• Title/Summary/Keyword: DiI

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The Morphology, Structure and Melting Behaviour of Cold Crystallized Isotactic Polystyrene

  • Marega, Carla;Causin, Valerio;Marigo, Antonio
    • Macromolecular Research
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    • v.14 no.6
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    • pp.588-595
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    • 2006
  • The morphology, structure and melting behaviour of cold-crystallized isotactic polystyrene (iPS) were studied by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). The polymer was found to crystallize according to the dual-lamellar stack model. The two populations of lamellae, along with a melting-recrystallization phenomenon, determined the appearance of multiple melting peaks in DSC traces. The annealing peak was attributed to the relaxation of a rigid amorphous phase, rather than to the melting of crystalline material.

Common Control Channel Allocation in Cognitive Radio Networks through UWB Communication

  • Masri, Ahmed M.;Chiasserini, Carla-Fabiana;Casetti, Claudio;Perotti, Alberto
    • Journal of Communications and Networks
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    • v.14 no.6
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    • pp.710-718
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    • 2012
  • The implementation of a common control channel is one of the most challenging issues in cognitive radio networks, since a fully reliable control channel cannot be created without reserving bandwidth specifically for this purpose. In this paper, we investigate a promising solution that exploits the ultra wide band (UWB) technology to let cognitive radio nodes discover each other and exchange control information for establishing a communication link. The contribution of this paper is threefold: (i) We define the communication protocol needed to let cognitive radio nodes discover each other and exchange control information for link set up, (ii) we overcome the gap in coverage, which typically exists between UWB and long-medium range technologies, by using multi-hop communication, (iii) we evaluate the performance of our approach by adopting an accurate channel model and show its benefits with respect to an in-band signaling solution.

Free Volume in polymers. Note I。 : Theoretical background

  • Consolati, G.;Pegoraro, M.;Zanderighi, L.
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.8-24
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    • 1999
  • free volume in polymers is defined as the difference of the specific volume and the volume which is not available for the particular molecular motion which is responsible or the process that is considered . Relations between free volume and viscosity free volume and diffusion coefficient are pre-sented both in the case of simple low molecular weight liquids and in the case of polymers. Molecular models and free volume models are reminded starting from the equilibrium state equation of Simha and Somcynski. The non equilibrium situations of specific volume of glass polymers below Tg are shown introducing different relaxation volume equations which involve different material's parameters and con-cept of the fictitious temperature. The diffusivity equations of Vrentas and Duda are introduced both for the glassy and rubbery states. The possibility of introducing time relaxation functions is also suggested. The importance of finding experimental evidences of the free volume is stressed. highlights of the free volume measurement methods are given in particular as to dilatometry photocromy fluorescence electron spin resonance small angle X-ray scattering positron annihilation spectroscopy.

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Aeroelastic instability of long-span bridges: contributions to the analysis in frequency and time domains

  • Sepe, Vincenzo;Caracoglia, Luca;D'Asdia, Piero
    • Wind and Structures
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    • v.3 no.1
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    • pp.41-58
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    • 2000
  • According to research currently developed by several authors (including the present ones) a multimode approach to the aeroelastic instability can be appropriate for suspension bridges with very long span and so with close natural frequencies. Extending that research, this paper deals in particular with: i) the role of along-wind modes, underlined also by means of the flutter mode representation; ii) the effects of a variation of the mean wind speed along the span. A characterisation of the response in the time domain by means of an energetic approach is also discussed.

Multiple input describing function analysis of non-classical aileron buzz

  • Zafar, Muhammad I.;Fusi, Francesca;Quaranta, Giuseppe
    • Advances in aircraft and spacecraft science
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    • v.4 no.2
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    • pp.203-218
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    • 2017
  • This paper focuses on the computational study of nonlinear effects of unsteady aerodynamics for non-classical aileron buzz. It aims at a comprehensive investigation of the aileron buzz phenomenon under varying flow parameters using the describing function technique with multiple inputs. The limit cycle oscillatory behavior of an asymmetrical airfoil is studied initially using a CFD-based numerical model and direct time marching. Sharp increases in limit cycle amplitude for varying Mach numbers and angles of attack are investigated. An aerodynamic describing function is developed in order to estimate the variation of limit cycle amplitude and frequency with Mach number and angle of attack directly, without time marching. The describing function results are compared to the amplitudes and frequencies predicted by the CFD calculations for validation purposes. Furthermore, a limited sensitivity analysis is presented to demonstrate the potential of the approach for aeroelastic design.

A ONE-SIDED VERSION OF POSNER'S SECOND THEOREM ON MULTILINEAR POLYNOMIALS

  • FILIPPIS VINCENZO DE
    • Bulletin of the Korean Mathematical Society
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    • v.42 no.4
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    • pp.679-690
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    • 2005
  • Let K be a commutative ring with unity, R a prime K-algebra of characteristic different from 2, d a non-zero derivation of R, I a non-zero right ideal of R, f($x_1,{\cdots},\;x_n$) a multilinear polynomial in n non-commuting variables over K, a $\in$ R. Supppose that, for any $x_1,{\cdots},\;x_n\;\in\;I,\;a[d(f(x_1,{\cdots},\;x_n)),\;f(x_1,{\cdots},\;x_n)]$ = 0. If $[f(x_1,{\cdots},\;x_n),\;x_{n+1}]x_{n+2}$ is not an identity for I and $$S_4(I,\;I,\;I,\;I)\;I\;\neq\;0$$, then aI = ad(I) = 0.

