• 방사성폐기물학회지
• /
• 제19권2호
• /
• pp.225-231
• /
• 2021

The reaction between Li₂CO₃ and Cl₂ was investigated to verify its occurrence during a carbon-anode-based oxide reduction (OR) process. The reaction temperature was identified as a key factor that determines the reaction rate and maximum conversion ratio. It was found that the reaction should be conducted at or above 500℃ to convert more than 90% of the Li₂CO₃ to LiCl. Experiments conducted at various total flow rate (Q) / initial sample weight (W_i) ratios revealed that the reaction rate was controlled by the Cl₂ mass transfer under the experimental conditions adopted in this work. A linear increase in the progress of reaction with an increase in Cl₂ partial pressure (pCl₂) was observed in the pCl₂ region of 2.03-10.1 kPa for a constant Q of 100 mL·min^-1 and W_i of 1.00 g. The results of this study indicate that the reaction between Li₂CO₃ and Cl₂ is fast at 650℃ and the reaction is feasible during the OR process.

• Mass Spectrometry Letters
• /
• 제12권2호
• /
• pp.47-52
• /
• 2021

Evaluating the impurity concentrations in semiconductor thin films using time of flight secondary ion mass spectrometry (ToF-SIMS) is an effective technique. The mass interference between isotopes and matrix element in data interpretation makes the process complex. In this study, we have investigated the doping concentration of phosphorus in, phosphorus doped silicon thin film on glass using ToF-SIMS in the dynamic mode of operation. To overcome the mass interference between phosphorus and silicon isotopes, the quantitative analysis of counts to concentration conversion was done following two routes, standard relative sensitivity factor (RSF) and SIMetric software estimation. Phosphorus doped silicon thin film of 180 nm was grown on glass substrate using hot wire chemical vapor deposition technique for possible applications in optoelectronic devices. Using ToF-SIMS, the phosphorus-31 isotopes were detected in the range of 10¹~10⁴ counts. The silicon isotopes matrix element was measured from p-type silicon wafer from a separate measurement to avoid mass interference. For the both procedures, the phosphorus concentration versus depth profiles were plotted which agree with a percent difference of about 3% at 100 nm depth. The concentration of phosphorus in silicon was determined in the range of 10¹⁹~10²¹ atoms/cm³. The technique will be useful for estimating distributions of various dopants in the silicon thin film grown on glass using ToF-SIMS overcoming the mass interference between isotopes.

• 한국수소및신에너지학회논문집
• /
• 제32권6호
• /
• pp.636-641
• /
• 2021

Using numerical analysis, various factors influencing the performance development of high-pressure pumps for Dimethyl Ether (DME) engines were identified and the impact of each factor was evaluated using Taguchi method. DME fuels are more compressive than diesel fuels and have the lower heat generation, so it is necessary to increase the size of the plunger and speed (RPM) of the pump as well. In addition, it is necessary to change the shape and design of control valve to control the discharge flow and pressure. In this study, various variables affecting the performance and flow rate increase of high-pressure pumps for DME engines are planned using Taguchi method, and the best design method is proposed using correlation of the most important variables. As a result, we were able to provide the design value needed for a six-liter engine and provide optimal conditions. The best combination factors to optimize the flow rate at RPM 2,000 and diameter plunger with 20 mm. The regression equation can also be used to optimize the flow rate; -8, 13+0, 2552 RPM +54, 17 diam. Plunger.

• Nuclear Engineering and Technology
• /
• 제54권7호
• /
• pp.2579-2585
• /
• 2022

Ceramics of quaternary garnets (Gd,Y)₃Al₂Ga₃O₁₂ doped with Ce, Tb have been fabricated and evaluated as prospective materials for indirect energy converters of α-and β-voltaic. Samples were characterized at excitation with an X-ray source and an intense 150 keV electron beam and showed good temperature stability of their emission and tolerance to irradiation. The role of X-rays accompanied the α-particle emitting in the increase of the conversion efficiency is clarified. The garnet-type structure of the matrix in the developed materials allows the production of quality crystalline mass with a light yield exceeding that of the commonly used YAG: Ce scintillator by a factor of two times.

• 센서학회지
• /
• 제30권6호
• /
• pp.364-368
• /
• 2021

We developed a highly efficient organic photovoltaic (OPV) cell with a poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)]:[6,6]-phenyl-C71-butyric acid methyl ester active layer for harvesting lower-intensity indoor light energy to power various self-powered sensor systems that require power in the microwatt range. In order to achieve higher power conversion efficiency (PCE), we first optimized the thickness of the active layer of the OPV cell through optical simulations. Next, we fabricated an OPV cell with optimized active layer thickness. The device exhibited a PCE of 12.23%, open circuit voltage of 0.66 V, short-circuit current density of 97.7 ㎂/cm², and fill factor of 60.53%. Furthermore, the device showed a maximum power density of 45 ㎼/cm², which is suitable for powering a low-power (microwatt range) sensor system.

