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Alum and Hydroxide Routes to ${\alpha}-Al_2O_3$ (I) Calculation of Solubility Diagram for Extracting the Pure Alumina from Alumino-Silicate and its Experimetal Confirmation (명반 및 수산화 알루미늄을 이용한 ${\alpha}$-Al$_2$O$_3$의 합성 (I) 규산 알루미늄광으로부터 순수한 ${\alpha}$-Al$_2$O$_3$ 추출을 위한 용해도 모델 계산 및 실험적 검증)

  • Yoo Jong-Seok;Choy Jin-Ho;Han Kyoo-Seung;Han Yang-Su;Lee Chang-Kyo;Lee Nang-Ho
    • Journal of the Korean Chemical Society
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    • v.35 no.4
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    • pp.414-421
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    • 1991
  • High-purity alumina powder was prepared by extracting the natural alumino-silicate mineral (halloysite) in H$_2$SO$_4$ solution. For the selective precipitation of alum and aluminum hydroxide, the solubility diagram was prior calculated by also considering the formation of hydroxides and carbonates for all the metal ions in an aqueous solution, which allow us to control the contamination of impurities envolved in the natural minerals. Ammonium aluminum sulfate (alum) and alumium hydroxide could be successfully prepared at pH = 1.5∼2.5 and pH = 6∼8, respectively according to our solubility diagrams. The purity of alum-and hydroxide-derived ${\alpha}-Al_2O_3$ was determined to be 99.7${\%}$ and 99.0${\%}$, respectively, which indicates the former route would be more desirable for the large scale application. It is also worthy to note that the impurities like Na and Si were strongly reduced in the former (Na = 0.05${\%}$, Si = 0.09${\%}$) compared to the latter (Na = 0.29${\%}$, Si = 0.12${\%}$).

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Geochemical Characteristics of the Jurassic Chunyang Granites in Northeastern Part of the Yeongnam Massif (영남육괴에 분포하는 쥐라기 춘양화강암의 지화학적 특성)

  • Kang, Minyoung;Kim, Yunji;Wee, Soomeen
    • Journal of the Korean earth science society
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    • v.38 no.1
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    • pp.49-63
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    • 2017
  • The geochemical results of the Chunyang granites located in the northeastern part of the Yeongnam Massif, indicate that these rocks have characteristics of calc-alkaline series in the sub-alkaline field, I-type and peraluminous. Most of the geochemical features in major and trace elements show systematic trends, which are similar to differentiation trends of the general Jurassic granitoids in South Korea. The Chunyang granite is largely enriched in mobile LILE (Sr, K, Rb and Ba) relatively immobile HFSE. They show LREE enriched patterns [$(La/Lu)_{CN}=41.8-73.2$] with a slightly negative Eu anomaly [$(Eu/Eu^*)_{CN}=0.89-1.10$]. There are no meaningful correlations in major and trace elements between the Chunyang granites and the Buseok plutonic rock which is the main unit of the Yeongju batholith. This result may suggest that these two plutonic rocks be not derived from the same parent magma. Tectonic discrimination diagrams indicate that the Chunyang granite was formed in volcanic arc environments. These geochemical characteristics results suggest that the Chunyang granite must have been generated at the active continental margin during the subduction of the Jurassic proto-Pacific plate.

Object Modeling for Mapping from XML Document and Query to UML Class Diagram based on XML-GDM (XML-GDM을 기반으로 한 UML 클래스 다이어그램으로 사상을 위한 XML문서와 질의의 객체 모델링)

  • Park, Dae-Hyun;Kim, Yong-Sung
    • The KIPS Transactions:PartD
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    • v.17D no.2
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    • pp.129-146
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    • 2010
  • Nowadays, XML has been favored by many companies internally and externally as a means of sharing and distributing data. there are many researches and systems for modeling and storing XML documents by an object-oriented method as for the method of saving and managing web-based multimedia document more easily. The representative tool for the object-oriented modeling of XML documents is UML (Unified Modeling Language). UML at the beginning was used as the integrated methodology for software development, but now it is used more frequently as the modeling language of various objects. Currently, UML supports various diagrams for object-oriented analysis and design like class diagram and is widely used as a tool of creating various database schema and object-oriented codes from them. This paper proposes an Efficinet Query Modelling of XML-GL using the UML class diagram and OCL for searching XML document which its application scope is widely extended due to the increased use of WWW and its flexible and open nature. In order to accomplish this, we propose the modeling rules and algorithm that map XML-GL. which has the modeling function for XML document and DTD and the graphical query function about that. In order to describe precisely about the constraint of model component, it is defined by OCL (Object Constraint Language). By using proposed technique creates a query for the XML document of holding various properties of object-oriented model by modeling the XML-GL query from XML document, XML DTD, and XML query while using the class diagram of UML. By converting, saving and managing XML document visually into the object-oriented graphic data model, user can prepare the base that can express the search and query on XML document intuitively and visually. As compared to existing XML-based query languages, it has various object-oriented characteristics and uses the UML notation that is widely used as object modeling tool. Hence, user can construct graphical and intuitive queries on XML-based web document without learning a new query language. By using the same modeling tool, UML class diagram on XML document content, query syntax and semantics, it allows consistently performing all the processes such as searching and saving XML document from/to object-oriented database.

