• Title/Summary/Keyword: Cu hybrid structure

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Synthesis, Characterization and Magnetic Properties of a Novel Disulfonate-pillared Copper Hydroxide Cu2(OH)3(DS4)1/2, DS4 = 1,4-Butanedisulfonate

  • Park, Seong-Hun;Lee, Cheol-Eui
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1587-1592
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    • 2006
  • We report the preparation, structure and magnetic properties of a new pillared complex, copper(II) hydroxy-1,4-butanedisulfonate, $Cu_2(OH)_3(O_3SC_4H_8SO_3)_{1/2}$. The titled compound was obtained by anion exchange, using copper hydroxyl nitrate $(Cu_2(OH)_3NO_3)$ as the starting material. According to the XRD data, this compound exhibits a pillared layered structure with organic layers tilted between the copper hydroxide layers with a tilt angle of $21.8^{\circ}$. FTIR spectroscopy confirms total exchange of nitrate by the sulfonate and indicates that the sulfonate functions are linked to the copper(II) ions with each aliphatic chain bridging the adjacent hydroxide layers. According to the dc and ac magnetic measurements, the title compound is a metamagnet consisting of spin-canted antiferromagnetic layers, with a Neel temperature of 11.8 K.

Operating Characteristics of Hybrid Type Superconducting Fault Current Limiter (하이브리드형 초전도 한류기의 동작 특성)

  • Cho, Yong-Sun;Nam, Gueng-Hyun;Lim, Sung-Hun;Choi, Hyo-Sang
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.55 no.6
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    • pp.255-258
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    • 2006
  • We investigated the operating characteristics of the hybrid-type superconducting fault current limiter (SFCL) according to the inductance of secondary windings. The hybrid type SFCL consists of a transformer that has a primary winding and a secondary winding with serially connected $YBa_2Cu_3O_7$ (YBCO) films. The resistive-type SFCL has difficulty when it comes to raising the capacity of the SFCL due to slight differences of critical current densities between units and structure of the SFCL. The hybrid-type SFCL with closed-loop is able to achieve capacity increase through the electrical isolation and reduction of the inductance of the secondary winding with a superconducting element of the same critical current. On the other hand, the current limiting characteristics were nearly identical in the hybrid-type SFCL with open-loop compared to closed-loop, but quench time was longer than the hybrid-type SFCL with closed-loop. We confirmed that the capacity of the SFCL was increased effectively by the reduced inductance of the secondary winding. In addition, the power burden of the system also could be lowered by reducing the inductance of secondary winding.

Structural analysis and thermal expansion property of Cu doped LSM for SOFCs (Cu가 도핑된 LSM의 구조분석과 열팽창특성 연구)

  • Noh, Tai-Min;Ryu, Ji-Seung;Kim, Jin-Seong;Jeong, Cheol-Weon;Lee, Hee-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.4
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    • pp.175-180
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    • 2011
  • The doping effect of Cu in the Sr-doped lanthan manganites (LSM) has been investigated in terms of structural analysis and thermal expansion coefficient (TEC). The $La_{0.8}Sr_{0.2}Mn_{1-x}Cu_xO_3$ ($0{\leq}x{\leq}0.3$) were prepared by solid state reaction method and their crystal structure and TEC were measured. A decrease in the lattice parameters and the TEC were observed with increase eu content, whereas they were decreased for x = 0.3. For $0{\leq}x{\leq}0.2$, the decrease of the lattice parameter and the TEC with increase Cu content were attributed to the reduction of ionic radius of Cu ions due to the presence of $Cu^{3+}$ ions. For x = 0.3, however, the increase was originated from the formation of oxygen vacancies due 10 the presence of $Cu^{2+}$ and $Mn^{4+}$.

