• 한국기계가공학회지
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• 제19권11호
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• pp.109-115
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• 2020

Surfaces with various roughnesses were produced through laser processing, and the anisotropy and hydrophobicity of the surfaces were examined in the context of the microstructures. The fine particles transferred to the glass surface exhibited different sizes, and the roughness increased. Due to the change in the roughness, the liquid could not penetrate the space between the fine particles, and it was thus exposed to the air. We analyzed this phenomenon using the combined Wenzel and Cassie-Baxter models. Excessive fine particle formation on the substrate tended to increase the roughness and surface energy. The silver-glass-air contact analysis could clarify the mechanism of the reduction of the contact angle and differences in the metastable and stable states when the particles did not completely cover the glass substrate. The formation of microstructures with fine particles through the laser selective deposition led to the generation of an anisotropic surface as the water droplets diffused toward the glass substrate with a relatively high surface energy level.

• Nuclear Engineering and Technology
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• 제54권2호
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• pp.644-652
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• 2022

During the pyroprocessing operation, various signals can be collected by process monitoring (PM). These signals are utilized to diagnose process states. In this study, feasibility of using PM for nuclear safeguards of electrorefining operation was examined based on the use of machine learning for detecting off-normal operations. The off-normal operation, in this study, is defined as co-deposition of key elements through reduction on cathode. The monitored process signal selected for PM was cathode potential. The necessary data were produced through electrodeposition experiments in a laboratory molten salt system. Model-based cathodic surface area data were also generated and used to support model development. Computer models for classification were developed using a series of recurrent neural network architectures. The concept of transfer learning was also employed by combining pre-training and fine-tuning to minimize data requirement for training. The resulting models were found to classify the normal and the off-normal operation states with a 95% accuracy. With the availability of more process data, the approach is expected to have higher reliability.

• 한국진공학회지
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• 제6권S1호
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• pp.75-79
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• 1997

Optical and mechanical characteristics of $TiO-2, ZrO_2 \;and\; SiO_xN_y$ thin films prepared by ion assisted deposition (IAD) were investigated. IAD films were bombarded by Ar or nitrogen ion beam from a Kaufman ion source while they were grown in as e-beam evaporator. The result shows that the Ae IAD increases the refractive index and packing density of $TiO_2 films close to those of the bulk. For $ZrO_2$ films the Ar IAD increases the average refractive index decreases the negative inhomogeneity of refractive index and reverses to the positive inhomogeneity. The optical properties result from improved packing density and denser outer layer next to air The Ar-ion bombardment also induces the changes in microstructure of $ZrO_2$ films such as the preferred (111) orientation of cubic phase increase in compressive stress and reduction of surface roughness. Inhomogeneous refractive index SiOxNy films were also prepared by nitrogen IAD and variable refractive index of $SiO_xN_y$ film was applied to fabricate a rugate filter.

• Asian Journal of Atmospheric Environment
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• 제5권4호
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• pp.205-215
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• 2011

Ozone ($O_3$) is a main component of photochemical oxidants and a phytotoxic air pollutant. Although the current levels of tropospheric $O_3$ in East Asia could adversely affect productivity of forest tree species, risk assessments of $O_3$ impact were limited. In this paper, we summarize the methodology of risk assessment of $O_3$ on forest tree species based on our two previous studies, risk assessments of $O_3$ impact on the growth of Fagus crenata by Watanabe et al. (2012) and on the annual carbon absorption of three representative conifers, Cryptomeria japonica, Pinus densiflora and Larix kaempferi by Watanabe et al. (2010). $O_3$ sensitivity of each tree species obtained from an experimental study, $O_3$ exposure and atmospheric N deposition based on field monitoring and vegetation survey were integrated by geographic information system method. Based on the results, we conclude that the area with high risk of $O_3$ impact does not necessarily correspond to the area with high $O_3$ exposure. The varieties of tree habitat, tree sensitivity to $O_3$ and annual carbon absorption among the tree species, and N deposition-induced change in the $O_3$ sensitivity of F. crenata are raised as the factors of discordance between areas with high risk and those with high $O_3$ exposure. In the last part of this paper, we discuss the present uncertainty and perspectives of risk assessment for the future studies on the impact of $O_3$ on forest tree species in East Asia.

• 한국재료학회지
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• 제20권11호
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• pp.611-616
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• 2010

A cobalt oxide - tin oxide nanocomposite based gas sensor on an $SiO_2$ substrate was fabricated. Granular thin film of tin oxide was formed by a rheotaxial growth and thermal oxidation method using dc magnetron sputtering of Sn. Nano particles of cobalt oxide were spin-coated on the tin oxide. The cobalt oxide nanoparticles were synthesized by polymer-assisted deposition method, which is a simple cost-effective versatile synthesis method for various metal oxides. The thickness of the film can be controlled over a wide range of thicknesses. The composite structures thus formed were characterized in terms of morphology and gas sensing properties for reduction gas of $H_2$. The composites showed a highest response of 240% at $250^{\circ}C$ upon exposure to 4% $H_2$. This response is higher than those observed in pure $SnO_2$ (90%) and $Co_3O_4$ (70%) thin films. The improved response with the composite structure may be related to the additional formation of electrically active defects at the interfaces. The composite sensor shows a very fast response and good reproducibility.