Spectrophotometric Study of Acidity and Complex Formation of Anti-Inflammatory Drug Piroxicam with Some Transition Metal Ions in Different Methanol/Water Mixtures by Chemometric Methods (Chemometric 방법에 의한 메탄올/물 계에서 전이 금속 이온과 소염제 Piroxicam의 산성도 및 착체 형성에 관한 분광광도법 연구)

  • Ghasemi, Jahan B.;Jalalvand, Alireza
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.693-703
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    • 2009
  • The complex formation of anti-inflamatory drug piroxicam (PX, 4-hydroxy-2-methyl-N-2--pridyl-2H-1,2-benzothiazine-3-carboxadiamide-1,1-dioxide) with transition metal ions Co(II), Ni(II), Cu(II) and Zn(II) in methanol(MeOH)/water binary mixtures were studied by spectrophotometric method at 25$^{\circ}C$, constant pH = 5.0 and I = 0.1 M. The computer program SQUAD was used to extract the desired information from the spectral data. The outputs of the fitting processes were stability constants, standard deviations of the estimated stability constants, concentration distribution diagrams and spectral profiles of all species. The sequence of the stability constants of PX complexes with Co(II), Ni(II), Cu(II) and Zn(II) follow the Cu(II) > Co(II) > Ni(II) ${\approx}$ Zn(II) order. This may be due to different geometry tendencies of these metal ions. The acidity constants of the PX were also determined under above condition from its absorption spectra at different pH values. The computer program DATAN was used for determination of acidity constants of PX. The validity of the obtained acidity constants was checked by a well known computer program SPECFIT/32. The effects of the different parameters like solvent nature, cations characteristics on the stability and acidity constants were thoroughly discussed.

Energy Level Calculation of Fe3+ Paramagnetic Impurity Ion in a LiTaO3 Single Crystal (LiTaO3 단결정 내의 Fe3+ 상자성 불순물 이온에 대한 에너지 준위 계산)

  • Yeom, Tae Ho;Yoon, Dal Hoo;Lee, Soo Hyung
    • Journal of the Korean Magnetics Society
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    • v.24 no.3
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    • pp.71-75
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    • 2014
  • Ground state energy levels of the $Fe^{3+}$ paramagnetic impurity ion in stoichiometric $LiTaO_3$ and in congruent $LiTaO_3$ single crystals were calculated with electron paramagnetic resonance constants. Energy levels between six energy levels were obtained with spectroscopic splitting parameter g and zero field splitting constant D for $Fe^{3+}$ ion. The energy diagrams of $Fe^{3+}$ ion were different from different magnetic field directions ([100], [001], [111]) when magnetic field increases. The calculated ZFS energies of $Fe^{3+}$ ion in stoichiometric and congruent $LiTaO_3$ single crystals for ${\mid}{\pm}5/2$ > ${\leftrightarrow}{\mid}{\pm}3/2$ > and ${\mid}{\pm}3/2$ > ${\leftrightarrow}{\mid}{\pm}1/2$ > transitions were 12.300 GHz and 6.150 GHz, and 59.358 GHz and 29.679 GHz, respectively. It turns out that energy levels of $Fe^{3+}$ paramagnetic impurity in $LiTaO_3$ crystal are different from different crystal growing condition.