A study on the synthesis and formation behavior of nanostructrued TiN films by metal doping (금속원소 도핑에 따른 초고경도 나노구조 TiN 박막의 합성 및 형성 거동에 관한 연구)

  • 명현식;한전건
    • Journal of the Korean Vacuum Society
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    • v.12 no.3
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    • pp.193-199
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    • 2003
  • Ti-Cu-N and Ti-Ag-N nanocomposite films with various copper and silver contents were synthesized by arc ion plating and magnetron sputtering hybrid system. The structure and mechanical properties of these films were found to be dependant on the copper and silver concentration. The maximum hardness of Ti-Cu-N and Ti-Ag-N films showed approximately 40 ㎬ below 2 at%Me. The role of soft metallic phase in Ti-Me-N nanosturctured films containing one hard and one soft phase is also discussed.

Development of Carbon Nanotube-copper Hybrid Powder as Conductive Additive

  • Lee, Minjae;Ha, Seoungjun;Lee, Yeonjoo;Jang, Haneul;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.291-295
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    • 2018
  • A conductive additive is prepared by dispersing multi-walled carbon nanotubes (MWCNTs) on Cu powder by mechanical milling and is distributed in epoxy to enhance its electrical conductivity. During milling, the MWCNTs are dispersed and partially embedded on the surface of the Cu powder to provide electrically conductive pathways within the epoxy-based composite. The degree of dispersion of the MWCNTs is controlled by varying the milling medium and the milling time. The MWCNTs are found to be more homogeneously dispersed when solvents (particularly, non-polar solvent, i.e., NMP) are used. MWCNTs gradually disperse on the surface of Cu powder because of the plastic deformation of the ductile Cu powder. However, long-time milling is found to destroy the molecular structure of MWCNTs, instead of effectively dispersing the MWCNTs more uniformly. Thus, the epoxy composite film fabricated in this study exhibits a higher electrical conductivity than 1.1 S/cm.

Novel Two-dimensional Network Based on Amino-acid-octamolybdate Bridged by Second Metals: {M(H2O)3(pro)Mo4O13}2·2H2O (pro = proline, M = Co, Ni, Cu, Zn)

  • Wu, Xiao-Yuan;Lu, Can-Zhong;Xia, Chang-Kun;Chen, Shu-Mei;Liu, Jiu-Hui;Chen, Li-Juan;Yang, Wen-Bin
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1206-1210
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    • 2006
  • Four isostructural amino-acid-based polyoxomolybdates, {$M(H_2O)_3(pro)Mo_4O_{13}$}$_2{\cdot}2H_2O$ (pro = proline, M = Co (1), Ni (2), Cu (3), Zn (4)), have been synthesized and structurally characterized by single crystal X-ray diffraction, elemental analysis, IR spectrum, TG analysis. The structures of 1-4 are layered networks built up from {$Mo_8O_{26}(pro)_2$}$^{4-}$ units and {$M(H_2O)_3O_3$} octahedra, the uncoordinated water molecules occupying the interlayer regions.

A New Fabrication Method of Aluminum Nanotube Using Anodic Porous Alumina Film as a Template

  • Sung, Dae Dong;Choo, Myung Sook;Noh, Ji Seok;Chin, Won Bai;Yang, Woo Sung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1159-1163
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    • 2006
  • Aluminum nanotube has been fabricated by a physical vapor deposition/atmospheric pressure injection using an anodic porous alumina film as a template. The pore external-, and inside diameters and the length of the aluminum nanotubes fabricated by this method are 60 nm, 35 nm and 2 $\mu$m, respectively. The structure of the fabricated aluminum nanotubes was examined by a kind of chemical treatment as extraction of copper on the cross-sectional area of these aluminum tubes in a mixed solution of $CuCl_2$ and HCl by difference of ionization tendency between aluminum and copper. The composition of the aluminum nanotube was identified by the two dimensional Hybrid Plasma Equipment Model (HPEM) employing the inductively coupled plasma.

