• Title/Summary/Keyword: Constituent analysis

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Identification of the Materials of the Decorative Pieces Excavated from Geumnyeongchong Tomb (금령총 출토 장식편 재질 규명)

  • Lee Gyuhye;Shin Seungchul;Gwak Hongin;Yang Seokjin
    • Conservation Science in Museum
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    • v.30
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    • pp.89-100
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    • 2023
  • Museum collections are comprised of a variety of materials, and different scientific examinations are being conducted according to the types and production properties of the materials, but insufficient research has been carried out on ultra-small artifacts. To identify the material characteristics of the white ultra-small materials excavated from Geumnyeongchong tomb, this study carried out a wide range of non-destructive analyses (specific gravity, microscopy, nano-computed tomography (Nano-CT), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), X-ray diffraction (XRD), and Raman spectroscopy) and compared the said artifacts with the Goryeo-era burial accessories examined in prior research. Non-destructive analysis confirmed the presence of aragonite, which mainly consists of calcium carbonate (CaCO3) as the constituent mineral, and identified the material used for the ornaments as the gemstone pearl based on its growth lines. This study concludes that pearls began to be used in the ancient Korean Peninsula in the 6th century. It is expected that scientific examinations of the white ultra-small artifacts will yield information about the social culture of the time.

Quantitative Elemental Analysis in Soils by using Laser Induced Breakdown Spectroscopy(LIBS) (레이저유도붕괴분광법을 활용한 토양의 정량분석)

  • Zhang, Yong-Seon;Lee, Gye-Jun;Lee, Jeong-Tae;Hwang, Seon-Woong;Jin, Yong-Ik;Park, Chan-Won;Moon, Yong-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.5
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    • pp.399-407
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    • 2009
  • Laser induced breakdown spectroscopy(LIBS) is an simple analysis method for directly quantifying many kinds of soil micro-elements on site using a small size of laser without pre-treatment at any property of materials(solid, liquid and gas). The purpose of this study were to find an optimum condition of the LIBS measurement including wavelengths for quantifying soil elements, to relate spectral properties to the concentration of soil elements using LIBS as a simultaneous un-breakdown quantitative analysis technology, which can be applied for the safety assessment of agricultural products and precision agriculture, and to compare the results with a standardized chemical analysis method. Soil samples classified as fine-silty, mixed, thermic Typic Hapludalf(Memphis series) from grassland and uplands in Tennessee, USA were collected, crushed, and prepared for further analysis or LIBS measurement. The samples were measured using LIBS ranged from 200 to 600 nm(0.03 nm interval) with a Nd:YAG laser at 532 nm, with a beam energy of 25 mJ per pulse, a pulse width of 5 ns, and a repetition rate of 10 Hz. The optimum wavelength(${\lambda}nm$) of LIBS for estimating soil and plant elements were 308.2 nm for Al, 428.3 nm for Ca, 247.8 nm for T-C, 438.3 nm for Fe, 766.5 nm for K, 85.2 nm for Mg, 330.2 nm for Na, 213.6 nm for P, 180.7 nm for S, 288.2 nm for Si, and 351.9 nm for Ti, respectively. Coefficients of determination($r^2$) of calibration curve using standard reference soil samples for each element from LIBS measurement were ranged from 0.863 to 0.977. In comparison with ICP-AES(Inductively coupled plasma atomic emission spectroscopy) measurement, measurement error in terms of relative standard error were calculated. Silicon dioxide(SiO2) concentration estimated from two methods showed good agreement with -3.5% of relative standard error. The relative standard errors for the other elements were high. It implies that the prediction accuracy is low which might be caused by matrix effect such as particle size and constituent of soils. It is necessary to enhance the measurement and prediction accuracy of LIBS by improving pretreatment process, standard reference soil samples, and measurement method for a reliable quantification method.

