• 폴리머
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• 제26권2호
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• pp.227-236
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• 2002

열가역적인 polyvinylidene fluoride (PVDF)/propylene carbonate (PC) 의 매우 묽은 농도에서의 pregel 상태의 구조를 레이저 광산란법으로 조사한 결과 겔형성농도의 100배 이상 묽은 농도 조건에서도 PVDF 사슬은 낱개로 용해되어 있는 것이 아니라 많은 PVDF 사슬들이 응집된 거대한 구형 상태로 존재하며 이때의 응집체의 분산도는 상당히 낮으며 용액온도 $40^{\circ}C$에서 회전반경$R_G$ 는 232 nm, 동력학적 반경 $R_H$는 407 nm로 측정되었다. $R_H/R_G$=1.75의 커다란 비 값, 극소점을 갖는 정적 광산란 패턴 등으로부터 예측하건대 이 응집체의 구조는 core-shell 형태의 구형이며, 이때 내부 core의 반지름은 대략 215 nm, 외부 shell의 두께는 192 nm가 되며, shell 부분에서의 PVDF의 단량체 밀도는 core 부분의 단량체 밀도의 약 75% 수준에 머무르는 것으로 판명되었다.

• Smart Structures and Systems
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• 제30권2호
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• pp.121-133
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• 2022

An analytical approach for the free vibration behavior of a sandwich cylindrical shell with a functionally graded (FG) core is presented. It is considered that the FG distribution is in the direction of thickness. The material properties are temperature-dependent. The sandwich cylindrical shell with a FG core is considered with two cases. In the first model, i.e., Ceramic-FGM-Metal (CFM), the interior layer of the cylindrical shell is rich metal while the exterior layer is rich ceramic and the FG material is located between two layers and for the second model i.e., Metal-FGM-Ceramic (MFC), the material distribution is in reverse order. This study develops Carrera's Unified Formulation (CUF) to analyze sandwich cylindrical shell with an FG core for the first time. Considering the Principle of Virtual Displacements (PVDs) according to the CUF, the dependent boundary conditions and governing equations are obtained. The coupled governing equations are derived using Galerkin's method. In order to validate the present results, comparisons are made with the available solutions in the previous researches. The effects of different geometrical and material parameters on the free vibration behavior of a sandwich cylindrical shell with an FG core are examined.

• Steel and Composite Structures
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• 제48권3호
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• pp.263-273
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• 2023

This paper investigates dynamic characteristics of a graphene nanoplatelets reinforced composite (GNPRC) sandwich doubly curved shell based on the first-order shear deformation theory (FSDT) and Hamilton's principle. The sandwich doubly curved shell is fabricated from a core made of honeycomb materials sandwiched by composite GNPs reinforced face-sheets. Effective materials properties of composite face-sheets are assumed to vary based on Halpin-Tsai micromechanical models and rule of mixture. Furthermore, the material properties of honeycomb core are estimated using Gibson's formula. The fundamental frequencies of the shell are computed with changes of main geometrical and material properties such as amount and distribution type of graphene nanoplatelets, side length ratio, thickness to length ratio of and side length ratio of honeycomb. The Navier's technique is presented to obtain responses. Accuracy and trueness of the present model and analytical solution is confirmed through comparison of the results with available results in literature. It is concluded that an increase in thickness to length ratio yields a softer core with lower natural frequencies. Furthermore, increase in height to length ratio leads to significant decrease in natural frequencies.

• Journal of Electrical Engineering and Technology
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• 제1권3호
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• pp.302-307
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• 2006

The purpose of this paper is to develop an improved three-phase transformer model for ATP and parameter estimation methods that can efficiently utilize the limited available information such as factory test reports. In this paper, improved topologically-correct duality-based models are developed for three-phase autotransformers having shell-form cores. The problem in the implementation of detailed models is the lack of complete and reliable data. Therefore, parameter estimation methods are developed to determine the parameters of a given model in cases where available information is incomplete. The transformer nameplate data is required and relative physical dimensions of the core are estimated. The models include a separate representation of each segment of the core, including hysteresis of the core, ${\lambda}-i$ saturation characteristic and core loss.