Geochemical Studies on Petrogenesis of the Cretaceous Myeongseongsan Granite in the Northwestern Gyeonggi Massif (경기육괴 북서부에 분포하는 백악기 명성산 화강암의 성인에 대한 지화학적 연구)

  • Yi, Eun Ji;Park, Ha Eun;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.327-339
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    • 2017
  • The Cretaceous Myeongseongsan Granite in the northwestern Gyeonggi Massif consists of a major pale pink-colored biotite monzogranite and a minor white-colored biotite alkaligranite. Low Sr and high Ba concentrations, negative Eu-anomalies in REE plot, negative Sr anomalies in spider diagram, a negative correlation between Sr and Rb, and positive correlations between Sr and Ba and $Eu/Eu^*$ indicate that a fractional crystallization of both plagioclase and K-feldspar played a significant role during magma evolution. The Myeongseongsan Granite is plotted in I-& S-type granites on I, S, A-type granite classification scheme. While the biotite monzogranite is plotted in unfractionated I-& S-type granite, the biotite alkaligranite is plotted in fractionated I-& S-type granite, which indicates that the biotite alkaligranite is a more differentiated product. In order to elucidate the nature of the protoliths of the peraluminous Myeongseongsan magma, we plotted in $Al_2O_3/TiO_2$ vs. $CaO/Na_2O$ and Rb/Sr vs. Rb/Ba diagrams, and they suggest that the Myeongseongsan Granite was derived from clay-poor metagreywackes and meta-psammites or their igneous counterparts. Whole-rock zircon saturation temperature indicates that the Myeongseongsan magma was melted at $740-799^{\circ}C$.

Petrochemical Characteristics of the Granites in the Jeomchon area (점촌일대에 분포하는 화강암류에 대한 암석화학적 연구)

  • 최원희;좌용주
    • The Journal of the Petrological Society of Korea
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    • v.7 no.1
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    • pp.37-52
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    • 1998
  • The granites in the Jeomchon area can be divided into hornblende biotite granite (Hbgr), deformed biotite granite (Dbgr), deformed pinkish biotite granite(Dpbgr), biotite granite (Btgr), and granite porphyry(Gp). These granites show metaluminous, 1-type and calc-alkaine characteristics from their whole-rock chemistry. Hbgr and Dbgr belong to ilmenite-series granitoids, but Gp to magnetite-series. Dpbgr and Btgr show the intermediate nature between ilmenite- and magnetite-series. Tectonic discriminations indicate that Hbgr and Dbgr were formed in active continental margin environment, whereas Dpbgr, Btgr, and Gp in post-orogenic and/or anorogenic rift-related environment. From the Harker diagrams major oxide contents of Hbgr and Dbgr show a continuous variation with $SiO_2$, indicating that they are genetically correlated with each other. On the other hand, any correlation of major oxides variation cannot be recognized among Dpbgr, Btgr and Gp. It seems like that Hbgr and Dbgr were derived from a same parent granitic magma, judging from their occurrence of outcrop, mineral composition as well as whole-rock chemistry. Variation trends of major oxide contents between Hbgr and Baegnok granodiorite are very similar and continuous. If the two granites were derived from a cogenetic magma, there exists a possibility that the granitic bodies had been separated by Btgr and Gp of Cretaceous age. Three stages of the granitic intrusions are understood in the Jeomchon area. After the intrusion of Hbgr and Dbgr during middle to late Paleozoic time, Dpbgr emplaced into the area next, and finally Btgr and Gp intruded during Cretaceous time. Tectonic movement accompanying shear and/or thrust deformation seems likely to have occurred bewteen the intrusions of Dpbgr and Btgr.

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Geochemistry and Tectonic Implications of Triassic Bojangsan Trachyte in the Southern Margin of the Imjingang Belt, Korea (임진강대 남변부 트라이아스기 보장산조면암의 지구화학과 조구조적 의미)

  • Hwang, Sang Koo;Ahn, Ung San
    • The Journal of the Petrological Society of Korea
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    • v.26 no.2
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    • pp.113-125
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    • 2017
  • We investigates geochemical and tectonic characteristics for the Triassic Bojangsan trachyte in the southern margin of the Imjingang belt. The geochemical signatures of the thracyte are characterized by enrichments of REE and HFS, and show no Nb trough, suggesting that would not experience arc magmatic processes involving continental crustal materials. The trachyte reveals within-plate setting in tectonic discrimination diagrams using immobile HFS Nb and Y elements. And the trachyte shows typical signatures of A-type volcanic rocks with high Ga abundance and is classified as A1-type volcanic rocks rich in Nb. The geochemical signatures suggest that the trachyte was produced by the differentiation of mantle-derived magmatism at the continental rift in extensional setting subsequent to a major collision during the Permo-Triassic Songrim orogeny. The results provide robust evodence to consider the Imjingang belt as an extension of the the Qinling-Dabie-Sulu belt between the North and South China blocks.