An Analysis of Aerosol Mass Concentrations and Elemental Constituents Measured at Cheongwon depending on the Backward Trajectories of Air Parcel in East Asia in 2011 (2011년 동아시아에서 기류의 이동 경로에 따른 청원에서 측정한 에어로졸 질량 농도 및 원소 성분 분석)

  • Kim, Hak-Sung;Byun, Kwang-Tae;Chung, Yong-Seung;Choi, Hyun-Jung;Kim, Min-Jung
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.855-863
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    • 2012
  • This study analyzed mass concentrations of TSP, PM10 and PM2.5 and elemental constituents according to the isentropic backward trajectories of air parcel from Cheongwonin East Asia during the period January - October, 2011. Mass concentrations of the continental polluted airflow (CP) showed levels of TSP and PM10 mass concentrations higher than the continental background airflow (CB). Also, PM2.5 mass concentrations of anthropogenic fine particles ran higher in CP than in CB. The elemental constituents and elemental constituent ratio ended up varying depending on the origin of atmospheric aerosols generated. The average absolute content of elemental constituents reached its height in CB, the ratio of anthropogenically originating elements (PE) among the all elements (AE) analyzed marked a high in CP, and Mg+Na/AE reached its height in the oceanic airflow (OA). At the same time, TSP, PM10 and PM2.5 mass concentrations, the ratio of PM2.5/TSP and PE/AE element ratio ran higher in CP than CB. Episodes of large-scale transport of atmospheric pollutants as observed at Cheongwon were 8 cases and 22 days. The ratios of PM10, PM2.5 among TSP mass concentrations showed different results and the ratios of PM2.5 showed an increasing trend in the episodes of anthropogenic air pollution transport. Overall, dustfall episodes show a level of elemental constituents higher than those of anthropogenic air pollution.Dustfall episodes were observed to contain more of Fe, Al and Ca originating from continental soils and those of air pollution were observed to contain more of Zn, Mn, Cu and Pb. By difference in contents of absolute elemental constituents, episodes of anthropogenic air pollution showed a high PE/AE rate, and dustfall episodes a high SE/AE rate.

A Study on the Influence of the Organizational Culture of Korean Network Marketing Companies on Customer Orientation and Service Orientation (한국형 네트워크 마케팅 기업의 조직문화가 고객 지향성과 서비스지향성에 미치는 영향에 관한 연구)

  • Kim, Moon-Jun
    • Industry Promotion Research
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    • v.5 no.4
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    • pp.29-37
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    • 2020
  • The purpose of this study was to confirm the influence of the types of organizational culture perceived by members of Korean network companies on customer orientation and service orientation. Therefore, the results of the valid survey for the final 165 among the results of 204 applicants for about two weeks from September 7th to 25th, 2020 using the SSP 24.0 and AMOS 24.0 statistical package programs showed the following results. First, as a result of the analysis of the impact of organizational culture on customer orientation, the sub-factors of the organizational culture, such as relationship-oriented culture, innovation-oriented culture, hierarchical-oriented culture, and task-oriented culture types, all had a positive (+) effect on customer-oriented. It was analyzed as crazy. In other words, it can be seen that the organizational culture has a statistically significant impact on customer orientation in that it gives positive meaning through a comprehensive operation rather than a single substructure. Second, as a result of analyzing the effect of organizational culture on service orientation, organizational culture showed positive (+) influence on service orientation. In other words, it was analyzed that relational orientation, innovation orientation, hierarchical orientation, and task orientation, which are sub-constituent factors of organizational culture, act as positive factors for service orientation.

Lattice Preferred Orientation(LPO) and Seismic Anisotropy of Amphibole in Gapyeong Amphibolites (경기육괴 북부 가평 지역에 분포하는 각섬암 내부 각섬석의 격자선호방향(LPO)과 지진파 비등방성)

  • Kim, Junha;Jung, Haemyeong
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.259-272
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    • 2020
  • The seismic properties in the crust are affected by the lattice preferred orientation(LPO) of major minerals in the crust. Therefore, in order to understand the internal structure of the crust using seismic data, information on the LPO of the major constituent minerals and the seismic properties of major rocks in a specific region are needed. However, there is little research on the LPOs of minerals in the crust in Korea. In this study, we collected amphibolites from two outcrops in Wigokri, Gapyeong, located in the nothern portion of Gyeonggi Massif, and we measured the LPOs of major minerals of amphibolite, especially amphibole and plagioclase through EBSD analysis, and calculated seismic properties of amphibolite. Two types of LPOs of amphibole, which are defined as type I and type IV, were observed in the two outcrops of Gapyeong amphibolites, respectively. In the case of amphibolites with the type I LPO of amphibole, large seismic anisotropy of both P- and S-wave was observed, while in the amphibolites with the type IV LPO of amphibole, small seismic anisotropy was observed. This is consistent with previous experimental results. The polarization direction of the fast S-wave was aligned subparallel to the lineation regardless of the LPO types of amphibole. The seismic anisotropy observed in Gapyeong is expected to be helpful to interpret the structure and seismic data within the crust in Gyeonggi Massif.

