• Steel and Composite Structures
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• 제45권5호
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• pp.767-774
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• 2022

A geometrically nonlinear stability analysis of sandwich annular plates with cellular core and particle-reinforced composite layers has been performed in the present research. The particles are powders of graphene oxide (GOP) which act as nanoscale filler of epoxy matrix. To this regard, Halpin-Tsai micromechanical scheme has been used to define the material properties of the layers. A square shaped core has been considered for which the material properties have been defined based on the relative density concept. Large deflection theory of thin shells has been selected to develop the complete formulation of sandwich plate. The geometrically nonlinear stability analysis of sandwich annular plates has been carried out by indicating that the buckling load is dependent on particle amount, thickness of layer and core relative density.

• Steel and Composite Structures
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• 제48권3호
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• pp.263-273
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• 2023

This paper investigates dynamic characteristics of a graphene nanoplatelets reinforced composite (GNPRC) sandwich doubly curved shell based on the first-order shear deformation theory (FSDT) and Hamilton's principle. The sandwich doubly curved shell is fabricated from a core made of honeycomb materials sandwiched by composite GNPs reinforced face-sheets. Effective materials properties of composite face-sheets are assumed to vary based on Halpin-Tsai micromechanical models and rule of mixture. Furthermore, the material properties of honeycomb core are estimated using Gibson's formula. The fundamental frequencies of the shell are computed with changes of main geometrical and material properties such as amount and distribution type of graphene nanoplatelets, side length ratio, thickness to length ratio of and side length ratio of honeycomb. The Navier's technique is presented to obtain responses. Accuracy and trueness of the present model and analytical solution is confirmed through comparison of the results with available results in literature. It is concluded that an increase in thickness to length ratio yields a softer core with lower natural frequencies. Furthermore, increase in height to length ratio leads to significant decrease in natural frequencies.

• 공업화학
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• 제32권1호
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• pp.28-34
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• 2021

SiO2/Ag 코어-쉘 나노입자를 수정된 Stöber 공정법과 물/dodecylbenzenesulfonic acid (DDBA)/cyclohexane의 역 미셀에서 acetoxime을 환원제로 사용하는 역 미셀 방법을 상호 조합하여 합성하였다. SiO2/Ag 코어-쉘은 UV-visible spectroscopy, XRD, SEM 및 TEM을 사용하여 구조, 형태 및 크기를 조사하였다. SiO2/Ag 코어-쉘의 나노입자 크기는 [물]/[DDBA]의 몰비(WR)의 값을 조절하여 제어할 수 있었다. SiO2/Ag 코어-쉘의 크기와 다분산성은 WR 값이 증가함에 따라 증가하였다. 비정질 SiO2 나노입자 위에 생성된 Ag 나노입자는 430 nm에서 강한 표면 플라즈몬 공명 (SPR) 피크를 나타내었다. SPR 피크는 나노입자 크기의 증가에 따라 장파장으로의 적색 이동을 나타내었다. 합성된 SiO2/Ag 코어-쉘을 분산시켜 70 wt% 조성의 전도성 페이스트를 제조하고, 스크린 인쇄법으로 PET 필름에 코팅하여 전도성을 조사하였다. SiO2/Ag 코어-쉘 페이스트로 코팅된 필름은 상용 Ag 페이스트에 비하여 높은 460~750 µΩ/sq 영역의 표면저항을 나타내었다.

• Steel and Composite Structures
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• 제24권2호
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• pp.151-176
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• 2017

This paper deals with general equations of motion for free vibration analysis response of thick three-layer doubly curved sandwich panels (DCSP) under simply supported boundary conditions (BCs) using higher order shear deformation theory. In this model, the face sheets are orthotropic laminated composite that follow the first order shear deformation theory (FSDT) based on Rissners-Mindlin (RM) kinematics field. The core is made of orthotropic material and its in-plane transverse displacements are modeled using the third order of the Taylor's series extension. It provides the potentiality for considering both compressible and incompressible cores. To find these equations and boundary conditions, Hamilton's principle is used. Also, the effect of trapezoidal shape factor for cross-section of curved panel element ($1{\pm}z/R$) is considered. The natural frequency parameters of DCSP are obtained using Galerkin Method. Convergence studies are performed with the appropriate formulas in general form for three-layer sandwich plate, cylindrical and spherical shells (both deep and shallow). The influences of core stiffness, ratio of core to face sheets thickness and radii of curvatures are investigated. Finally, for the first time, an optimum range for the core to face sheet stiffness ratio by considering the existence of in-plane stress which significantly affects the natural frequencies of DCSP are presented.

