• Title/Summary/Keyword: DISSOLVE OXYGEN

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Evaluation of pure oxygen with MBR(Membrane Bio Reactor) process for anaerobic digester effluent treatment from food waste (순산소의 MBR(Membrane Bio Reactor) 공정 적용을 통한 음식물류 폐기물 혐기성소화 유출수 처리 평가)

  • Park, Seyong;Kim, Moonil;Park, Seonghyuk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.3
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    • pp.5-16
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    • 2021
  • In this study, the applicability of the MBR(Membrane Bio Reactor) process of oxygen dissolve was evaluated through comparison and evaluation of the efficiency of oxygen dissolve device and conventional aeration device in the explosive tank within the MBR process. The organic matter and ammonia oxidation by oxygen dissolve device were evaluated, and the efficiency of persaturation was evaluated by applying real waste water (anaerobic digester effluent treatement from food waste). SCOD and ammonia removal rates for oxygen dissolve device and conventional aeration device methods were similar. However, it was determined that the excess sludge treatment cost could be reduced as the yield of microorganisms by oxygen dissolve device is about 0.03 g MLSS-produced/g SCOD-removed lower than that of microorganisms by conventional aeration device. The removal rates of high concentrations of organic matter (4,000 mg/L) and ammonia (1,400 mg/L) in anaerobic digester effluent treatment from food waste were compared to the conventional aeration device and the oxygen dissolve device organic matter removal rate was approximately 13% higher than that of the conventional aeration device. In addition, for MLSS, the conventional aeration device was 0.3 times higher than for oxygen dissolve device. This is believed to be due to the high progress of sludge autooxidation because the dissolved oxygen is sufficiently maintained and supplied in the explosive tank for oxygen dissolve device. Therefore, it was determined that the use of oxygen dissolve device will be more economical than conventional aeration device as a way to treat wastewater containing high concentrations of organic matter.

Development of Fe-Mn-based Hybrid Materials Containing Nano-scale Oxides by a Powder Metallurgical Route (분말야금법을 활용한 나노 하이브리드 구조 철-망간계 분말야금재 제조)

  • Jeon, Jonggyu;Kim, Jungjoon;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.203-209
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    • 2020
  • The automotive industry has focused on the development of metallic materials with high specific strength, which can meet both fuel economy and safety goals. Here, a new class of ultrafine-grained high-Mn steels containing nano-scale oxides is developed using powder metallurgy. First, high-energy mechanical milling is performed to dissolve alloying elements in Fe and reduce the grain size to the nanometer regime. Second, the ball-milled powder is consolidated using spark plasma sintering. During spark plasma sintering, nanoscale manganese oxides are generated in Fe-15Mn steels, while other nanoscale oxides (e.g., aluminum, silicon, titanium) are produced in Fe-15Mn-3Al-3Si and Fe-15Mn-3Ti steels. Finally, the phases and resulting hardness of a variety of high-Mn steels are compared. As a result, the sintered pallets exhibit superior hardness when elements with higher oxygen affinity are added; these elements attract oxygen from Mn and form nanoscale oxides that can greatly improve the strength of high-Mn steels.

Nutrient dynamics study of overlying water affected by peroxide-treated sediment

  • Haque, Niamul;Kwon, Sung-Hyun
    • Journal of Ecology and Environment
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    • v.41 no.9
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    • pp.235-245
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    • 2017
  • Background: Loading of excess nutrient via bioremediation of polluted sediment to overlying water could trigger anoxia and eutrophication in coastal area. The aim of this research was to understand the changes of overlying water features such as dissolved oxygen (DO); pH; oxidation reduction potential (ORP); $chlorophyll-{\alpha}$ ($Chl-{\alpha}$); and nitrogen nutrients ammonia ($N-NH_4{^+}$), nitrate ($N-NO_3{^-}$), and nitrite ($N-NO_2^-$) when the sediment was not treated (control) and treated by calcium peroxide for 5 weeks. Methods: The water samples were analyzed for measuring physical and chemical properties along with the sediment analyzed by polymerase chain reaction (PCR) including denaturing gradient gel electrophoresis (DGGE) for identifying the phylogenetic affiliation of microbial communities. Results: Results showed that due to the addition of calcium peroxide in sediment, the overlying water exposed the rise of dissolve oxygen, pH, and ORP than control. Among the nitrogen nutrients, ammonia inhibition was higher in calcium peroxide treatment than control but in case of nitrate inhibition, it was reversed than control. $Chlorophyll-{\alpha}$ was declined in treatment column water by 30% where it was 20% in control column water. Actibacter and Salegentibacter group were detectable in the calcium-peroxide-treated sediment; in contrary, no detectable community ware found in control sediment. Both phylogenetic groups are closely related to marine microflora. Conclusions: This study emphasizes the importance of calcium peroxide as an oxygen release material. Interaction with peroxide proved to be enhancing the formation of microbial community that are beneficial for biodegradation and spontaneity of nutrient attenuation into overlying water.

