• Title/Summary/Keyword: Copper removal

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A Simple and Modified Photometric Method for Measuring Lipase Activity (리파제 활성측정을 위한 간편한 비색정량법)

  • Kim, Chul-Jin;Cheigh, Hong-Sik;Byun, Si-Myung
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.251-253
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    • 1984
  • A simple and modified method is developed to determine a lipase activity. A linear relationship exists between the color intensity and the free fatty acid liberated by enzyme action. The range of determination is from 0.05 to $1.5\;{\mu}moles$ of long chain fatty acid (oleic acid) and 0.2 to $2.0\;{\mu}moles$ of short chain fatty acid (caproic acid). The cumbersome procedure of the removal of the upper aqueous phase which was required in the previous copper soap extraction method was eliminated by the movement of solvent phase to upper phase in the respective biphasic system with a mixture solvent (chloroform: n-hexane:ethanol = 49:49:2) and copper reagent saturated with sodium chloride.

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The Studies on the Removal of Harmful Microorganisms in Water by Using Antimicrobial Copper (친환경 항균성 구리의 수질 내 생물학적 오염원 제거 가능성 연구)

  • Ji, Keunho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.384-390
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    • 2018
  • Air and soil are being contaminated by the environmental pollution as a result of climate change and urbanization, resulting in water pollution reaching serious levels. In this studies, we investigated the use of antimicrobial copper for the removal of biological pollutants from water system. Specifically, we tested its effects against E. coli, B. subtilis, S. aureus, K. pneumoniae and P. aeruginosa. Made a sphere shape having a diameter of 2cm using a strip-shaped copper wire of 0.5g, 1g and 2g. And then, to confirm the antimicrobial activities, each copper ball was equipped in the broth which inoculated each pathogens. The results showed that bacterial growth of the five test bacteria was inhibited by more than 99% after reaction with a 0.5 g copper ball for at least 20 minutes. Based on the these results, if perform the further experiment such cytotoxicity, it is expected that will be enough to be used as a filter for water quality purification. The developed technique is expected to be widely applied in various industries.

Heavy Metal Detection and Removal in Artificial Wastewater Using Two-Component System Based Recombinant Bacteria (Two-component System 기반 재조합균을 이용한 인공폐수에서의 중금속 인지 및 제거)

  • Ravikumar, Sambandam;Hong, Soon-Ho;Yoo, Ik-Keun
    • Korean Journal of Microbiology
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    • v.48 no.3
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    • pp.187-191
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    • 2012
  • Two-component system (TCS)-based bacterial zinc and copper biosensors, in which green fluorescent protein (GFP) is expressed under the control of zraP and cusC promoter in ZraS/R and CusS/R TCS, were evaluated in artificial wastewater. Bacterial biosensors developed in this study efficiently expressed GFP by the recognition of $Zn^{2+}$ and $Cu^{2+}$ in artificial wastewater. Secondly, TCS-based zinc and copper removing bacteria with the peptide displayed on cell surface were examined in artificial wastewater. Zinc and copper removing bacteria expressed the peptide as a fusion protein such as OmpC-ZBP (zinc binding peptide) and OmpC-CBP (copper binding peptide) on the cell surface when sensing exogenous $Zn^{2+}$ and $Cu^{2+}$ through ZraS/R and CusS/R TCS. The recombinant cell expressing metal-adsorbing peptide could efficiently remove copper and zinc (15 and 18 mg/g dry cell weight, respectively) in artificial wastewater. Therefore, it was demonstrated that the TCS-based recombinant cell for the recognition or removal of heavy metal functions well in artificial wastewater environment.

Adsorption Characteristics of Copper using Biochar Derived from Exhausted Coffee Residue (커피찌꺼기 biochar를 활용한 구리의 흡착특성)

  • Park, Jong-Hwan;Kim, Hong-Chul;Kim, Yeong-Jin;Kim, Seong-Heon;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.36 no.1
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    • pp.22-28
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    • 2017
  • BACKGROUND: There is very limited knowledge of the effects of biochar derived from exhausted coffee residue on metal adsorption processes. Furthermore, only limited information is available on the adsorption mechanism of copper. The aim of this study was to evaluate the absorption behaviors of copper by biochar derived from exhausted coffee residue. METHODS AND RESULTS: Biochars produced by pyrolysis of exhausted coffee residue at $300^{\circ}C$(CB300) and $600^{\circ}C$(CB600) were characterized and investigated as adsorbents for the removal of copper from aqueous solution. The results indicated that the adsorption equilibrium was achieved around 2 h and the pseudo-second-order kinetic model fit the data better than the pseudo-first-order kinetic model. The maximum Cu adsorption capacities of CB600 by Freundlich and Langmuir isotherms were higher than those of CB300. The adsorption data were well described by a Langmuir isotherm compare to Freundlich isotherm. CONCLUSION: Our results suggest that exhausted coffee residue can be used as feedstock materials to produce high quality biochar, which could be used as adsorbents to removal copper.

