• Polymer(Korea)
• /
• v.36 no.3
• /
• pp.315-320
• /
• 2012

Ultra violet (UV) curable pressure sensitive adhesives (PSA) were prepared by controlling both the structure of acryl copolymer and the functionality and content of multi-functional monomers. Acryl copolymer worked as the base polymer for giving the tackiness. Multi-functional monomers were used to vary the crosslinked structure and the degree of crosslink. Acryl copolymer showed the reduced peel strength after UV curing by decreasing the content of 2-ethylhexyl acrylate in the monomer composition. Both the peel strength of PSA and the content of residue found on silicon wafer decreased after UV curing by increasing the functionality of multi-functional monomers. UV curable PSA containing 20 phr six-functional monomer showed the higher peel strength before UV curing and the lower peel strength and the least residue on silicon wafer after UV curing.

• Tunnel and Underground Space
• /
• v.19 no.3
• /
• pp.181-189
• /
• 2009

This study is to evaluate an effect of supports with respect to these supports after comparing the characteristic of support between rock bolt of a widely used type and spiral bolt of a new type. For these purposes, we performed pull-out test in laboratory about rock and spiral bolts in the case of cement-mortar grout curing periods, 7 and 28 days, then calculated pull-out load, displacement, external pressure, inner pressure and shear stress using data obtained from the results of pull-out test, respectively. In relation between pull-out load and displacement, displacement of spiral bolt is larger than one of rock bolt. It is considered that mechanical property of rock bolt is due to larger than one of spiral bolt. In addition, displacement of supports shows nearly same or decreasing with curing periods. We found that because adhesive force between supports and cement-mortar grout is increasing with compressive strength of grout according to curing periods. The inner pressure of spiral bolt is represented larger than one of rock bolt at a step of same pull-out load. It is suggested that spiral bolt is more stable than rock bolt, maintaining stability of ground or rock mass, when supports are installed in a ground or rock mass under the same condition. Putting together with above results, we can consider that spiral bolt as a new support on an aspect of pull-out load and inner pressure is larger than rock bolt in a ground or rock mass under the same condition. Moreover, spiral bolt is more effective support than rock bolt, considering an economical and constructive aspects of supports, as well as ground or rock stability before or after installing supports.

• Journal of Technologic Dentistry
• /
• v.39 no.1
• /
• pp.9-16
• /
• 2017

Purpose: The purpose of this study was to evaluate flexural strength, composite surface and fractured surface of three different indirect composite resins. Methods: Fifteen bar-shaped specimens ($25mm{\times}2mm{\times}2mm$) were fabricated for each FL group (Flow type and Light curing) and PLP group (Putty type and Light, Pressure curing) and PL group (Putty type and Light curing) according to manufacturer's instructions and ISO 10477. Fabricated specimens were stored in the distilled water for 24 hours at the temperature of $37^{\circ}C$. Three-point bending strength test was performed to measure flexural strength using universal testing machine at a crosshead speed of 1mm/min (ISO 10477). Surface and fractured surface of specimens were observed by digital microscope. Results were analyzed with Kruskal-wallis tests (${\alpha}=0.05$). Results: Mean (SD) of three different indirect composite resins were 83.38 (6.67) MPa for FL group, 139.90(16.53) MPa for PLP group and 171.72(16.74) MPa for PL group. Flexural strength were statistically significant (p<0.05). Differences were not observed at fractured surface among three groups. However, many pores over $100{\mu}m$ were observed at PL group in observing surface of specimen. Conclusion: Flexural strength of composite resins was affected by second polymerization method and content of inorganic filler.

• Journal of Advanced Marine Engineering and Technology
• /
• v.22 no.2
• /
• pp.139-145
• /
• 1998

Filament winding method is widely used for composite fabrications using low viscosity liquid for-mation and processing asymmetrical structures of pressure vessel pipe rocket motor case etc. The filament winding method is affected by several parameters such as pot life of process time viscosi-ty of resin filament winding temperature and schedules curing condition and post curing condi-tion of resin. To develope high functional composite materials the rotation(5, 15, 20, 30rpm) of the winding machine was controlled by D.C motor. And the wiper to give proper tension was equipped between strand and resin bath. The resin is hooked by the design wiper. The adequate cure schedule was found by DSC. NOL ring test is carried out to investigate the basic physical properties such as design technology. The void contents in filament winding is generally higher than that of the prepreg laminated plate. These high contents of void can make a crack in resin in spite of low deformation. These problem was solved by giving tension in processing. To improve the characteristics of fiber volume fraction void contents resin/fiber bonding the winding speedc is changed under constant tension. It was found that resin impregnation was not different from in fiber contents void contents at the range of 0.5~1kg tension but it was found that resin was not impregnated at the above of 1.5kg tension. In burst test a pure PE liner was failed at a nozzle part under the $14kg/\textrm{cm}^2$ pressure but a pressure vessel of CNG was failed at a cylinder part under the $200kg/\textrm{cm}^2$ pressure.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.05a
• /
• pp.172-175
• /
• 2001

The co-cured Joining method, which is regarded as an adhesively bonded Joining method, is an efficient joining technique because both curing and bonding processes for the composite structures can be achieved simultaneously. It requires neither surface treatment onto the composite adherend nor an additional adhesive joining process because the excess resin, which is extracted from composite materials during consolidation, accomplishes the co-cured Joining process. Since the adhesive of the co-cured joint is the same material as the resin of the composite adherend, the analysis and design of the co-cured joint for composite structures are simpler than those of an adhesively bonded joint, which uses an additional adhesive. In this paper, effects of the manufacturing parameters, namely surface roughness, stacking sequence of the composite adherend, and manufacturing pressure in the autoclave during curing process, on the tensile load bearing capacity of the co-cured single lap joint will be experimentally investigated.