Characterization and Action Patterns of Two ${\beta}$-1,4-Glucanases Purified from Cellulomonas uda CS1-1

  • Yoon, Min-Ho;Choi, Woo-Young
    • Journal of Microbiology and Biotechnology
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    • v.17 no.8
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    • pp.1291-1299
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    • 2007
  • Two ${\beta}$-1,4-glucanases (DI and DIII fractions) were purified to homogeneity from the culture filtrate of a cellulolytic bacteria, Cellulomonas sp. CS 1-1, which was classified as a novel species belonging to Cellulomonas uda based on chemotaxanomic and phylogenetic analyses. The molecular mass was estimated as 50,000 Da and 52,000 Da for DI and DIII, respectively. Moreover, DIII was identified as a glycoprotein with a pI of 3.8, and DI was identified as a non-glycoprotein with a pI of 5.3. When comparing the ratio of the CMC-saccharifying activity and CMC-liquefying activity, DI exhibited a steep slope, characteristic of an endoglucanase, whereas DIII exhibited a low slope, characteristic of an exoglucanase. The substrate specificity of the purified enzymes revealed that DI efficiently hydrolyzed CMC as well as xylan, whereas DIII exhibited a high activity on microcrystalline celluloses, such as Sigmacells. A comparison of the hydrolysis patterns for pNP-glucosides (DP 2-5) using an HPLC analysis demonstrated that the halosidic bond 3 from the nonreducing end was the preferential cleavage site for DI, whereas bond 2, from which the cellobiose unit is split off, was the preferential cleavage site for DIII. The partial N-terminal amino acid sequences for the purified enzymes were $^1Ala-Gly-Ser-Thr-Leu-Gln-Ala-Ala-Ala-Ser-Glu-Ser-Gly-Arg-Tyr^{15}$-for DI and $^1Ala-Asp-Ser-Asp-Phe-Asn-Leu-Tyr-Val-Ala-Glu-Asn-Ala-Met-Lys^{15}$-for DIII. The apparent sequences exhibited high sequence similarities with other bacterial ${\beta}$-1,4-glucanases as well as ${\beta}$-1,4-xylanases.

FOOTNOTE TO A MANUSCRIPT BY GWENA AND TEIXIDOR I BIGAS

  • Ballico, Edoardo;Fontanari, Claudio
    • Bulletin of the Korean Mathematical Society
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    • v.46 no.1
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    • pp.67-69
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    • 2009
  • Recent work by Gwena and Teixidor i Bigas provides a characteristic-free proof of a part of a previous theorem by one of us, under a stronger numerical assumption. By using an intermediate result from the mentioned manuscript, here we present a simpler, characteristic-free proof of the whole original statement.

Mitochondrial Damage and Metabolic Compensatory Mechanisms Induced by Hyperoxia in the U-937 Cell Line

  • Scatena, Roberto;Messana, Irene;Martorana, Giuseppe Ettore;Gozzo, Maria Luisa;Lippa, Silvio;Maccaglia, Alessandro;Bottoni, Patrizia;Vincenzoni, Federica;Nocca, Giuseppina;Castagnola, Massimo;Giardina, Bruno
    • BMB Reports
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    • v.37 no.4
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    • pp.454-459
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    • 2004
  • Experimental hyperoxia represents a suitable in vitro model to study some pathogenic mechanisms related to oxidative stress. Moreover, it allows the investigation of the molecular pathophysiology underlying oxygen therapy and toxicity. In this study, a modified experimental set up was adopted to accomplish a model of moderate hyperoxia (50% $O_2$, 96 h culture) to induce oxidative stress in the human leukemia cell line, U-937. Spectrophotometric measurements of mitochondrial respiratory enzyme activities, NMR spectroscopy of culture media, determination of antioxidant enzyme activities, and cell proliferation and differentiation assays were performed. The data showed that moderate hyperoxia in this myeloid cell line causes: i) intriguing alterations in the mitochondrial activities at the levels of succinate dehydrogenase and succinate-cytochrome c reductase; ii) induction of metabolic compensatory adaptations, with significant shift to glycolysis; iii) induction of different antioxidant enzyme activities; iv) significant cell growth inhibition and v) no significant apoptosis. This work will permit better characterization the mitochondrial damage induced by hyperoxia. In particular, the data showed a large increase in the succinate cytochrome c reductase activity, which could be a fundamental pathogenic mechanism at the basis of oxygen toxicity.

Optimization simulation for High Voltage 4H-SiC DiMOSFET fabrication (고전압 4H-SiC DiMOSFET 제작을 위한 최적화 simulation)

  • Kim, Sang-Cheol;Bahng, Wook;Kim, Nam-Kyun;Kim, Eun-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.353-356
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    • 2004
  • This paper discribes the analysis of the I-V characteristics of 4H-SiC DiMOSFET with single epi-layer Silicon Carbide has been around for over a century. However, only in the past two to three decades has its semiconducting properties been sufficently studied and applied, especially for high-power and high frequency devices. We present a numerical simulation-based optimization of DiMOSFET using the general-purpose device simulator MINIMIS-NT. For simulation, a loin thick drift layer with doping concentration of $5{\times}10^{15}/cm^3$ was chosen for 1000V blocking voltage design. The simulation results were used to calculate Baliga's figure of Merit (BFOM) as the criterion structure optimization and comparison.

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