• 제목/요약/키워드: DC conductivity

검색결과 214건 처리시간 0.031초

DC마그네트론 스퍼터링으로 Pd박막 입힌 Nafion막의 특성 (Characteristics of Nafion Membranes with Pd Thin Films Deposited by DC Magnetron Sputtering Technique)

  • 황기호;조원일;조병원;윤성렬;하흥용;오인환;김광범
    • 전기화학회지
    • /
    • 제5권2호
    • /
    • pp.68-73
    • /
    • 2002
  • 상용 고분자 전해질인 Nafion 115 및 Nafion 117막 위에 do magnetron sputtering방법으로 Pd박막을 다양한 두께로 증착한 다음, 개질된 고분자 전해질 막의 morphology, proton 전도도(conductivity), 메탄을 투과도(permeability)를 측정하였으며, membrane and electrode assemblies(MEA)를 구성하여 DMFC 단위전지 성능을 측정하였다. Pd 박막은 Nafion막이 지니고 있는 단점인 메탄을 crossover에 대한 barrier로서 작용하였지만, 동시에 Nafion막의 고유 특성인 proton전도도의 감소를 가져왔다. Pd박막에 의하여 개질된 Nafion막의 메탄올에 대한 투과도와 proton전도도는 Nafion 막 상에 증착된 Pd 박막의 두께가 증가할수록 직선적으로 감소하는 경향을 나타냈다 개질된 Nafon 막을 사용하여 제작한 direct methanol fuel cell(DMFC)단위전지의 성능은 전체적으로 약간 저하되었다.

PWM 인버터의 스위칭 주파수에 따른 브러시레스 DC 모터에서의 와전류 손실 특성 해석 (Analysis of Eddy Current Loss in Brushless DC Motor according to the Swiching Frequency of the PWM Inverter)

  • 김와성;최태식;김윤현;이주
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 하계학술대회 논문집 B
    • /
    • pp.675-677
    • /
    • 2000
  • In the paper the eddy current loss in brushless DC motor due to switching frequency supplied by PWM inverter, is analyzed. The compensated conductivity is used in order to analyze the eddy current loss in brushless DC motor which has lamination structure. The eddy current loss is deceased when switching frequency supplied by PWM inverter is gradually increased from 1.2kHz up to 12kHz. The high switching frequency of PWM inverter make the output wave into a similar sine wave and this leads to the decreasing eddy current loss.

  • PDF

고효율 DC 마그네트론 스파터링법으로 성장시킨 다이아몬드상 카본의 물리적, 전기적 특징 (Physical and Electrical Properties of Amorphous Carbon(a-C) Thin Films Grown by High Rate DC Magnetron Sputtering method)

  • 박용섭;한전건;홍병유
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
    • /
    • pp.83-87
    • /
    • 2003
  • Thin films of amorphous carbon (a-C) generally combine high wear resistance with low friction coefficients and a-C films have widespread applications as protective coatings and passivation of electrical circuit and insulating layer. In this work we deposited the amorphous carbon (a-C) films on silicon substrate with a high rate DC magnetron sputtering system. It is obtained parameters on the deposition rate and physical properties of a-C films using a wide range of Ar gas pressure and DC power. The physical properties of the films were analyzed by Nanoindenter and AFM (Atomic Force Microscopy), The electrical properties were investigated by electrical conductivity measurement.

  • PDF

마그네트론 스퍼터링법으로 증착한 Au 박막의 전기전도특성에 미치는 열처리 온도와 Ta 삽입층의 영향 (The effect of annealing temperature and Ta layer on the electric conductivity of Au thin film deposited by the magnetron sputtering)

  • 최혁철;유천열
    • 한국진공학회지
    • /
    • 제16권6호
    • /
    • pp.433-438
    • /
    • 2007
  • 열처리 온도에 따른 Au 결정립 크기의 변화와 표면 거칠기 및 전기전도도를 연구하기 위해 dc 마그네트론 스퍼터링법을 사용하여 Si(111) 또는 Si(100) 기판위에 Au (30nm) 와 Ta (5 nm)/Au (30 nm) 를 증착하였다. 열처리 온도가 증가함에 따라 시료의결정립 크기가 증가하였고, 박막 표면 거칠기 또한 증가함을 확인하였다. Si/Au보다Si/Ta/Au구조에서 결정립 크기가 증가하였고 표면거칠기는 감소되었으며 Si(111)기판보다 Si(100) 기판위의 Ta/Au구조에서 전기 저항이 감소되었다. Si(100)/Au구조에 5 nm 두께의 Ta의 buffer layer를 삽입하여 표면 거칠기 정도를 낮춤과 동시에 열처리 온도를 적절히 조절하여 결정립 크기를 증가시킴으로서 전도성이우수한 양질의 Au 박막을 얻을 수 있었다.

플라즈마 용사된 Al2O3-TiO2 코팅의 전기적 특성 (The Electrical Behavior of Plasma Sprayed Al2O3-TiO2 Coatings)

  • 박상준;이성민
    • 한국전기전자재료학회논문지
    • /
    • 제30권12호
    • /
    • pp.788-793
    • /
    • 2017
  • Electrical behaviors of plasma-sprayed $Al_2O_3-TiO_2$ coatings have been investigated in terms of their $TiO_2$ content. On increasing the $TiO_2$ content from 6 to 30 wt%, the DC electrical conductivity increased by several orders of magnitude. From impedance spectroscopy analysis, the total conductivity of the grains and grain boundaries and their respective activation energies were determined without the electrode effects that could impede ionic transfer. An electron transference number was also estimated, ranging between 6.5% and 7.3% for 13 wt% $TiO_2$ and between 0.4% and 0.7% for 30 wt% $TiO_2$ in the coating. Because of the high electronic contribution to the total conductivity, the $Al_2O_3-TiO_2$ coating could be a new candidate material to obtain superior electrical conductivity as well as corrosion and wear resistances.