A Design and Adaptation Technique of UML-based Layered Meta-Model for Component Development (컴포넌트 개발을 위한 UML 기반의 계층형 메타 모델 설계 및 적용기법)

  • Lee, Sook-Hee;Kim, Chul-Jin;Cho, Eun-Sook
    • Journal of the Korea Society for Simulation
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    • v.15 no.2
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    • pp.59-69
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    • 2006
  • Component-based software development is introduced as a new development paradigm in software development method. This approach is different from existing software development approach because it is based on reusable and autonomous unit, component. Therefore, component-based development(CBD)is divided into two stages; component development process and component assembly process; application development process. Component development process is the core of CBD because component has a key for good software. Currently many methodologies or tools have been introduced by various academies or industries. However, those don't suggest systematic and flexible modeling techniques adaptable easily into component development project. Existing approaches have a unique orarbitrary modeling technique or provide heuristic guidelines for component modeling. As a result, many component developers are faced with a difficult problems; how to developcomponent models, when develop which diagrams, and so on. In order to address this problem, we suggest a meta-model driven approach for component development in this paper. We provide meta-models according to both layer and development phase. We expect that suggested meta-models allow component developers to develop appropriate models of the time.

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A Study on the Morphological Diagrgmmings of Four Constitutiens (사상인(四象人)의 형태학적(形態學的) 도식화(圖式化)에 관(關)한 연구(硏究))

  • Huh, Man Hoee;Song, Jeong-Mo;Kim, Dal-Rae;Go, Byeong-Hui
    • Journal of Sasang Constitutional Medicine
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    • v.4 no.1
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    • pp.107-148
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    • 1992
  • The definitions of Four Constitution (Tae-Yang-In, So-Yang-In, Tae-Eum-In, So-Eum-In) in Four-Beginning-Theory (四端論) and Distribution-Theory (擴充論) were morphologically diagrammatized. the method of measuring the five parts came from the diagrams. The five parts are the followings; Top-Line is the distance between Rt. & Lt.Shoulders. Bosom-Line is the horizontal distance passing through the Rt. & Lt.nipples. Stomach-Line is the horizontal distance passing through the Rt. & Lt. acupuncture point Bool-Yong (不容穴). Navel-Line is the horizontal distance passing through the navel. Bottom-Line is the distance between the Rt.& Lt. anterior superior iliac spines. According to it, 311 people were measured in the clinic. Through the measured numerical values, to find out the objective propriety of the morphological diagrammings and the discriminating ability of Four Constitutions by the method of measuring the five, the author tried this study and got the following results. 1. On the ground of the Internal Organs-Theory (臟腑論), the definitions of Four Constitutions were classified and diagrammatized step by step and it was possible to draw the morphological graphs satisfying the reasonable condition objectively. 2. It was found that the graphings by Mean, Standard Deviation and 95% Confidence Interval for mean of the numerical values of five measured parts and the morphological diagrammings of the definitions in Four-Beginning Theory and Distribution-Theory drove to the same figures. 3. Through the method of the Analysis of variance and the Discriminant Analysis, it was discovered that the measured numerical values of five parts could distinguish the Four Constitutions. 4. Tae-Yang-In has the longest Top-Line and the shortest Bottom-Line. The Mean head of Confidence Interval from Top to Bottom is downwardly decreased at the rate of 3.7, 1.5, 1.8, 3.4. 5. So-Yang-In has the longest Top-Line and the shortest Bottom-Line. The Mean head of confidence Interval from Top to Bottom is downwardly decreased at the rate of 2.3, 1.5, 1.5, 1.1. 6. Tae-Eum-In has the longest Navel-Line. The Mean head of Confidence Interval from Navel to Top is upwardly decreased at the rate of 0.5, 0.4, 2.5 and downwardly decreased at the rate of 2.7 between Navel and Bottom. 7. So-Eum-In has the longest Bottom-Line. The Mean head of Confidence Interval from Bottom to Top is upwardly decreased at the rate of 1.1, 1.1, 1.8, 2.3. From the above findings, it was possible to draw the morphological graphings satisfying the objectively reasonable conditions in the definitions of Four-Beginning-Theory and Distribution-Theory and it was proved that the results of the Positive Analysis, carried with the measured numerical values of five parts from the diagramming, could show the objective propriety of the morphological graphings and the discerning ability of Four Constitutions by the method of measuring the five parts.

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