Modification of Vermiculite for Use as a Floating Adsorbent for Copper Removal (수중의 구리 제거를 위한 질석흡착제의 표면개질 연구)

  • Lee, Sangmin;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.11
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    • pp.5-14
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    • 2016
  • The main objective of this study was to evaluate the removal properties of Cu from existing exfoliated vermiculite (EV) coated with a mixed solution of sulfuric acid and glycerol on the $580^{\circ}C$ in heating, which uses coated with glycerol of copper ions can be removed more effectively. Serial batch kinetic tests and batch sorption tests were conducted to determine the removal characteristics for Cu in aqueous solution. The result of batch kinetic test shows that removal rate, $K_{obs}$ (1/hr), of Cu are 0.579, 0.878, 3.459, and 6.578 for MEV weight 1 g (25 g/L), 2 g (50 g/L), 3 g (75 g/L), 4 g (100 g/L), respectively. In this case the initial pH of the solution was 3.26. The removal experiment according to the concentration, $K_{obs}$ (1/hr), of Cu are 1.96, 0.878, 1.25, and 1.04 for the initial concentration of 3 mg/L, 5 mg/L, 8 mg/L, 10 mg/L, and the initial pH of the solution are 3.46, 3.26, 3.10, 2.96, respectively. Influence of initial pHs on Cu removal were tested under 1g of MEV with 5 mg/L of Cu solution. $K_{obs}$ (1/hr) were increased from 0.263 (pH 3) to 0.525 (pH 5). It leads to the conclusion that the removal rates are inversely proportional to the initial Cu concentration and are increased proportional to the initial pHs. Sorption capacity of MEV was determined by batch sorption tests. The maximum sorption capacity ($Q_{max}$) obtained from Langmuir was 0.761 mg/g, Linear and Freundlich partition coefficients were 0.494 L/g and 0.729 L/g (1/n = 0.476). These results show that the MEV could be used as an excellent adsorbent for copper contained in various types of aqueous solutions.

Treatment Characteristics of Plating Wastewater Containing Freecyanide, Cyanide Complexes and Heavy Metals (II) - Effect of Aldehyde Compounds and Polysulfide - (도금폐수내 유리시안과 착염시안 및 중금속의 처리특성 (II) - aldehyde와 polysulfide첨가에 따른 영향 -)

  • Jung, Yeon-Hoon;Lee, Soo-Koo
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.687-690
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    • 2010
  • The objective of this study is to investigate the effect of aldehyde compounds and ploysulfide as accelerating agents on removal of heavy metals and CN in plating wastewater. As a results of the experiments, the removal efficiency of cyanide using the formaldehyde type of aldehydes was the highest at pH 9. Next types were sodium formaldehyde bisulfite addut> paraldehyde> paraformaldehyde. Also, optimum pH and dosage for treating the residual heavy metals by using polysulfide were pH 9 and 30 mg/L, respectively. The removal efficiencies of cyanide, chromium, zinc and copper were above 96.7% at optimum condition.

Removal and Regeneration of $SO_2$ by Cupric Oxide Supported on Zeolite (CuO/Zeolite에 의한 $SO_2$의 제거 및 재생)

  • 이승재;신창섭;이태희
    • Journal of Korean Society for Atmospheric Environment
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    • v.6 no.2
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    • pp.161-167
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    • 1990
  • The reaction of sulfur dioxide with cupric oxide supported on zeolite was investigated over a temperature range of $250{\sim}450^{{\circ}C$. After the completion of the $SO_2$ removal reaction, the cupric sulfate produced was regenerated to copper by hydrogen or LPG. The experimental results showed that the removal efficiency of $SO_2$ was improved with temperature increase and with $SO_2$ inlet concentration decrease. The reaction of $SO_2$ with CuO/Zeolite was well explained by the shrinking unreacted core model using first order chemical reaction control and diffusion control. THe reaction rate constant and the effective diffusivity were respectively as follows: 1k (cm/s) = 2.519 exp[-10991 (cal/mol)/RT] $De(cm^2/s) = 2.06 \times 10^{-5} exp[-8380 (cal/mol)/RT]$

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The effect of buffing on particle removal in Post-Cu CMP cleaning (Post-Cu CMP cleaning에서 연마입자 제거에 buffing 공정이 미치는 영향)

  • Kim, Young-Min;Cho, Han-Chul;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.537-537
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    • 2008
  • Copper (Cu) has been widely used for interconnection structure in intergrated circuits because of its properties such as a low resistance and high resistance to electromigration compared with aluminuim. Damascene processing for the interconnection structure utilizes 2-steps chemical mechanical polishing(CMP). After polishing, the removal of abrasive particles on the surfaces becomes as important as the polishing process. In the paper, buffing process for the removal of colloidal silica from polished Cu wafer was proposed and demonstrated.

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Preparation of Solid-Phase Extractant by Immobilizing Di-(2-ethylhexyl)phosphoric Acid (D2EHPA) and Tri-butyl-phosphate (TBP) in Polysulfone and Removal Characteristics of Cu(II) (Polysulfone에 추출제 Di-(2-ethylhexyl)phosphoric acid (D2EHPA)와 tri-butyl-phosphate(TBP)를 고정화한 고체상 추출제의 제조와 Cu(II)의 제거 특성)

  • Kam, Sang-Kyu;Jeon, Jin-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.24 no.1
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    • pp.1-7
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    • 2015
  • The solid-phase extractant PS-D2EHPA/TBP was prepared by immobilizing two extractants D2EHPA and TBP in polysulfone (PS). The prepared PS-D2EHPA/TBP was characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal of Cu(II) from aqueous solution was investigated in batch system. The experiment data were obeyed the pseudo-second-order kinetic model. Equilibrium data were well fitted by Langmuir model and the removal capacity of Cu(II) by solid extractant PS-D2EHPA/TBP obtained from Langmuir model was 3.11 mg/g at 288 K. The removal capacity of Cu(II) was increased according to increasing pH from 2 to 6, but the removal capacity was decreased below pH 3 remarkably.