• Korean Journal of Materials Research
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• v.31 no.8
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• pp.427-432
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• 2021

This study uses silicone monomer, DMA, crosslinking agent EGDMA, and initiator AIBN as a basic combination to prepare hydrogel lenses using fluorine-based perfluoro polyether and iron oxide and zinc oxide nanoparticles as additives. After manufacturing the lens using iron oxide nanoparticles and zinc oxide nanoparticles, the optical, physical properties, and polymerization stability are evaluated to investigate the possibility of application as a functional hydrogel lens material. As a result of this experiment, it is found that the addition of the wetting material containing fluorine changes the surface energy of the produced hydrogel lens, thereby improving the wettability. Also, the addition of iron oxide and zinc oxide nanoparticles satisfies the basic hydrogel ophthalmic lens properties and slightly increases the UV blocking performance; it also increases the tensile strength by improving the durability of the hydrogel lens. The polymerization stability of the nanoparticles evaluated through the eluate test is found to be excellent. Therefore, it is judged that these materials can be used in various conditions as high functional hydrogel lens material.

• Korean Journal of Materials Research
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• v.34 no.7
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• pp.315-320
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• 2024

In order to maximize the function and increase the compatibility of silicone hydrogel lens, this study compared and analyzed the properties of Amino modified silicone oil using mini and microemulsion technique, respectively. Optical and physical properties were evaluated by spectral transmittance, refractive index, water content, oxygen transmittance and contact angle measurements to evaluate the performance of the manufactured hydrogel lens. The spectral transmittance results revealed the copolymerization method lens showed 31 % of the visible light area, which did not satisfy the basic optical properties. However, the lens using the mini and microemulsion materials showed more than 90 % of the visible light area, satisfying the optical characteristics. In addition, all physical properties were superior to a basic hydrogel lens. The mini and microemulsion techniques effectively improved the stability and function of the ophthalmic hydrogel lens and are considered a promising ways of manufacturing an ophthalmic hydrogel contact lens with increased compatibility and stability.

• Korean Journal of Materials Research
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• v.30 no.6
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• pp.273-278
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• 2020

This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

• Journal of the Korean Chemical Society
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• v.64 no.6
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• pp.354-359
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• 2020

This research was conducted to analyze the compatibility of used monomers and produce the high functional contact lens material containing silicone monomers. Silicone monomer (Sil-OH), Trimethylsilylmethacrylate (TSMA) were used as additives for the basic combination of Polyhedral Oligomeric Silsesquioxane (POSS), methyl methacrylate (MMA) and methyl acrylate (MA). And also, the materials were copolymerized with ethylene glycol dimethacrylate (EGDMA) as the cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the fabricated lenses of all combinations are optically excellent and thus used monomers have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic lens material were varied in each case. Especially TSMA with POSS increases the oxygen permeability and Sil-OH with POSS increases the wettability by the addition of Sil-OH. These materials were considered to have compatibility each other, so it can be used in functional contact lens material.

• Korean Journal of Materials Research
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• v.32 no.4
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• pp.193-199
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• 2022

In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1 % to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.

• Proceedings of the KAIS Fall Conference
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• 2010.05b
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• pp.894-897
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• 2010

적청 색필터와 새로운 시표를 이용한 교대가림법(Twinkle R/B법)이 임상적으로 새로운 사위검사법으로 사용될 수 있는지 그 가능성을 평가하였다. 대학생 109명(남 73명, 여 36명)을 대상으로 Twinkle R/B법, Modified Thorington법, Howell법, 그리고 Von Graefe법으로 40cm 거리에서 사위검사를 실시하였다. 사위검사는 검사자별로 반복 측정을 실시하여 검사방법에 따른 신뢰도를 평가하였다. 실험 결과, 검사자의 반복측정에 따른 신뢰도는 Twinkle R/B법이 가장 높았다. 결과적으로 Twinkle R/B법은 신뢰도가 높은 사위검사법으로서 임상에서 충분히 사용 가능한 것으로 나타났다.