• Structural Engineering and Mechanics
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• 제55권4호
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• pp.719-742
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• 2015

This paper dealt the free vibration analysis of thick truncated conical composite sandwich shells with transversely flexible cores and simply supported boundary conditions based on a new improved and enhanced higher order sandwich shell theory. Geometries were used in the present work for the consideration of different radii curvatures of the face sheets and the core was unique. The coupled governing partial differential equations were derived by the Hamilton's principle. The in-plane circumferential and axial stresses of the core were considered in the new enhanced model. The first order shear deformation theory was used for the inner and outer composite face sheets and for the core, a polynomial description of the displacement fields was assumed based on the second Frostig's model. The effects of types of boundary conditions, conical angles, length to radius ratio, core to shell thickness ratio and core radius to shell thickness ratio on the free vibration analysis of truncated conical composite sandwich shells were also studied. Numerical results are presented and compared with the latest results found in literature. Also, the results were validated with those derived by ABAQUS FE code.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2002년도 추계학술대회 논문집
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• pp.859-862
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• 2002

The Core Support Barrel (CSB) is a major component of Reactor Internals, and is designed to support and protect the Reactor Core. In this study, Reactor Core, Core Shroud and CSB were simplified to coaxial cylinders and then the offset of Reactor Core & Core Shroud to the dynamic characteristic of CSB was analyzed. For the beam modes, natural frequencies of the cantilevered cylinder are compared with those of the cantilevered beam. And it was found out that shear modulus must be used correctly to convert the shell model to the equivalent beam model. From the dynamic characteristics of the beam model, it was found out that natural frequencies are proportional to the length of Reactor Core & Core Shroud and inversely proportional to the mass. From the comparison with the dynamic characteristics of a beam model and a lumped-mass model it was found out that the size of lumped-mass must be determined considering both the length and the mass of Reactor Core & Core Shroud.

• Nuclear Engineering and Technology
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• 제47권2호
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• pp.165-175
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• 2015

The application of neutron noise analysis (NNA) to the ex-core neutron detector signal for monitoring the vibration characteristics of a reactor core support barrel (CSB) was investigated. Ex-core flux data were generated by using a nonanalog Monte Carlo neutron transport method in a simulated CSB model where the implicit capture and Russian roulette technique were utilized. First and third order beam and shell modes of CSB vibration were modeled based on parallel processing simulation. A NNA module was developed to analyze the ex-core flux data based on its time variation, normalized power spectral density, normalized cross-power spectral density, coherence, and phase differences. The data were then analyzed with a fuzzy logic module to determine the vibration characteristics. The ex-core neutron signal fluctuation was directly proportional to the CSB's vibration observed at 8Hz and15Hzin the beam mode vibration, and at 8Hz in the shell mode vibration. The coherence result between flux pairs was unity at the vibration peak frequencies. A distinct pattern of phase differences was observed for each of the vibration models. The developed fuzzy logic module demonstrated successful recognition of the vibration frequencies, modes, orders, directions, and phase differences within 0.4 ms for the beam and shell mode vibrations.

• Advances in environmental research
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• 제4권2호
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• pp.69-81
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• 2015

A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

• Advances in aircraft and spacecraft science
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• 제9권5호
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• pp.377-400
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• 2022

The aim of this work is a numerical comparison (FEM) between lattice pyramidal-core panel and honeycomb core panel for different core thicknesses. By evaluating the mid-span deflection, the shear rigidity and the shear modulus for both core types and different core thicknesses, it is possible to define which core type has got the best mechanical behaviour for each thickness and the evolution of that behaviour as far as the thickness increases. Since a specific base geometry has been used for the lattice pyramidal core, the comparison gives us the opportunity to investigate the unit cell strut angle giving the higher mechanical properties. The presented work considers a detailed FEM modelling of a standard 3-point bending test (ASTM C393/C393M Standard Practice). Detailed FEM modelling addresses to detailed discretization of cores by means of beam elements for lattice core and shell elements for honeycomb core. Facings, instead, have been modelled by using shell elements for both sandwich panels. On lattice core structure, elements of core and facings are directly connected, to better simulate the additive manufacturing process. Otherwise, an MPC-based constraint between facings and core has been used for honeycomb core structure. Both sandwich panels are entirely built of Aluminium alloy. Prior to compare the two models, the FEM sandwich panel model with lattice pyramidal core needs to be validated with 3-point bending test experimental results, in order to ensure a good reliability of the FEM approach and of the comparison. Furthermore, the analytical validation has been performed according to Allen's theory. The FEM analysis is linear static with an increasing midspan load ranging from 50N up to 500N.

• Bulletin of the Korean Chemical Society
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• 제27권2호
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• pp.251-254
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• 2006

The formation of polyaniline (PANI) in the reverse micelles of poly(oxyethylene) nonylphenyl ether, $(NP5, H(CH_2)_9Ph(OC_2H_4)_5OH)$, was investigated by small-angle neutron scattering (SANS). The reverse micellar solution containing initiators in the inner part of reverse micelle was prepared with surfactant (NP5), water, cyclohexane and an initiator (ammonium persulfate (APS)). The core-shell sphere model containing smearing effect reveals that the polymerization occurs on the shell layer of the reverse micelles. Shell thickness averages varied from 48 $\AA$ to 109 $\AA$ with increases of monomer concentration.