Reaction Characterization of a Photosynthetic Bacterium Containing $Q_{10}$ ($Q_{10}$ 함유 광합성세균의 반응특성)

  • Jeong, Soo Kyoung;Kim, Joong Kyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.2 no.3
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    • pp.198-200
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    • 2007
  • Cultivation of a $Q_{10}$-producing photosynthetic bacterium, Rhodobacter sphaeroids, was carried out in a 1-L flask to characterize its cellular growth reaction. The result of experiment showed that dissolve oxygen in the broth was depleted within 7 h. ORP decreased with decrease of DO, and recovered somewhat with increase of pH. The growth of R. spahaeroids reached at late-log phase in 140 h of reaction. The final pH and dry-cell weight were 7.62 and 2.2 mg/mL, respectively. The $Q_{10}$ content in the final broth was 2.35 mg/g dry cell weight, which was higher than that obtained in tube culture.

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Correlation between Characteristics of SOD in Coastal Sewage and Predictive Factor (연안 저질 SOD의 특성과 유발 영향인자에 대한 상관관계)

  • Kim, Beom-Geun;Khirul, Md Akhte;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.596-604
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    • 2019
  • This study conducted a sediment culture experiment to investigate the effects of sediment oxygen demand (SOD) and environmental factors on sediment and water quality. We installed a leaching tank in the laboratory, cultured it for 20 days, and analyzed the relationship between P and Fe in the sediment. As a result, the dissolved oxygen of the water layer decreased with time, while the oxidation-reduction potential of the sediment progressed in the negative direction to form an anaerobic reducing environment. The SOD was measured to be 0.05 mg/g at the initial stage of cultivation and increased to 0.09 mg/g on the 20th day, indicating the tendency of increasing consumption of oxygen by the sediment. The change is likely to have caused by oxygen consumption from biological-SOD, which is the decomposition of organic matter accumulated on the sediment surface due to the increase of chl-a, and chemical-SOD consumed when the metal-reducing product produced by the reduction reaction is reoxidized. The correlation between SOD and causality for sediment-extracted sediments was positive for Ex-P and Org-P and negative for Fe-P. The analysis of the microbial community in the sediment on the 20th day showed that anaerobic iron-reducing bacteria (FeRB) were the dominant species. Therefore, when the phosphate bonded to the iron oxide is separated by the reduction reaction, the phosphate is eluted into the water to increase the primary productivity. The reduced substance is reoxidized and contributes to the oxygen consumption of the sediment. The results of this study would be useful as the reference information to improve oxygen resin.

The annihilation of the flow pattern defects in CZ-silicon crystal by high temperature heat treatment (고온 열처리에 의한 결정결함의 재용해)

  • 서지욱;김영관
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.3
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    • pp.89-95
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    • 2001
  • The CZ-silicon crystal was annealed at $1350^{\circ}C$ to dissolve the vacancy type grown-in defects. A this temperature, the equilibrium concentration of the oxygen in the silicon crystal is around $1.7{\times}10^{18}$ which induces the oxygen undersaturation in the silicon crystal. This situation results in the faster dissolution of the grown-in defects in the bulk of the silicon wafer than near the surface. This indicates the possibility that the presence of the higher concentration of silicon interstitial hinders the dissolution of the grown-in defects, which were known to compose of the vacancy clusters with surrounding silicon oxide film. This expectation was confirmed by the observation that the slower dissolution of the grown-in defects near the surface of the silicon wafer in the oxygen atmosphere than in the argon atmosphere. This result is quite opposite to the previous argument hat presence of the excess silicon interstitial leads to faster dissolution of the vacancy type defects.

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Comparative Bioreactor Studies in Terms of Oxygen Transfer between Suspended and Immobilized Fungal Systems for Cyclosporin A Fermentation (Cyclosporin A 생산을 위한 액체배양과 고정화배양의 생물반응기에서의 산소전달 비교 연구)

