• 한국재료학회지
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• 제1권2호
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• pp.71-76
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• 1991

The superconducting powders in $YBa_2Cu_3O_{7-x}$ and Bi-Pb-Sr-Ca-Cu-O system were easily prepared from water in oil type emulsion by loading each cation into the aqueous phase. In $YBa_2Cu_3O_{7-x}$ system, the superconducting orthorhombic phase was formed by calcining at $750^{\circ}C$ for 10h in $O_2$. The size of the superconducting phase powders was submicron. The density of the sintered specimen using this powders was about 95% of the theoretical density and the resistance sharply decreases at about 90K, In Bi-Pb-Sr-Ca-Cu-O system the low Tc phase($(Bi, Pb)_2Sr_2Ca_1Cu_2O_y$) was formed by calcining at $800^{\circ}C$ for 10h in a low oxygen partial pressure of 1/20 atm The shape of clacined powder is thin plate of which size is about $2\mu\textrm{m}$ and thickness is smaller than $\mu\textrm{m}$. It was observed that the high Tc phase ($(Bi, Pb)_2Sr_2Ca_2Cu_3O_y$) was formed by sintering at $850^{\circ}C$ for 30h in oxygen pressure of 1/20 atm without intermediary grinding. The above sintered sample exhibited superconductivity with a Tc(zero)=105K.

• Nuclear Engineering and Technology
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• 제54권10호
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• pp.3855-3863
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• 2022

An evaluation of the radiation shielding performance of high-Z-particle-loaded polylactic acid (PLA) composite materials was pursued. Specimens were produced via fused deposition modeling (FDM) using copper-PLA, steel-PLA, and BaSO₄-PLA composite filaments containing 82.7, 75.2, and 44.6 wt% particulate phase contents, respectively, and were tested under broad-band flash x-ray conditions at the Sandia National Laboratories HERMES III facility. The experimental results for the mass attenuation coefficients of the composites were found to be in good agreement with GEANT4 simulations carried out using the same exposure conditions and an atomistic mixture as a model for the composite materials. Further simulation studies, focusing on the Cu-PLA composite system, were used to explore a shield design parameter space (in this case, defined by Cu-particle loading and shield areal density) to assess performance under both high-energy photon and electron fluxes over an incident energy range of 0.5-15 MeV. Based on these results, a method is proposed that can assist in the visualization and isolation of shield parameter coordinate sets that optimize performance under targeted radiation characteristics (type, energy). For electron flux shielding, an empirical relationship was found between areal density (AD), electron energy (E), composition and performance. In cases where ${\frac{E}{AD}}{\geq}2MeV{\bullet}cm{\bullet}g^{-1}$, a shield composed of >85 wt% Cu results in optimal performance. In contrast, a shield composed of <10 wt% Cu is anticipated to perform best against electron irradiation when ${\frac{E}{AD}}<2MeV{\bullet}cm{\bullet}g^{-1}$.

• 한국수소및신에너지학회논문집
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• 제14권2호
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• pp.155-170
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• 2003

$Cu-Ce/{\gamma}-Al_2O_3$ based catalysts were prepared and tested for selective oxidation of CO in a $H_2$-rich stream(1% CO, 1% $O_2$, 60% $H_2$, $N_2$ as balance). The effects of Cu loading and weight ratio(=Cu/(Cu+Ce)) upon both activity and selectivity were investigated upon the change in temperatures, It was also examined how the activity and selectivity of catalysts were varied with the presence of $CO_2$ and $H_2O$ in the reactant feed. Among the various Cu-Ce catalysts with different catalytic metal composition, Cu-Ce(4 : 16 wf%) /${\gamma}-Al_2O_3$ catalyst showed the highest activity(>$T_{99}$) and selectivities(50-80%) under wide range of temperatures($175-220^{\circ}C$). However, in the Cu-Ce(4 : 16 wt%)/ ${\gamma}-Al_2O_3$, the presence of $CO_2$ and $H_2O$ in the reactant feed decreased the activity and the maximum activity(>$T_{99}$) in terms of reaction temperature moved by about $25^{\circ}C$ toward higher temperature, the $T_{>99}$ window was seen between $210-230^{\circ}C$ (selectivity 50-75%). From $CO_2-/H_2O-TPD$, it can be concluded that the main cause for the decrease in catalytic activity may be attributed to the blockage of the active sites by competitive adsorption of water vapor and $CO_2$ with the reactant at low temperatures.

• 한국지반공학회논문집
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• 제34권2호
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• pp.5-17
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• 2018

본 연구에서는 연약지반에서의 재하/제하에 대한 안정해석과 응력-변형 해석시 전단 파라미터(UU; Unconsolidated Undrained, CU; Consolidated Undrained(전응력), ${\bar{CU}}$ ; Consolidated Undrained(유효응력))에 따른 초기 지중응력, 강도, 응력-변형 특성을 평가하였다. 시공단계를 고려한 유한요소 해석시 입력하는 전단 파라미터에 따라 초기 지중응력과 이후 해석 결과가 달라질 수 있음을 확인하였다. 특히, Mohr-Coulomb 모델의 입력 파라미터인 내부마찰각(Phi)을 0으로 입력하여 초기 지중응력과 이후 응력-변형 거동을 해석할 경우 잘못된 결과를 도출 할 수 있다는 것을 확인하였다. 전응력 파라미터, CU를 초기 및 전단시 일괄 적용한 해석과 유효응력 파라미터, CU에서 전응력 파라미터, CU로 변경한 해석 결과가 큰 차이를 보이지 않았다. 따라서, 연약지반에 대한 수치해석시 CU 파라미터를 적용하여도 초기 지중응력과 이후 응력-변형 거동에 큰 차이 없이 예측할 수 있음을 알 수 있었다. 또한, 실무에서 적용하기 편한 방법으로 실제 흙의 거동과 동일한 강도를 갖는 Mohr-Coulomb 모델의 전단 파라미터를 산정하는 방법을 제안하였다.