The Formation of Hybridized Porous Structure of Al Alloy by Alkali Surface Modification (알칼리 표면개질을 통한 다공성 알루미늄 합금의 하이브리드 기공구조 형성)

  • Seo, Young-Ik;Kim, Young-Moon;Lee, Young-Jung;Kim, Dae-Gun;Lee, Kyu-Hwan;Kim, Young-Do
    • Journal of Powder Materials
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    • v.16 no.1
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    • pp.22-27
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    • 2009
  • To improve the filtration efficiency of porous materials used in filters, an extensive specific surface area is required to serve as a site for adsorption of impurities. In this paper, a method for creating a hybridized porous alloy using a powder metallurgical technique to build macropores in an Al-4 wt.% Cu alloy and subsequent surface modification for a microporous surface with a considerably increased specific surface area is suggested. The macropore structure was controlled by granulation, compacting pressure, and sintering; the micropore structure was obtained by a surface modification using a dilute NaOH solution. The specific surface area of surface-modified specimen increased about 10 times compare to as-sintered specimen that comprised of the macropore structure. Also, the surface-modified specimens showed a remarkable increase in micropores larger than 10 nm. Such a hybridized porous structure has potential for application in water and air purification filters, as well as membrane pre-treatment and catalysis.

Magnetoresistance Properties of Hybrid GMR-SV Films with Nb Buffer Layers (Nb 버퍼층과 거대자기저항-스핀밸브 하이브리드 다층박막의 자기저항 특성)

  • Yang, Woo-Il;Choi, Jong-Gu;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.27 no.3
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    • pp.82-86
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    • 2017
  • The IrMn based GMR-SV films with three different buffer layers were prepared on Corning glass by using ion beam deposition and DC magnetron sputtering method. The major and minor magnetoresistance curves for three different buffer layers beneath the structure of NiFe(15 nm)/CoFe(5 nm)/Cu(2.5 nm)/CoFe(5 nm)/NiFe(7 nm)/IrMn(10 nm)/Ta(5 nm) at room temperature have shown different magnetoresistance properties. When the samples were annealed at $250^{\circ}C$ in vacuum, the magnetoresistance ratio, the coercivity of pinned ferromagnetic layer, and the interlayer coupling field of free ferromagnetic layer were enhanced while the exchange bias coupling field did not show noticeable changes.

Application of Adaptive Loop Filter for NRT-Based Stereoscopic Video Coding (비실시간 기반 스테레오스코픽 비디오 부호화를 위한 적응루프필터 적용기법)

  • Lee, Byung-Tak;Lee, BongHo;Choi, Haechul;Kim, Jin-Soo;Yun, Kugjin;Cheong, Won-Sik;Kim, Jae-Gon
    • Journal of Broadcast Engineering
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    • v.18 no.2
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    • pp.261-270
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    • 2013
  • A stereoscopic 3D video service is able to provide a 3D video service while keeping backward compatibility with the existing 2D video service. In the terrestrial digital television (DTV) system, a stereoscopic video codec is required to have high coding efficiency in order to provide a 3D video service in the same channel capacity. A hybrid codec consisting of MPEG-2 for base video and H.264/AVC or HEVC for 3D auxiliary video is considered. Furthermore, Non-Real-Time (NRT) delivery of stereoscopic video is also considered as a service scenario for 3DTV services to overcome the limited bandwidth. In this paper, we propose a stereoscopic video coding scheme using adaptive loop filter (ALF) which had been considered in HEVC as a pre-/post-filter for enhancing coding efficiency in NRT-based 3DTV services. In order to apply ALF as a post-filter to the reconstructed additional view coded by H.264/AVC, we devise a method in which ALF is adaptively applied based on a structure determined by using macroblock (MB) coding information such as MB mode type and reference index instead of coding unit (CU) structure on which ALF is applied in the HEVC. Experimental results shows that the proposed stereoscopic video coding scheme applying ALF obtains up to 24.9% gain of bit saving.