  • 전계택
    • KSBB Journal
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    • v.9 no.2
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    • pp.211-223
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    • 1994
  • In fermentations with a 4-liter stirred tank bioreactor, a better than two-fold enhancement of the gas-liquid mass transfer coefficient$(k_La)$ in the celite-immobilized fungal cultures of Tolypocladium in flatum over the parallel conventional free-cell was observed at identical biomass concentrations, despite the higher specific oxygen uptake rate of the immobilized fungi during exponential growth. As a result oxygen sufficient conditions, i. e., dissolve oxygen(D.O.) concentrations exceeding 75% air saturation, could be maintained throughout exponential growth period of the immobilized culture, in contrast to the suspended fungal culture, whose D.O. levels fell below 50% air saturation. A linear monotonic dependence of $k_La$ upon impeller agitaion rate was found for both immobilized and conventional cultivation modes over a range of 250 to 550rpm, the slope being a function of biomass concentration for the free but not for the immobilized cell system In contrasts oxygen transfer rate was a much weaker function of aeration rate up to about 2.5 vvm for both culture configurations. Above this level, aeration rate had no further effect on the mass transfer. In addition, the immobilized cultures sustained good morphological and physiological states, leading to almost two times higher cyclosporln A (CyA) productivity overt the parallel free cell system. These experiments suggest that the celite-immobilized fungal system in a stirred tank reactor has considerable promise for scaling up cyclosporin A production in terms of high-density cultivation.

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MOF-Derived FeCo-Based Layered Double Hydroxides for Oxygen Evolution Reaction

  • Fang Zheng;Mayur A. Gaikwad;Jin Hyeok Kim
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.377-384
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    • 2023
  • Exploring earth-abundant, highly effective and stable electrocatalysts for electrochemical water splitting is urgent and essential to the development of hydrogen (H2) energy technology. Iron-cobalt layered double hydroxide (FeCo-LDH) has been widely used as an electrocatalystfor OER due to its facile synthesis, tunable components, and low cost. However, LDH synthesized by the traditional hydrothermal method tends to easily agglomerate, resulting in an unstable structure that can change or dissolve in an alkaline solution. Therefore, studying the real active phase is highly significant in the design of electrochemical electrode materials. Here, metal-organic frameworks (MOFs) are used as template precursors to derive FeCo-LDH from different iron sources. Iron salts with different anions have a significant impact on the morphology and charge transfer properties of the resulting materials. FeCo-LDH synthesized from iron sulfate solution (FeCo-LDH-SO4) exhibits a hybrid structure of nanosheets and nanowires, quite different from other electrocatalysts that were synthesized from iron chloride and iron nitrate solutions. The final FeCo-LDH-SO4 had an overpotential of 247 mV with a low Tafel-slope of 60.6 mV dec-1 at a current density of 10 mA cm-2 and delivered a long-term stability of 40 h for the OER. This work provides an innovative and feasible strategy to construct efficient electrocatalysts.

Design of High Frequency Casting Machine for Dental using Induction Heating System (유도가열 시스템을 적용한 치과용 고주파 주조기 설계)

  • Song, Seung-Gun;Lim, Sang-Kil;Lee, Sang-Hun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.8
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    • pp.79-87
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    • 2012
  • Currently, The method to produce a brewing body for dentistry supplementation water produces a brewing body by fabrication, burying and it is heat wish in city gas and oxygen. It uses an original judgment found airplane the brewing body uses a spring of the back wait that melting temperature dissolved various alloys in by a blow pipe, and to generate centrifugal force and produces it. In addition, because it uses preheating to dissolve an alloy in general, it is hard to regulate the appropriate melting temperature of the alloy and brewing time and generates a brewing defect hereby same as gas industry and pinhole and shows the defect of the supplementation thing due to the super-heating. In this paper, We developed the high induction heating system which it could set brewing time,temperature and had durability and security,by the kind of the alloy to produce a high quality prosthetic thing brewing body.

Nitrogen Dissolution in CaO-SiO2-Al2O3-MgO-CaF2 Slags (CaO-SiO2-Al2O3-MgO-CaF2 슬래그의 질소용해도에 관한 연구)

  • Baek, Seoung Bae;Lim, Jong Ho;Jung, Woo Jin;Lee, Seoung Won
    • Korean Journal of Materials Research
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    • v.24 no.2
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    • pp.81-86
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    • 2014
  • The nitrogen solubility and nitride capacity of $CaO-SiO_2-Al_2O_3-MgO-CaF_2$ slag systems were measured by using gas-liquid equilibration at 1773K. The nitrogen solubility of this slag system decreased with increasing CO partial pressure, with the linear relationship between nitrogen contents and oxygen partial pressure being -3/4. This system was expected to show two types of nitride solution behavior. First, the nitrogen solubility decreased to a minimum value and then increased with the increase of CaO contents. These mechanisms were explained by considering that nitrogen can dissolve into slags as "free nitride" at high basicities and as "incorporated nitride" within the network at low basicities. Also, the basicity of slag and nitride capacity were explained by using optical basicity. The nitrogen contents exhibited temperature dependence, showing an increase in nitrogen contents with increasing temperature.