• 한국안전학회지
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• 제31권5호
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• pp.133-140
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• 2016

Most small weir installed in Korea is concrete solidated weir. Fixed weir causes stagnant flow, which leads to deposit sediment just upstream of weir. As time goes on, it would induce reduction of water storage capacity and invoke the serious water quality issues. Therefore, there has been a growing interest in movable weir. Especially, the flexible rubber weir is easy to install and possible to operate in extreme environments. However, even though this type can be flatable, it is also not free from sediment deposition problem. Thus, to enhance the ability of releasing deposition the bypass pipe was constructed underneath it. In this study the performance of its ability was examined with hydraulic model test. This bypass pipe was designed with 3 different dimensions to connect between each bottom of upstream and downstream of a weir, such as Type A, B, and C. The efficiency of drainage of deposition upstream was studied under two water of upstream and sediment heights. In addition, the ability of sediment emission through the bypass pipe after the pipe was blocked by debris like soil, vegetation et al. was examined by video monitoring. From this study, it was suggested a dimensionless equation which show the relationship of variable parameters and amount of emission sediment through bypass pipe. And it was found that the most significant factors on efficiency of releasing were elbow angle and discharge, and the ability of emission when the pipe was blocked was most highly influenced in tilting length.

• 한국농공학회논문집
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• 제60권3호
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• pp.135-148
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• 2018

Reservoir sedimentation is a major environmental issue, and various sediment load controls and plans have been proposed to secure clean and safe water resources. The objectives of this study were to estimate soil loss in the upper basins and predict sediment deposition in Ipjang reservoir using hydrologic and hydraulic model. To do so, SWAT (Soil and Water Assessment Tool) and EFDC (Environmental Fluid Dynamics Code) was used to estimate soil loss in two upper basins and to predict spatial distribution and amount of sediment deposition in the Ipjang reservoir, respectively. The hydrologic modeling results showed that annual average soil loss from the upper basins was 500 ton. The hydraulic modeling results demonstrated that sediment particles transported to the reservoir were mostly trapped in the vicinity of the reservoir inlet and then moved toward the bank over time. If long-term water quality monitoring and sediment survey are performed, this study can be used as a tool for predicting the dredging amount, dredging location and proper dredging cycle in the reservoir. The study findings are expected to be used as a basis to establish management solutions for sediment reduction.

• 한국재료학회지
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• 제15권3호
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• pp.149-154
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• 2005

Teflon like fluorocarbon thin films have been deposited on silicon and oxide molds as an antistiction layer for the hot embossing process by an inductively coupled plasma (ICP) chemical vapor deposition (CVD) method. The process was performed at $C_4F_8$ gas flow rate of 2 sccm and 30 W of plasma power as a function of substrate temperature. The thickness of film was measured by a spectroscopic ellipsometry. These films were left in a vacuum oven of 100, 200 and $300^{\circ}C$ for a week. The change of film thickness, contact angle and adhesion and friction force was measured before and after the thermal test. No degradation of film was observed when films were treated at $100^{\circ}C$. The heat treatment of films at 200 and $300^{\circ}C$ caused the reduction of contact angles and film thickness in both silicon and oxide samples. Higher adhesion and friction forces of films were also measured on films treated at higher temperatures than $100^{\circ}C$. No differences on film properties were found when films were deposited on either silicon or oxide. A 100 nm silicon template with 1 to $500\;{\mu}m$ patterns was used for the hot embossing process on $4.5\;{\mu}m$ thick PMMA spun coated silicon wafers. The antistiction layer of 10 nm was deposited on the silicon mold. No stiction or damages were found on PMMA surfaces even after 30 times of hot embossing at $200^{\circ}C$ and 10 kN.

• 마이크로전자및패키징학회지
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• 제11권2호
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• pp.29-35
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• 2004

65 nm급 게이트 유전체로의 $HfO_2$의 적용을 위해 hydrogen-terminate된 Si 기판과 ECR $N_2$ plasma를 이용하여 SiNx를 형성한 기판 위에 MOCVD를 이용하여 $HfO_2$를 증착하였다. $450^{\circ}C$에서 증착시킨 박막의 경우 낮은 carbon 불순물을 가지며 비정질 matrix에 국부적인 결정화와 가장 적은 계면층이 형성되었으며 이 계면층은 Hf-silicate임을 알 수 있었다. 또한 $900^{\circ}C$, 30초간 $N_2$분위기에서 RTA 결과 $HfO_2/Si$의 single layer capacitor의 경우 계면층의 증가로 인해 EOT가 열처리전(2.6nm)보다 약 1 nm 증가하였다. 그러나 $HfO_2/SiNx/Si$ stack capacitor의 경우 SiNx 계면층은 열처리후에도 일정하게 유지되었으며 $HfO_2$ 박막의 결정화로 열처리전(2.7nm)보다 0.3nm의 EOT 감소를 나타내었으며 열처리후에도 $4.8{\times}10^{-6}A/cm^2$의 매우 우수한 누설전류 특성을 가짐을 알 수 있었다.

• 대한화학회지
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• 제35권2호
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• pp.151-157
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• 1991

In-HQ 착물에 대한 벗김전압전류법적 연구를 HMDE를 사용하여 0.1M 아세테이트 완충용액에서 수행하였다. 흡착된 착물의 환원피크 높이에 영향을 주는 여러 가지 분석상의 조건들에 관하여 알아보았다. 최적의 분석조건은 착화제의 농도가 $2{\times}10^{-5}$M, 용액의 pH는 4.75, 주사속도는 10mV/s, 흡착전위와 시간은 각각 -0.450V와 90초임을 알 수 있었다. 여러 다른 이온들의 방해효과와 계면활성제의 영향을 검토하였다. 본 연구에서의 검출한계는 농도 대 피크높이의 직선식으로부터 구하였을 때 90초의 흡착시간시 0.2 ppb이었으며, 4 ppb의 In을 10회 분석하였을 때 상대표준편차는 3.2%이었다.