Synthesis, Structure and Characterization of Nd2XCd2-3XSiO4 (0.01≤X≤0.21) Solid-Solutions (Nd2XCd2-3XSiO4 (0.01≤X≤0.21) 고용체의 합성과 구조 규명)

  • Ramesh, S.;Das, B.B.
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.502-508
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    • 2011
  • Synthesis of $Nd_{2x}Cd_{2-3x}SiO_4$ ($0.01{\leq}x{\leq}0.21$) [S1-S3: x=0.01, 0.11 and 0.21] solid solutions were prepared by solgel method. Powder x-ray diffraction (XRD) results show monoclinic unit cell with space group P21/m. The average crystallite sizes are found to be 20 to 45 nm. The Scanning Electron Microcopy (SEM) images show morphology of the sample is in globular nature. The energy dispersive analysis of x-rays (EDX) and X-ray mapping results confirmed that all the constituent elements of the composites were present and that were distributed in uniformly. The optical absorption band at ~750 nm was due to $^4I_{9/2}{\rightarrow}^4F_{7/2}+^4S_{3/2}$ transition optically active $Nd^{3+}$ ions. Electron Paramagnetic Resonance (EPR) lineshapes of S1-S3 at 10, 40, 77 and 300 K show a broad unresolved isotropic lineshapes were observed due to rapid spin lattice relaxation of $Nd^{3+}$.

Performance Comparison between Random CA Group Authentication and Home CA Authentication in Mobile Ad hoc Network (모바일 애드혹 네트워크에서 임의의 CA 그룹을 이용한 이동노드의 인증과 홈 CA를 이용한 인증방법의 성능 비교)

  • Lee, Yong;Lee, Goo-Yeon
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.10
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    • pp.40-48
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    • 2008
  • Security of self organized mobile ad hoc networks is an important issue because administration information in the networks is managed by the constituent nodes. Especially authentication mechanism is necessary for trust setup between newly joining nodes and the network. The authentication models and protocols which are based on the wireline infrastructure could not be practical for mobile ad hoc network. Although public key algorithm-based method is widely used for authentication, it is not easy to be applied to mobile ad hoc networks because they do not have infrastructure such as centralized CA which is needed for certificate verification. In this paper, we consider the public key based random CA group method proposed in [1] to provide efficient authentication scheme to mobile ad hoc networks and analyze the performance of the method, which is then compared to the home CA method. From the analysis results, we see that the random CA method where the function of CA is distributed to some mobile nodes and the authentication information is propagated to randomly chosen CAs shows higher reliability and lower cost than home CA method.

Fumigant Toxicity of the Constituents of Coriander Oil, Coriandum sativum against Blattella germanica (바퀴에 대한 Coriander Oil (Coriandum sativum) 성분의 훈증효과)

  • Bae Jeong-Sook;Kim Gil-Hah
    • Korean journal of applied entomology
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    • v.44 no.1 s.138
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    • pp.37-41
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    • 2005
  • Essential oil of five plants were screened for fumigation toxicity against Blattella germanica male adults. Among them, coriander oil showed $100\%$ fumigation toxicity against B. germanica male adults at 20 and $10{\mu}{\ell}/{\ell}$ (air) dose, respectively. Through the constituent analysis using GC and GC/MS, we confirmed that main constituents of coriander oil were ${\alpha}$-pinene ($6.1\%$), camphene ($1.1\%$), ${\beta}$-pinene ($0.5\%$), ${\beta}$-myrcene ($0.8\%$), limonene ($2.5\%$), ${\gamma}$-terpinene ($4.5\%$), ${\rho}$-cymene ($1.8\%$), ${\alpha}$-terpinolene ($0.5\%$), camphor ($4.9\%$), linalool ($70.5\%$), ${\alpha}$-tepineol ($0.7\%$), geranyl acetate ($2.8\%$) and geraniol ($1.4\%$). Among them, ${\gamma}$-terpinene and geranyl acetate showed $100\%$ fumigation toxicity at $10{\mu}{\ell}/{\ell}$ (air) dose, respectively. It can be concluded that coriander oil is potential control agents against B. germanica.

