Browse > Article
http://dx.doi.org/10.5012/bkcs.2006.27.10.1587

Synthesis, Characterization and Magnetic Properties of a Novel Disulfonate-pillared Copper Hydroxide Cu2(OH)3(DS4)1/2, DS4 = 1,4-Butanedisulfonate  

Park, Seong-Hun (Energy Nano Material Team, Korea Basic Science Institute (KBSI))
Lee, Cheol-Eui (Institute for Nano Science and Department of Physics, Korea University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.10, 2006 , pp. 1587-1592 More about this Journal
Abstract
We report the preparation, structure and magnetic properties of a new pillared complex, copper(II) hydroxy-1,4-butanedisulfonate, $Cu_2(OH)_3(O_3SC_4H_8SO_3)_{1/2}$. The titled compound was obtained by anion exchange, using copper hydroxyl nitrate $(Cu_2(OH)_3NO_3)$ as the starting material. According to the XRD data, this compound exhibits a pillared layered structure with organic layers tilted between the copper hydroxide layers with a tilt angle of $21.8^{\circ}$. FTIR spectroscopy confirms total exchange of nitrate by the sulfonate and indicates that the sulfonate functions are linked to the copper(II) ions with each aliphatic chain bridging the adjacent hydroxide layers. According to the dc and ac magnetic measurements, the title compound is a metamagnet consisting of spin-canted antiferromagnetic layers, with a Neel temperature of 11.8 K.
Keywords
Anion exchange reaction; Disulfonate; Triangular 2D magnetic system; Magnetism; Inorganic/organic hybrid layered structure;
Citations & Related Records