Electrical Conductivity, Dielectric Behavior and EMI Shielding Effectiveness of Polyaniline-Yttrium Oxide Composites

  • Faisal, Muhammad;Khasim, Syed
    • Bulletin of the Korean Chemical Society
    • /
    • 제34권1호
    • /
    • pp.99-106
    • /
    • 2013
  • Polyaniline-yttrium trioxide (PAni-$Y_2O_3$) composites were synthesized by the in-situ polymerization of aniline in the presence of $Y_2O_3$ The composite formation and structural changes in these composites were investigated by X-ray diffraction (XRD), Fourier transform infra red spectroscopy (FTIR), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The direct current (DC) electrical conductivity of the order of $0.51{\times}10^{-2}\;S\;cm^{-1}-0.283\;S\;cm^{-1}$ in the temperature range 300 K-473 K indicates semiconducting behavior of the composites. Room temperature AC conductivity and dielectric response of the composites were studied in the frequency range of 10 Hz to 1 MHz. The variation of AC conductivity with frequency obeyed the power law, which decreased with increasing weight percentage (wt %) of $Y_2O_3$. Studies on dielectric properties shows the relaxation contribution coupled by electrode polarization effect. The dielectric constant and dielectric loss in these composites depend on the content of $Y_2O_3$ with a percolation threshold at 20 wt % of $Y_2O_3$ in PAni. Electromagnetic interference shielding effectiveness (EMI SE) of the composites in the frequency range 100 Hz to 2 GHz was in the practically useful range of -12.2 dB to -17.2 dB. The observed electrical and shielding properties were attributed to the interaction of $Y_2O_3$ particles with the PAni molecular chains.

용액 전도도 및 삼투압 조절된 PBS에서의 위암 세포 전기 분해 (Stomach Cancer Cell Lysis in PBS with Conductivity and Osmotic-Pressure Control)

  • 김민수;이국녕;조수형;김병기;김용권
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 하계학술대회 논문집 C
    • /
    • pp.2137-2139
    • /
    • 2004
  • Cancer cell lysis at pulsed DC is realized using micromachined electrodes. In this research, quantitative analyses are performed on cell lysis results. The cell volume increasing at the pulses applied are analyzed in different medium conditions on osmotic pressure and conductivity, and the cell lysis procedures are studied in detail experimentally. Phosphate buffered saline (PBS) is used as the medium. To change the conductivity of PBS, NaCl concentration of PBS is adjusted, and inositol is used with PBS to control the effects of the osmotic pressure to cell lysis performance.

  • PDF

Morphology of the Conducting Poly-N-vinylcarbazole-coated Silica Gel Nanocomposites

  • Basavaraja, C.;Kim, Na-Ri;Jo, Eun-Ae;Revanasiddappa, M.;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권2호
    • /
    • pp.298-302
    • /
    • 2010
  • We report the effect of surface morphology on the conductivity of the poly-N-vinylcarbazole (PVK)/silica gel ($SiO_2$) nanocomposites as a function of $SiO_2$ weight percentage (%).The polymerization of PVK was initiated by a free-radical polymerization. The surface morphology of the prepared composite shows the incorporation of $SiO_2$ in the prepared PVK-$SiO_2$ (PS) nanocomposites. The conductivity increased from $9.2{\times}10^{-5}S\;cm^{-1}$ to $9.6{\times}10^{-4}S\;cm^{-1}$ with the increase in the percentage of silica gel from 5 to 30%. The nanocomposites show a percolation behavior having a threshold value between 15 and 20%.

레벨셋 기법의 물성 보간 방법에 대한 고찰 (ASSESSMENT OF PROPERTY INTERPOLATION METHODS IN LEVEL SET METHOD)

  • 박준권;오정민;강관형
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 2009년 춘계학술대회논문집
    • /
    • pp.283-289
    • /
    • 2009
  • In level set method, material properties are made to change smoothly across an interface of two materials with different properties by introducing an interpolation or smoothing scheme. So far, the weighted arithmetic mean (WAM) method has been exclusively adopted in level set method, without complete assessment for its validity. We showed here that the weighted harmonic mean (WHM) method for rate constants of various rate processes, including viscosity, thermal conductivity, electrical conductivity, and permittivity, gives much more accurate results than the WAM method. The selection of interpolation scheme is particularly important in multi-phase electrohydrodynamic problems in which driving force for fluid flow is electrical force exerted on the phase interface. Our analysis also showed that WHM method for both electrical conductivity and permittivity gives not only more accurate, but also more physically realistic distribution of electrical force at the interface. Our arguments are confirmed by numerical simulations of drop deformation under DC electric field.

  • PDF

Protonic Conduction Properties of Nanostructured Gd-doped CeO2 at Low Temperatures

  • Park, Hee Jung;Shin, Jae Soo;Choa, Yong Ho;Song, Han Bok;Lee, Ki Moon;Lee, Kyu Hyoung
    • 한국세라믹학회지
    • /
    • 제52권6호
    • /
    • pp.527-530
    • /
    • 2015
  • The electrical properties of nanostructured Gd-doped $CeO_2$ (n-GDC) as a function of temperature and water partial-pressure were investigated using ac and dc measurements. For n-GDC, protonic conductivity prevails under wet condition and at low temperatures (< $200^{\circ}C$), while oxygen ionic conductivity occurs at high temperatures (> $200^{\circ}C$) under both dry and wet conditions. The grain boundaries in n-GDC were highly selective, being conductive for protonic transport but resistive for oxygen ionic transport. The protonic conductivity reaches about $4{\times}10^{-7}S/cm$ at room temperature (RT).