• Restorative Dentistry and Endodontics
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• v.36 no.2
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• pp.139-148
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• 2011

Objectives: This study investigated the effect of the strength and wetting characteristics of adhesives on the bond strength to dentin. The experimental adhesives containing various ratios of hydrophobic, low-viscosity Bis-M-GMA, with Bis-GMA and TEGDMA, were made and evaluated on the mechanical properties and bond strength to dentin. Materials and Methods: Five experimental adhesives formulated with various Bis-GMA/Bis-MGMA/TEGDMA ratios were evaluated on their viscosity, degree of conversion (DC), flexural strength (FS), and microtensile bond strength (MTBS). The bonded interfaces were evaluated with SEM and the solubility parameter was calculated to understand the wetting characteristics of the adhesives. Results: Although there were no significant differences in the DC between the experimental adhesives at 48 hr after curing (p > 0.05), the experimental adhesives that did not contain Bis-GMA exhibited a lower FS than did those containing Bis-GMA (p < 0.05). The experimental adhesives that had very little to no TEGDMA showed significantly lower MTBS than did those containing a higher content of TEGDMA (p < 0.05). The formers exhibited gaps at the interface between the adhesive layer and the hybrid layer. The solubility parameter of TEGDMA approximated those of the components of the primed dentin, rather than Bis-GMA and Bis-M-GMA. Conclusions: To achieve a good dentin bond, a strong base monomer, such as Bis-GMA, cannot be completely replaced by Bis-M-GMA for maintaining mechanical strength. For compatible copolymerization between the adhesive and the primed dentin as well as dense cross-linking of the adhesive layer, at least 30% fraction of TEGDMA is also needed.

• Journal of the Korean Society of Food Science and Nutrition
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• v.38 no.6
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• pp.727-731
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• 2009

Effects of various plasticizers (1.5%) such as glycerol, sorbitol, fructose, sucrose, and polypropylene glycol, and ferulic acid on the physical properties of Gelidium corneum (GC) film were examined. GC films containing plasticizer and ferulic acid were prepared by incorporating various amounts (10, 30, 50, 70, 100 mg/100 mL) of ferulic acid into the film. Water vapor permeability (WVP) of the GC film varied depending on the type of plasticizer, and among them the film containing sucrose had the lowest WVP. Tensile strength (TS) and % elongation (%E) of the film were in the range of $1.29{\sim}11.29$ MPa and $5.55{\sim}36.44$ %, respectively, and the WVP values were of $1.30{\sim}1.60\;ng\;m/m^{2}sPa$. In addition, the GC films were prepared using ferulic acid as a cross-linking agent. WVP of the film decreased with the addition of ferulic acid, and the film containing 30 mg ferulic acid had the lowest WVP value. TS value of the GC film containing 10 mg of ferulic acid was significantly higher than that of the control. However, further increase of ferulic acid concentration decreased the TS value. Therefore, 10 mg of ferulic acid was determined to be the optimal concentration for the film.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.433-442
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• 2021

In this study, the properties of no-fines polymer concrete with different polymer binder contents were evaluated. The polymer concrete was formulated using a polymeric binder (unsaturated polyester resin), fly ash, and recycled coarse aggregate (60%) and crushed coarse aggregate (40%). The polymeric binder content (4.0-6.0wt.%) was used as an experimental variable because it dramatically affects both the cost-effectiveness and material properties. The results showed that the density, compressive strength, flexural strength both before and after exposure to freezing and thawing increased as the polymer binder content increased, while the absorption, void ratio, permeable voids, coefficient of permeability, and acid resistance (mass loss by acid attack) decreased as the polymeric binder content increased. In particular, even though the void ratio was 18.4% and the water permeability coefficient was 7.3mm/sec, the compressive strength and flexural strength were as high as 38.0MPa and 10.0MPa, respectively, much more significant than those of previous studies. Other properties such as absorption and acid resistance were also found to be excellent. The results appear to be rooted in the increased adhesion of the binder by adding a cross-linking agent and the surface hydrophobicity of the polymer.