• 청정기술
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• 제6권1호
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• pp.17-25
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• 2000

상압유통식 고정층반응기를 이용하여 전이금속을 ALO-6에 담지한 촉매상에서 휘발성유기화합물인 벤젠, 톨루엔, 자일렌의 촉매산화에 관하여 조사하였다. 15% 전이금속/ALO-6 촉매상에서 톨루엔의 완전산화반응에 대한 활성의 크기는 Cu>Mn>Fe>V>Mo>Co>Ni>Zn의 순서였다. 15% Cu/ALO-6 촉매에서 소성온도의 증가는 비표면적을 감소시켰고 결과적으로 활성은 감소하였다. Cu/ALO-6촉매계에서 Cu의 담지량이 5%일 때 활성이 우수하였다. 5% Cu/ALO-6촉매상에서 벤젠, 톨루엔, 자일렌은 반응온도 $380^{\circ}C$, 접촉시간 4.5 g-cat.hr./g-mole 이상일 때 이산화탄소로 완전산화 되었다. 반응물에 따른 활성순서는 톨루엔>자일렌>벤젠 이었다. 반응물의 농도가 증가함에 따라 self-poison 에 기인하여 활성은 감소하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.342-347
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• 2004

The deformation behavior of a $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass under tensile loading at different range of strain rates and temperatures between 680 K and 740 K were investigated. The variation in the deformation behavior of $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass which resulted from the crystallization induced during testing was reported. The$Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass has showed either homogeneous or inhomogeneous deformation depending on test condition. It exhibited a maximum elongation of about 560 % at the condition of $407^{\circ}C{\times}\;10^{-4}/s$. The flow behavior exhibited three different types and the flow stress became lower at higher temperatures and lower strain rates. The increase of the time elapsed during heating resulted in the partial crystallization of bulk metallic glass phase and eventually strain hardening and brittle fracture.

• 한국표면공학회지
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• 제43권2호
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• pp.64-72
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• 2010

CuSnZn electroplating was investigated as alternative to Ni plating. Evaluation of electrolyte and plating process was performed to control physical characteristics of the film, and to collect practical data for application. Hull-cell test was conducted for basic comparison of two commercialized products and developed product. Based on hull-cell test results, long term test of three electrolytes was performed. Various analysis on long term tested electrolyte and samples have been done. Reliable and practical data was collected using FE-SEM (FEI, Sirion), EDX (ThermoNoran SIX-200E), ICP Spectrometer (GBC Scientifi c, Integra XL), FIB (FEI, Nova600) for anlysis. Physical analysis and reliability test of the long term tested film were also carried out. Through this investigation plating time, plating speed, electrolyte composition, electrolyte metal consumption, hardness and corrosion resistance has been compared. This set of data is used to predict and control the chemical composition of the film and modify the physical characteristics of the CuSnZn alloy.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.57-64
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• 2020

The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h^-1 over the Cu-Nb-CeO₂ catalysts prepared by co-precipitation method. In order to investigate the effect of Nb₂O₅ promotion over a Cu-CeO₂ catalyst, the Nb₂O₅ loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO₂ (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO₂ selectivity. The high activity and stability of Cu-Nb-CeO₂ (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.333-337
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• 2008

This study investigates crack propagation behavior of Sn-3.0Ag-0.5Cu solder under pull-push loading conditions. Fatigue Crack Growth (FCG) tests were conducted on Center Cracked Plate (CCP) specimens in fast-fast (pp) strain waveform. The fast-slow (pc), slow-fast (cp) and slow-slow (cc) strain waveforms were also used to study the effect of strain rates. The crack propagation rates for the four strain waveforms were correlated with J-integral range and a scatter band of factor 4 was found. The crack growth rates for the pc waveform was highest, followed by cp, cc and then pp waveforms.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2000년도 춘계학술대회 논문집
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• pp.250-257
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• 2000

A Helmholtz free energy for a martensitic transformation of a single crystalline shape-memory alloy is obtained by a micromechanical approach, 24 variants of the single crystal are taken into account. In the framework of irreversible thermodynamics, a kinetic relation, a martensitic nucleation criterion and the reorientation criterion of martensitic variants are obtained. These relations are valid for a three-dimensional proportional or non-proportional mechanical loading or a combination of mechanical and thermal loading. Reorientation behavior of a single crystalline shape-memory alloy CuZnAl is simulated. When a tensile load is applied to a thermally-induced martensite, 24 self-accommodated martensitic variants are reoriented to the most favorable variant. In the following unloading, the most favorable variant in the tensile load is reoriented to the most favorable variant in this loading condition.