• Nuclear Engineering and Technology
• /
• 제54권1호
• /
• pp.293-300
• /
• 2022

During the decommissioning of the nuclear facilities, the radioactive gases in pressure vessels may leak due to the demolition operations. The decommissioning site has large space, slow air circulation, and many large nuclear facilities, which increase the difficulty of workers' inhalation exposure assessment. In order to dynamically evaluate the activity distribution of radionuclides and the committed effective dose from inhalation in nuclear decommissioning environment, an inhalation exposure assessment method based on the modified eddy-diffusion model and the inhaled dose conversion factor is proposed in this paper. The method takes into account the influence of building, facilities, exhaust ducts, etc. on the distribution of radioactive gases, and can evaluate the influence of radioactive gases diffusion on workers during the decommissioning of nuclear facilities.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제16권6호
• /
• pp.2094-2114
• /
• 2022

Due to the wide application of fifth generation communication, wireless sensor networks have become an indispensable part in our daily life. In this paper, we analyze physical layer security for two-way relay with energy harvesting (EH), where power splitter is considered at relay. And two kinds of combined methods, i.e., selection combining (SC) and maximum ratio combining (MRC) schemes, are employed at eavesdropper. What's more, the closed-form expressions for security performance are derived. For comparison purposes, this security behaviors for orthogonal multiple access (OMA) networks are also investigated. To gain deeper insights, the end-to-end throughput and approximate derivations of secrecy outage probability (SOP) under the high signal-to-noise ratio (SNR) regime are studied. Practical Monte-Carlo simulative results verify the numerical analysis and indicate that: i) The secure performance of SC scheme is superior to MRC scheme because of being applied on eavesdropper; ii) The secure behaviors can be affected by various parameters like power allocation coefficients, transmission rate, etc; iii) In the low and medium SNR region, the security and channel capacity are higher for cooperative non-orthogonal multiple access (NOMA) systems in contrast with OMA systems; iv) The systematic throughput can be improved by changing the energy conversion efficiency and power splitting factor. The purpose of this study is to provide theoretical direction and design of secure communication.

• Nuclear Engineering and Technology
• /
• 제55권9호
• /
• pp.3417-3422
• /
• 2023

Recently, as the clinically positive biological effects of ultra-high dose rate (UHDR) radiation beams have been revealed, interest in flash radiation therapy has increased. Generally, FLASH preclinical experiments are performed using UHDR electron beams generated by linear accelerators. Real-time monitoring of UHDR beams is required to deliver the correct dose to a sample. However, it is difficult to use typical transmission-type ionization chambers for primary beam monitoring because there is no suitable electrometer capable of reading high pulsed currents, and collection efficiency is drastically reduced in pulsed radiation beams with ultra-high doses. In this study, a monitoring method using bremsstrahlung photons generated by irradiation devices and a water phantom was proposed. Charges collected in an ionization chamber located at the back of a water phantom were analyzed using the bremsstrahlung tail on electron depth dose curves obtained using radiochromic films. The dose conversion factor for converting a monitored charge into a delivered dose was determined analytically for the Advanced Markus® chamber and compared with experimentally determined values. It is anticipated that the method proposed in this study can be useful for monitoring sample doses in UHDR electron beam irradiation.

• 한국해양학회지:바다
• /
• 제12권3호
• /
• pp.234-238
• /
• 2007

현재까지 우리나라에선 연구자마다 각기 다른 세 가지 조석지각 기준(관측지점 경도 기준 지각, 표준시 자오선 기준 지각, 그리니치 자오선 기준 지각)을 사용하여 오고 있다. 이처럼 통일되지 않는 조석지각 정보체계는 전체적인 우리나라 조석의 특성이나 변화를 이해하는데 장애가 되고 있다. 이 연구에서는 올바른 조석지각 기준의 상호전환과 관련하여, 세 가지 지각기준에 관하여 자세히 살펴보았다. 이에 앞서 조석 조화분해 과정에서 분조의 지각이 어떻게 계산되며, 조석예측프로그램에선 계산된 지각이 어떻게 사용되게 되는지 살펴보았다. 또한 이것을 바탕으로 과거 일부 연구에서 불명확하게 기술된 조석지각의 정의에 관하여 논의하였다.

• 방사선산업학회지
• /
• 제17권2호
• /
• pp.209-217
• /
• 2023

The biosphere has important function in the safety assessment of a radioactive waste disposal facility. A biosphere model in the safety assessment needs various input data that contain significantly inherent uncertainties. This paper reviews the effects of the input data on the radiological impact assessment from main radionuclides such as ¹⁴C and ⁹⁹Tc in the biosphere model. In addition, it is confirmed that the safety criteria is met, when the conservative input data for the intake rate, soil to plant concentration ratio, and distribution coefficients of the radionuclides are applied and probabilistic analysis are conducted in the biosphere model. Nevertheless, it is required to generate site-specific input data for the confidence building and reduce excessive conservatism in the biosphere model.