• Smart Structures and Systems
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• 제25권4호
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• pp.471-486
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• 2020

Stability analysis of three-layered piezoelectric doubly curved nano shell with accounting size dependency is performed in this paper based on first order shear deformation theory and curvilinear coordinate system relations. The elastic core is integrated with sensor and actuator layers subjected to applied electric potentials. The principle of virtual work is employed for derivation of governing equations of stability. The critical electrical and mechanical buckling loads are evaluated in terms of important parameters of the problem such as size-dependent parameter, two principle angle of doubly curved shell and two parameters of Pasternak's foundation. One can conclude that mechanical buckling loads are decreased with increase of nonlocal parameter while the electrical buckling loads are increased.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 춘계학술대회 논문집
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• pp.266-267
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• 2007

Sandwich sheet with inner structure is expected to find many applications because of high stiffness to mass ratio. In order to simulate forming of sandwich sheet with pyramid core, an effective simulation method is required. Compared to the expensive model using solid elements, cost effective model using simplified elements such as shells and beams is developed. By comparing two models in terms of the cost and accuracy for unit cell deformation, a developed model shows some advantages over the model using solid elements. Evolution of two kind of forming limits, face buckling and core buckling are successfully expressed by developed model. Developed model is also applied in the simulation of square cup drawing and L-type bending. The corresponding experiments are carried out. Deformation shape and wrinkling behavior are compared and discussed. It is found that simulation results using a developed model are in good agreement with experiments.

• 공업화학
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• 제25권5호
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• pp.526-530
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• 2014

2,2'-Bis[4-(3,4-dicarboxyphenoxy) phenyl]propane dianhydride와 3,5-diamniobenzoic acid의 반응에 의해 얻어진 폴리에테르아미드산을 안정제로 사용하여 스티렌을 분산중합하여 폴리스티렌-폴리에테르아미드산 코어-셀 입자를 얻었다. 폴리에테르아미드산의 결합 효율을 증가시키기 위하여 4-vinylbenzyltrimethylammonium chloride를 공단량체로 사용하였다. 에탄올-물(7 : 3) 혼합용액을 반응매질로 사용했을 때 입자의 안정성 가장 높았고 입자의 크기도 비교적 균일하였다. 폴리스티렌-폴리에테르아미드산 코어-셀 입자의 크기는 스티렌의 양에 비례하여 증가하였다. Dimethylformamide-물 혼합용액에서 중합한 경우에는 입자의 크기 분포가 넓어졌다. 폴리스티렌-폴리에테르아미드산 코어-셀 입자의 셀을 화학적으로 이미드화 하여 폴리스티렌-폴리에테르이미드 코어-셀 입자로 변환시켰다.

• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2333-2337
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• 2012

We report the synthesis and thermal annealing of Si-core/ZnO-shell nanorods using a two-step process comprising the metal-assisted electroless etching of Si and the sputter deposition of ZnO. Transmission electron microscopy and X-ray diffraction analysis showed that the cores of the annealed core-shell nanorods were single crystal diamond cubic-type Si, whereas the shells of the annealed core-shell nanorods were single crystal wurtzite-type ZnO. The PL spectra of Si nanorods consisted of a broad red emission band and a weaker blue emission band. The major emission band of Si nanorods was shifted from 700 nm (in the red region) to 440 nm (in the violet region) by ZnO coating. The violet emission of the core-shell nanorods was enhanced in intensity considerably by annealing in an oxidizing atmosphere. The origin of the PL enhancement by annealing is also discussed.

• 한국분말재료학회지
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• 제26권6호
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• pp.463-470
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• 2019

Fe₃O₄/SiO₂/YVO₄:Eu³⁺ multifunctional nanoparticles are successfully synthesized by facile stepwise sol-gel processes. The multifunctional nanoparticles show a spherical shape with narrow size distribution (approximately 40 nm) and the phosphor shells are well crystallized. The Eu³⁺ shows strong photoluminescence (red emission at 619 nm, absorbance at 290 nm) due to an effective energy transfer from the vanadate group to Eu. Core-shell structured multifunctional nanoparticles have superparamagnetic properties at 300 K. Furthermore, the core-shell nanoparticles have a quick response time for the external magnetic field. These results suggest that the photoluminescence and magnetic properties could be easily tuned by either varying the number of coating processes or changing the phosphor elements. The nanoparticles may have potential applications for appropriate fields such as laser systems, optical amplifiers, security systems, and drug delivery materials.

• Steel and Composite Structures
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• 제43권2호
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• pp.241-256
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• 2022

In this article, an analytical procedure is presented for static analysis of composite cylinders with the geometrically nonlinear behavior, and non-uniform thickness profiles under different loading conditions by considering moderately large deformation. The composite cylinder includes two inner and outer isotropic layers and one honeycomb core layer with adjustable Poisson's ratio. The Mirsky-Herman theory in conjunction with the von-Karman nonlinear theory is employed to extract the governing equations which are a system of nonlinear differential equations with variable coefficients. The governing equations are solved analytically using the matched asymptotic expansion (MAE) method of the perturbation technique and the effects of moderately large deformations are studied. The presented method obtains the results with fast convergence and high accuracy even in the regions near the boundaries. Highlights: • An analytical procedure based on the matched asymptotic expansion method is proposed for the static nonlinear analysis of composite cylindrical shells with a honeycomb core layer and non-uniform thickness. • The effect of moderately large deformation has been considered in the kinematic relations by assuming the nonlinear von Karman theory. • By conducting a parametric study, the effect of the honeycomb structure on the results is studied. • By adjusting the Poisson ratio, the effect of auxetic behavior on the nonlinear results is investigated.