• Journal of Life Science
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• v.29 no.3
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• pp.382-393
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• 2019

Wound care is a health industry concern affecting millions worldwide. Recent increase in metabolic disorders such as diabetes comes with elevated risk of wound-based complications. Treatment and management of wounds are difficult practices due to complexity of the wound healing process. Conventional wound dressings and treatment applications only provide limited benefits which are mainly aimed to keep wound protected from external factors. To improve wound care, recent developments make biopolymers to be of high interest and importance to researchers and medical practitioners. Biopolymers are polymers or natural origin produced by living organisms. They are credited to be highly biocompatible and biodegradable. Currently, studies reported biopolymers to exhibit various health beneficial properties such as antimicrobial, anti-inflammatory, hemostatic, cell proliferative and angiogenic activities which are crucial for effective wound management. Several biopolymers, namely chitosan, cellulose, collagen, hyaluronic acid and alginic acid have been already investigated and applied as wound dressing agents. Different derivatives of biopolymers have also been developed by cross-linking with other molecules, grafting with other polymers, and loading with bioactive agents or drugs which showed promising results towards wound healing without any undesired outcome such as scarring and physiological abnormalities. In this review, current applications of common biopolymers in wound treatment industry are highlighted to be a guide for further applications and studies.

• Journal of Korean Library and Information Science Society
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• v.54 no.1
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• pp.45-68
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• 2023

This study aims to investigate the awareness and experiences of domestic researchers regarding data publishing, which has been recognized as a new channel of data sharing as scholarly communication evolves in the open science environment. A survey is conducted among researchers from five government-funded research institutes in the field of science and technology and members of the GeoAI Data Society to confirm the awareness of data publishing. As a result of the study, domestic researchers recognized providing explanations for data, stable access to data, citation, and quality assurance through peer review as the advantages of data journals. On the contrary, a low level of recognition for data paper as one of the research outputs was presented. With regard to the properties of data publication, the respondents answered that the data description, metadata description, and permanent identifiers are highly related, however, their recognition of the relation between the properties of data publication and the data submission to a repository and data peer review was relatively low. Finally, to expand the data publication, the need for the development of an editorial system that supports data paper peer review and cross-linking to a data repository as well as the development of a repository that supports data citation was identified. This study on the domestic researchers' experience and awareness of data publishing can provide insights for the implementation of data publishing services and infrastructure in the future.

• Journal of the Korean GEO-environmental Society
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• v.24 no.9
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• pp.5-13
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• 2023

Cement-based reinforcement materials, which are representative slope reinforcement materials, can cause contamination of ground and groundwater when ground injection or surface application is applied. Accordingly, slope reinforcement materials using eco-friendly biopolymers are attracting attention as a means of replacing existing materials, but the biopolymers currently used are easily dissolved when exposed to groundwater or rainfall environments, reducing strength. In order to solve this problem, the cross-linking of protein between sodium casein and Transglutaminase (TGase, C₂₀H₁₆N₄O₂S₂) was used to increase the water resistance of biopolymers, and a rainfall slope test was conducted to evaluate their usability and applicability as a slope reinforcing material. In the case of reinforcement with only sodium casein, the precipitation dissolved sodium casein, and the slope was completely destroyed in 1 hour. On the other hand, it was observed that the slope reinforced by adding a small amount of TGase (0.5%) do not collapse even after 80 hours of rainfall duration due to increased water resistance. Strength and water resistance increases due to the addition of a small amount of TGase, and its applicability as an eco-friendly reinforcement is confirmed.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.3D
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• pp.407-415
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• 2008

This study presents the methodology to link with aerial photos for advancing the accuracy of topographic survey data that is used to calculate water volume in urban stream. First, GIS spatial interpolation technique as Inverse Distance Weight (IDW) and Kriging was applied to construct the terrain morphology to the sand-bar and grass area using cross-sectional survey data, and also validation point data was used to estimate the accuracy of created topographic data. As the result of comparison, IDW ($d^{-2}_{ij}$, 2nd square number) in Sand-bar area and Kriging Spherical model in grass area showed more efficient results in the construction of topographic data of river boundary. But the differences among interpolation methods are very slight. Image classification method, Minimum Distance Method (MDM) was applied to extract sand-bar and grass area that are located to river boundary efficiently and the elevation value of extracted layers was allocated to the water level point value. Water volume with topographic data from aerial photos shows the advanced accuracy of 13% (in sand-bar) and 12% (in grass) compared to the water volume of original terrain data. Therefore, terrain analysis method in river linking with aerial photos is efficient to the monitoring about sand-bar and grass area that are located in the downstream of Dam in flooding season, and also it can be applied to calculate water volume efficiently.