Times Cited By Web Of Science : 5  (Related Records In Web of Science)
Times Cited By SCOPUS : 6
연도 인용수 순위
1 Laget, V.; Drillon, M.; Hornick, C.; Trabu, P.; Romero, F.; Turek, P.; Ziessel, R. J. Alloys and Compounds 1997, 262-263, 423   DOI   ScienceOn
2 Yamanaka, S.; Sato, T.; Hattori, M. Chem. Lett. 1989, 1869
3 Yamanaka, S.; Sato, T.; Seki, K.; Hattori, M. Solid State Ionics 1992, 53-56, 527   DOI   ScienceOn
4 Liu, B.; Yu, S.-H.; Zhang, F.; Zhang, L.; Li, Q.; Ren, L.; Jiang, K. J. Phys. Chem. B 2004, 108, 4338   DOI   ScienceOn
5 Miyata, S.; Kumura, T. Chem. Lett. 1973, 843
6 Rabu, P.; Drillon, M.; Hornick, C. Analusis 2000, 28, 103   DOI   ScienceOn
7 Alberti, G. In Comprehensive Supramolecular Chemistry; Lehn, J. M., Eds.; Pergamon: Elmsford, New York, 1996; Vol. 7, p 151
8 Clearfield, A. Progr. Inorg. Chem. 1998, 47, 371
9 Mitzi, D. M. Progr. Inorg. Chem. 1999, 48, 1   DOI
10 Kurmoo, M. J. Mater. Chem. 1999, 9, 2595   DOI   ScienceOn
11 Huang, Z.-L.; Drillon, M.; Masciocchi, N.; Sironi, A.; Zhao, J.-T.; Rabu, P.; Panissod, P. Chem. Mater. 2000, 12, 2805   DOI   ScienceOn
12 de Jongh, L. J. Magnetic Properties of Layered Transition Metal Complexes; Kluwer Academic Publishers: Dordrecht, 1990
13 Laget, V.; Hornick, C.; Rabu, P.; Drillon, M.; Ziessel, R. Coord. Chem. Rev. 1998, 178-180, 1533   DOI   ScienceOn
14 Park, S.-H.; Kim, H. J. J. Am. Chem. Soc. 2004, 126, 14368   DOI   ScienceOn
15 Huh, Y.-D.; Kwon, S.-S. Bull. Korean Chem. Soc. 2005, 26, 2054   DOI   ScienceOn
16 Fan, W.; Sun, S.; Song, X.; Zhang, W.; Yu, H.; Tan, X.; Cao, G. J. Solid State Chem. 2004, 177, 2329   DOI   ScienceOn
17 Fan, W.; Sun, S.; You, L.; Cao, G.; Song, X.; Zhang, W.; Yu, H. J. Mater. Chem. 2003, 13, 3062   DOI   ScienceOn
18 Rabu, P.; Angelov, S.; Logoll, P.; Belaiche, M.; Drillon, M. Inorg. Chem. 1993, 32, 2463   DOI   ScienceOn
19 Rouba, S.; Rabu, P.; Ressouche, E.; Regnault, L.-P.; Drillon, M. J. Magn. Magn. Mater. 1996, 163, 365   DOI   ScienceOn
20 Laget, V.; Rouba, S.; Hornick, C.; Drillon, M. J. Magn. Magn. Mater. 1996, 154, L7   DOI   ScienceOn
21 Rouba, S.; Rabu, P.; Ressouche, E.; Regnault, L.-P.; Drillon, M. J. Magn. Magn. Mater. 1996, 163, 365   DOI   ScienceOn
22 Laget, V.; Hornick, C.; Rabu, P.; Drillon, M.; Ziessel, R. Coord. Chem. Rev. 1998, 178-180, 1533.   DOI   ScienceOn
23 Fujita, W.; Awaga, K. Inorg. Chem. 1996, 35, 1915   DOI   ScienceOn
24 Fujita, W.; Awaga, K.; Yokoyama, T. Inorg. Chem. 1997, 36, 196   DOI   ScienceOn
25 Cao, G.; Hong, H.; Mallouck, T. Acc. Chem. Res. 1992, 25, 420   DOI
26 Fujita, W.; Awaga, K. J. Am. Chem. Soc. 1997, 119, 4563   DOI   ScienceOn
27 Fujita, W.; Awaga, K.; Yokoyama, T. Appl. Clay Sci. 1999, 15, 281   DOI   ScienceOn
28 Girtu, M.; Wynn, C. M.; Fujita, W.; Awaga, K.; Epstein, A. J. J. Appl. Phys. 1998, 83, 7378   DOI   ScienceOn
29 Hornick, C.; Rabu, P.; Drillon, M. Polyhedron 2000, 19, 259   DOI   ScienceOn
30 Girtu, M.; Wynn, C. M.; Fujita, W.; Awaga, K.; Epstein, A. J. Phys. Rev. 1998, B57, R11058
31 Girtu, M.; Wynn, C. M.; Fujita, W.; Awaga, K.; Epstein, A. J. Phys. Rev. 2000, B61, 4117
32 Laget, V.; Hornick, C.; Rabu, P.; Drillon, M.; Turek, P.; Ziessel, R. Adv. Mater. 1998, 10, 1024   DOI   ScienceOn
33 Kurmoo, M. Chem. Mater. 1999, 11, 1546   DOI   ScienceOn
34 Kurmoo, M. Chem. Mater. 1999, 11, 3370   DOI   ScienceOn
35 Kurmoo, M.; Day, P.; Derory, A.; Estoures, C.; Poinsot, R.; Stead, M. J.; Kepert, C. J. J. Sol. State Chem. 1999, 145, 452   DOI   ScienceOn
36 Taibi, M.; Ammar, S.; Jouini, N.; Fievet, F.; Molinie, P.; Drillon, M. J. Mater. Chem. 2002, 12, 3238   DOI   ScienceOn
37 Park, S.-H.; Lee, C. H.; Lee, C. E.; Ri, H.-C.; Shim, S. Y. Mater. Res. Bull. 2002, 37, 1773   DOI   ScienceOn
38 Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley & Sons: New York, 1997
39 Colthup, N. B. Introduction to Infrared and Raman Spectroscopy, 3rd ed.; Academic Press: 1990
40 Effenberger, H. Z. Kristallogr. 1983, 165, 127   DOI
41 Rabu, P.; Drillon, M. Adv. Eng. Mater. 2003, 5, 189   DOI   ScienceOn
42 Carlin, R. L. Magnetochemistry; Springer-Verlag: Berlin-Heidelberg, 1986
43 Eltner, N.; Singh, R. R. P.; Young, A. P. Phys. Rev. Lett. 1993, 71, 1629   DOI   ScienceOn
44 Takeda, T.; Bando, Y.; Kiyama, M.; Miyamoto, H. J. Phys. Soc. Jpn. 1966, 21, 2726   DOI
45 Takeda, T.; Bando, Y.; Kiyama, M.; Miyamoto, H. J. Phys. Soc. Jpn. 1966, 21, 2745   DOI
46 Miyamoto, H.; Shinjo, T.; Bando, Y.; Takeda, T. J. Phys. Soc. Jpn. 1967, 23, 1421   DOI
47 Drillon, M.; Panissod, P. J. Magn. Magn. Mater. 1998, 188, 93   DOI   ScienceOn
48 Tarte, P. Spectrochim. Acta 1958, 13, 107   DOI   ScienceOn
49 Rabu, P.; Rouba, S.; Laget, V.; Hornick, C.; Drillon, M. J. Chem. Soc., Chem. Comm. 1996, 1107
50 Fujita, W.; Awaga, K.; Yokoyama, T. Appl. Clay Sci. 1999, 15, 281   DOI   ScienceOn
51 Laget, V.; Hornick, C.; Rabu, P.; Drillon, M. J. Mater. Chem. 1999, 9, 169   DOI   ScienceOn
52 Park, S.-H.; Lee, C. E. J. Phys. Chem. 2005, B109, 1118