀 옥사이드(GO) 복합체의 GO 분산성 연구)

  • Lee, Bom Yi;Park, Ju Young;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.336-340
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    • 2015
  • Three different types of polycarbonate (PC)/graphene oxide (GO) composites using diphenyl carbonate as a monomer were fabricated by melt polymerization. Those were the PC/GO composite (PC/GO) using a twin extruder, in-situ PC/GO composite (PC/GO-cat.) using a catalyst, and in-situ PC/GO composite (PC/GO-COCl) using a GO-COCl treated by -COCl, Chemical structures of the composites were confirmed by C-H and C=O stretching peak at $3000cm^{-1}$ and $1750cm^{-1}$, respectively. The slope for the storage (G') versus loss (G") modulus plot decreased with an increase in the heterogeneous property of polymer melts. So we can check the GO dispersion of the PC/GO composites using by the slop for G'-G" plot. According to the G'- G" slopes for three different types of PC/GO composites, GO was well dispersed within PC matrix in case of PC/GO and PC/GO-cat.. It was also confirmed by atomic force microscope (AFM) photos. One of the reasons for the poor GO dispersion of PC/GO-COCl is branching and crosslinking processes occurred during polymerization, which was further confirmed by a plot for the complex modulus versus phase difference.

Ball end milling of sculptured surface models by considering machinability (절삭성을 고려한 자유곡면 모형의 볼 엔드 밀링가공에 관한 연구)

  • 박천경;맹희영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.2048-2061
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    • 1991
  • As compared with other cutting types, the ball end milling process causes a complexity in cutting system and a falling-off of machinability. In order to increase the productivity and efficiency in th NC machining of sculptured surfaces, this study carried out the qualitative linearized evaluation about the ball end milling system and applied their practical expressions to the technological processor at the cutter path planning stage. The evaluated expressions were proved to be adequate for practical use from an accuracy point of view and the estimation models were applied to sculptured surface machining processes for finding variable machining conditions. Consequently, it was recognized that variable machining conditions bring about the dispersion of force system and the reduction of machining time by more than 50%.

The Effect of Form and Hardness of Outsoles on the Motion of the Lower Extremity Joints and on Foot Pressure during Gait (보행 시 신발의 아웃솔 형태가 하지 관절 운동과 발의 압력에 미치는 영향)

  • Kim, Eui-Hwan;Kim, Sung-Sup;Kwon, Moon-Seok;Wi, Ung-Ryang;Lim, Jung;Chung, Chae-Wook
    • Korean Journal of Applied Biomechanics
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    • v.21 no.2
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    • pp.223-230
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    • 2011
  • The purpose of this study was to analysis the effect of form and hardness of outsoles on the motion of the lower extremity joints and on foot pressure during gait. The subjects were 15 women(mean age, $48.5{\pm}2.4$ years), who had no serious musculoskeletal, coordination, balance or joint/ligament problems within 1 year prior to the study. The pelvic tilt, joint angles at the lower extremities and the vertical ground reaction force(GRF) were compared during gait with 3 types of shoes (A, B, C) by using one-way repeated ANOVA(p<.05). During gait, the peak tilt angle and the range of motion(ROM) of the ankle and knee joints were found to be significantly different among the 3 types of shoes. The type C shoes showed a significantly lower mean second maximum vertical GRF than types A and B. The curved outsoles of type C shoes, which had a form and hardness different from those of A and B, was designed strategically for walking shoes to provide stability to the Additionally, type C induced the dispersion of eccentric pressure and made the center of pressure roll over to the center line of the foot.