• Geomechanics and Engineering
• /
• v.10 no.1
• /
• pp.77-94
• /
• 2016

Cyclic triaxial and resonant column tests were conducted to understand the beneficial effects of various grouted sands on liquefaction resistance and dynamic properties. The test procedures were performed on a variety of grouted sands, such as silicate-grouted sand, silicate-cement grouted sand and cement-grouted sand. For each type of grout, sand specimen was mixed with a 3.5% and 5% grout by volume. The specimens were tested at a curing age of 3, 7, 28 and 91 days, and the results of the cyclic stress ratio, the maximum shear modulus and the damping ratio were obtained during the testing program. The influence of important parameters, including the type of grout, grout content, shear strain, confining pressure, and curing age, were investigated. Results indicated that sodium silicate grout does not improve the liquefaction resistance and shear modulus; however, silicate-cement and cement grout remarkably increased the liquefaction resistance and shear modulus. Shear modulus decreased and damping ratio increased with an increase in the amplitude of shear strain. The effect of confining pressure on clean sand and sodium silicate grouted sand was found to be insignificant. Furthermore, a nonlinear regression analysis was used to prove the agreement of the shear modulus-shear strain relation presented by the hyperbolic law for different grouted sands, and the coefficients of determination, $R^2$, were nearly greater than 0.984.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.397-400
• /
• 2006

Most of the civil structures in Korea and abroad have many kinds of damages when they are facing over-loaded traffics, long-term serviceability, and severe environmental conditions. Repair, rehabilitation, and retrofit are important for maintaining the serviceability of structures. In recent year, VES-LMC has been widely used as repair material for bridge deck repair and rehabilitation, because the VES-LMC has a various benefits such as traffic opening after 3 hours of curing, higher durability and bond strength. In case of any structure repaired or rehabilitated with VES-LMC, those were influenced capacity of bond between the base layer of slab and VES-LMC as well as physical properties of each other materials. The capacity of bond depended on purity of interface, micro cracks, curing of VES-LMC and so like. A kind of popular concrete repair technique, High pressure water jetting equipment is extremely efficient at removing damaged concrete. Removing damaged or poor quality concrete from sensitive structures such as bridge, tunnels, multi-story car parking decks and runways, using the high pressure water jetting could remove damaged or poor quality concrete remaining healthy and sound concrete. Accordingly, the purpose of this study is that it was to evaluate effect of hydrodemolition on the bond strength of VES-LMC overlay compared with effects of other method such as breaker, untreated. Also, it was evaluated the effect of surface moisture.

• Geomechanics and Engineering
• /
• v.23 no.2
• /
• pp.151-163
• /
• 2020

Grouting method is an effective way of reinforcing cracked rock masses and plugging water gushing. Current grouting diffusion models are generally developed for horizontal cracks, which is contradictory to the fact that the crack generally occurs in rock masses with irregular spatial distribution characteristics in real underground environments. To solve this problem, this study selected a cement-sodium silicate slurry (C-S slurry) generally used in engineering as a fast-curing grouting material and regarded the C-S slurry as a Bingham fluid with time-varying viscosity for analysis. Based on the theory of fluid mechanics, and by simultaneously considering the deadweight of slurry and characteristics of non-uniform spatial distribution of viscosity of fast-curing grouts, a theoretical model of slurry diffusion in an oblique crack in rock masses at constant grouting rate was established. Moreover, the viscosity and pressure distribution equations in the slurry diffusion zone were deduced, thus quantifying the relationship between grouting pressure, grouting time, and slurry diffusion distance. On this basis, by using a 3-d finite element program in multi-field coupled software Comsol, the numerical simulation results were compared with theoretical calculation values, further verifying the effectiveness of the theoretical model. In addition, through the analysis of two engineering case studies, the theoretical calculations and measured slurry diffusion radius were compared, to evaluate the application effects of the model in engineering practice. Finally, by using the established theoretical model, the influence of cracking in rock masses on the diffusion characteristics of slurry was analysed. The results demonstrate that the inclination angle of the crack in rock masses and azimuth angle of slurry diffusion affect slurry diffusion characteristics. More attention should be paid to the actual grouting process. The results can provide references for determining grouting parameters of fast-curing grouts in engineering practice.

• Journal of Adhesion and Interface
• /
• v.19 no.2
• /
• pp.74-82
• /
• 2018

Many methods for cross-linking acrylic PSAs have been discussed previously. For high cross-linking density, epoxy functionalized monomer and methyl aziridines as cross-linking agents were used in this study. Additionally, photopolymerization using different UV doses was investigated to synthesize a binder because of its rapid productivity. FT-IR analysis, curing behaviours and adhesion performance were examined for the relationship between UV doses and temperature as curing conditions. According to the results, the gel fraction was over 50% even at $120^{\circ}C$ after UV curing at a dose of $800mJ/cm^2$. On the other hand, while gel fractions of all samples reached approximately 80% only at $180^{\circ}C$ in thermal curing for 1 hour, gel fractions of the samples after thermal curing for 3 hours increased rapidly above $120^{\circ}C$ regardless of UV doses and reached approximately 100% at $180^{\circ}C$. This means that the second cross-linking reaction, esterification, is mainly dependent on the curing temperature.

• Tribology and Lubricants
• /
• v.26 no.5
• /
• pp.297-302
• /
• 2010

This study is focused on the resin layer formation of UV imprinting process by changing imprinting pressure and period. The mold shape is made for the process of window open over the pattern transfer area and the imprinting period is assigned as the time just before the UV light curing. The residual layer is measured by changing the imprinting period and pressure magnitude, and the measured data of residual layer provides useful information for the design of the process conditions of imprinting processes.