• Elastomers and Composites
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• v.37 no.4
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• pp.224-233
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• 2002

This study has investigated the flame retardant properties of EPDM rubber with the addition of various flame retardants. Carbon black, stearic acid, zinc oxide cross-linking agent were mixed with EPDM rubber to produce the base rubber E0 without the addition of flame retardants. Phosphorus flame retardant Tricrecyl phosphate(TCP) was added to E0 in 0.5, 1, 1.5, 2 phr to make E1~E4 samples and red phosphorus was added in 3, 6, 9, 12 phr to make E5~E8 samples. A flame retardant of the bromine family Decabromodiphenyloxide(DBDPO), and a chlorinated paraffin retardant of the chlorine family was added to E0 in 3, 6, 9, 12 phr to make E9~E12 and E13~E16 samples, repectively. Basic physical properties such as tensile strength, tear strength and hardness were measured for all the rubber samples with various flame retardant additions. There was no substantial differences. On the other hand, Oxygen index and UL94 were measured to study flame retardant properties. From oxygen index measurements E0 sample showed a value of 23.5%, indicating the improvement of flame retardant properties. Also from UL94 measurements, it was found that addition of red phosphorus resulted in maximum flame retardant effect. It was found that increasing the amount of addition resulted in decreasing combustion rate and improving flame retardant effect regardless of the kind of flame retardant.

• Journal of the Korean Chemical Society
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• v.67 no.6
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• pp.420-428
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• 2023

Crosslinking was introduced into vinylized-mesoporous silica and recycled polyethylene. By introducing a vinyl group into the mesoporous silica, it becomes a material capable of inducing cross-linking with non-polar polyethylene. By synthesizing vinylized-mesoporous silica and inducing crosslinking with recycled polyethylene, a recycled polyethylene composite with improved physical properties than existing recycled polyethylene was synthesized. In addition, even when a small amount is added according to the grade of recycled polyethylene using vinylized-mesoporous silica, the crosslinking reaction proceeds and all physical properties are improved. Four types of vinylized-mesoporous silica were synthesized, and the shape, microstructure, and functional groups were analyzed by TEM, BET, FT-IR, and XRD. Using vinylized-mesoporous silica, three types of compounds were blended by crosslinking reaction with recycled polyethylene. In order to confirm the presence or absence of crosslinking, analysis was performed using XPS and FT-IR, and physical properties such as tensile strength, elongation, flexural strength, and flexural modulus were confirmed using a universal testing machine. As a result, by applying vinylized-mesoporous silica to recycled polyethylene in various grades, the weak physical properties of existing recycled polyethylene were overcome. By applying the vinylized-mesoporous silica, recycled polyethylene composite material that overcomes the weak physical properties to the normal polyethylene, it shows the optimal physical property index that can be used commercially. Therefore, it is expected that it can potentially increase the use of recycled polyethylene and recycle resources.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.30 no.1
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• pp.63-72
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• 2024

Poly (butylene adipate-co-terephthalate) (PBAT) is one of the representative biodegradable polymers with high ductility and processability to replace petroleum-based polymers. Many investigations have been conducted to broaden the applications of PBAT in a variety of industries, including the food packaging, agricultural mulching film, and logistics and distribution fields. Foaming process is widely known technique to generate the cell structure within the polymer matrix, offering the insulation and light weight properties. However, there was no commercially feasible foam product based on biodegradable polymers, especially PBAT, and maintaining a proper melt viscosity of the polymer would be a key parameter for the foaming process. In this study, chemical foaming agent and cross-linking agent were introduced to PBAT, and a compression molding process was applied to prepare a foam sheet. The correlation between cell morphological structures and mechanical and physical properties was evaluated. It was found that PBAT with foam structures effectively reduced the density and thermal conductivity, allowing them to be suitable for applications such as insulation and lightweight packaging or cushion materials.