A Study on Surface Characteristics and Stability of Implants Treated with Anodic Oxidation and Fluoride Incorporation (양극 산화와 불소 화합물로 처리한 임플랜트의 표면 특성 및 골유착 안정성에 관한 연구)

  • Lim, Jae-Bin;Cho, In-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.4
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    • pp.349-365
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    • 2006
  • State of problem : A number of investigation about increase of surface area via various surface treatments and modification of surface constituent have been carried out. Purpose : The surface characteristics and stability of implants treated with anodic oxidation, fluoride ion incorporation, and groups treated with both methods were evaluated. Material and method : Specimens were divided into six groups, group 1 was the control group with machined surface implants, groups 2 and 3 were anodic oxidized implants (group 2 was treated with 1M $H_2SO_4$ and 185V, group 3 was treated with 0.25M $H_2SO_4$ and $H_3PO_4$ and 300V). Groups 4, 5 and 6 were treated with fluoride. Group 4 was machined implants treated with 0.1% HF, and groups 5 and 6 were groups 2 and 3 treated with 10% NaF respectively. Using variable methods, implant surface characteristics were observed, and the implant stability was evaluated on rabbit tibia at 0, 4, 8 and 12 weeks. Result : 1. In comparison of the surface characteristics of anodic oxidized groups, group 2 displayed delicate and uniform oxidation layer with small pore size containing Ti, C, O and showed mainly rutile, but group 3 displayed large pore size and irregular oxidation layer with many crators. 2. In comparison of the surface characteristics of fluoride treated groups 4, 5, 6 and non-fluoride treated groups 1, 2, 3, the configurations were similar but the fluoride treated groups displayed rougher surfaces and composition analysis revealed fluoride in groups 4, 5, 6. 3. The fluoride incorporated anodic oxidized groups showed the highest resonance frequency values and removal torque values, and the values decreased in the order of anodic oxidized groups, fluoride treated group, control group. 4. According to implant stability tests, group 2 and 3 showed significantly higher values than the control group (P<.05). The fluoride treated groups showed relatively higher values than the non fluoride treated groups and there were significant difference between group 4 and group 1 (P<.05). Conclusion : From the results above, it can be considered that the anodic oxidation method is an effective method to increase initial bone stability and osseointegration and fluoride containing implant surfaces enhance new bone formation. Implants containing both of these methods should increase osseointegration, and reduce the healing period.

A Study on Preference Analysis on Eating/Drinking Table Decoration - Centering on Color Image and Aesthetic Value (실용 테이블 데커레이션에 대한 선호 분석에 관한 연구 - 색채 조화의 이미지 및 심미성의 영향요소를 중심으로 -)

  • Jang, Young-Soon;Hong, Jung-Pyo;Kim, Tai-Ho
    • Science of Emotion and Sensibility
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    • v.9 no.spc3
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    • pp.187-196
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    • 2006
  • This study has showed verified results on 'Survey into Observer Preference for Table Decoration for Eating and Drinking'. It is a preliminary study to look into interrelation of preference to color tables, image adjectives, aesthetic value, by giving color changes in a certain regularity to each influential factor in functional table decoration. The result has demonstrated that, as for color image and preference,'observers prefers mid/low dark-toned brown which gives a feeling of 'high-quality, and like to eat', and orange tone with a fooling of 'warm and colorful'. In evaluating interrelation between preference and aesthetic value, the study has revealed that ordinary people take the influential factor of 'unity and Gestalt' seriously, while non-professionals preferred 'uniqueness'. Stimulant No. 7 is one of constituent factors of functional table decoration, eliciting significance of images on colors ant aesthetic value. This study also has practical problems about insufficiency or inadequateness in producing mood suitable to T P O, according to depending upon color changes in picking up stimulants, or other problems in selecting stimulants, according to time, seasons and generational parameter in which the inquiry is conducted, but it will serve as a stepping stone for developing new design using both qualitative and quantitative data in 려nctional table decoration.

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