• Journal of Integrative Natural Science
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• v.13 no.1
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• pp.13-18
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• 2020

This study used cerium iron hydroxide nanoparticle with HEMA (2-hydroxyethyl methacrylate), the cross-linker EGDMA (ethylene glycol dimethacrylate), NVP (N-vinyl-2-pyrrolidone) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Also, the physical properties of the prepared lenses were compared, and their applicability as polymers for ophthalmic materials was experimented. The results of the measurement showed that the UV blocking rate and the wettability increased with the cerium iron hydroxide nanoparticles addition ratio, and the refractive index and water content were not affected. Thus, the produced copolymer is expected to be useful as a functional contact lens material while satisfying the basic physical properties of the hydrogel contact lens.

• Journal of Korean Ophthalmic Optics Society
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• v.16 no.3
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• pp.339-343
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• 2011

Purpose: In this study, we investigated changes of phoria based on varying the color and concentration of the color in lenses. Methods: We measured distance phoria for 39 students who aged 20 to 40 with different concentrated lenes - red, gray, brown and green lenses in concentration 20%, 50% and 80%, respectively. Results: Subjects were divided into three groups which were orthophoria, esophoria and exophoria. Orthophoria in all the color and concentration, there were a few of the esophoria. Esophoria of average 2.07${\Delta}$,B.O showed that a slight increase in all colors and concentration, especially in brown lenses showed the greatest increase. Exophoria of average 3.82${\Delta}$,B.I showed that a slight decrease in all colors and concentration, especially in green lenses showed to 2.95${\Delta}$,B.I to the greatest decrease. Different concentration in same color had no specific tendency regarding phoria. Conclusions: The phoria must be considered when selecting color of the lens because of phoria is changeable by color of the lens. It is expected to study the criteria that minimize the asthenopia.

• Journal of Korean Ophthalmic Optics Society
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• v.17 no.1
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• pp.27-35
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• 2012

Purpose: The present study was conducted to compare any difference caused by pigmentation in the centrations and movement patterns on the cornea between circle and soft contact lens with identical material and parameters during lens wearing. Methods: Soft and circle contact lenses with identical material and parameters were applied to twenty eyes with normal tear volume for 3 hrs a day during a total of 5 days and then their lens centrations, the moving distances and rotations by repeat blinking were compared. Results: The lens centration beyond the fitting criteria was shown in initial wears of both soft contact lens and circle contact lens. However, the centration of soft contact lens was changed to the pupil center for being suitable to the fitting criteria with longer wearing time. On the other hand, the decentration of circle contact lens in the horizontal direction was still presented even with longer wearing time. The moving distances of soft contact lens and circle contact lens decreased with the expand of lens wearing but were not significantly different between total wearing period and daily wearing time. The rotation of circle contact lens by repeat blinking was significantly different from that of soft contact lens even when the wearing period was extended. Conclusions: We revealed that the lens centration and movement of circle contact lens on cornea were different from those of regular soft contact lens resulting in bigger difference with the expand of wearing period in the study.

• Journal of Korean Ophthalmic Optics Society
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• v.14 no.4
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• pp.45-51
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• 2009

Purpose: The purpose of this study is to compare and analyze the survey results of clinical performance and visual problem, and the survey were carried out before and after of VDT working for 4 hours by wearing functional lens designed for improving VDT syndrome and single-vision lens. Methods: We tested near & far visual acuity, change of spherical equivalent, near point of accommodation, near point of convergence, AC/A ratio, accommodative facility and survey of subjective symptoms to visual problem of before and after VDT working for 4 hours after wearing single-vision lens and functional lens subjected on 30 males and females in the age of 20 to 45. Results: When wearing functional lens comparing to single-vision lens, near visual acuity, near point of accommodation, near point of convergence, and accommodative facility are significantly improved. It is investigated that average scores of 10 items to visual problem after VDT working for 4 hours are 3.63${\pm}$0.75 at single-vision lens and 4.69 ${\pm}$ 0.83 at functional lens, and therefore functional lens is significantly improved. Conclusions: It is thought that functional lens is an excellent lens which helps to improve accommodative function and visual problem after VDT working for 4 hours than single-vision lens.