• Title/Summary/Keyword: Consecutive process

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Study on the Development of CVD Precursors II-Synthesis and Properties of New Lathanum β-diketonates

  • 임종태;홍성택;이중철;이익모
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.1023-1031
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    • 1996
  • A new synthetic route for the lanthanum β-diketonate compounds via in-situ formed lanthanum alkyl complexes was developed in the process for the development of suitable MOCVD (metal-organic chemical vapor deposition) precursors of PLT, one of the promising material for the ferroelectric film. A series of lanthanum β-diketonate compounds were successfully synthesized by this method. This new method is found to have some merits; versatile method for almost every β-diketone, β-hydroxyketone, and β-hydroxyaldehyde, short reaction time, easy purification for high purity, moderate to high yield, and easy access to anhydrous compounds. In some cases, anhydrous oligomeric products fail to show the higher volatility. On the other hand, some lanthanum β-diketonates with aromatic groups such as La(1,3-biphenyl-l,3-propandione)3 are found to have favorable properties for a precursor of lanthanum oxide, one of major components of PLT, such as low melting point, and much higher decomposition temperature. A plausible pyrolysis mechanism is proposed by the TGA, where consecutive dissociation of R, CO, CH, C, and O fragments occurs.

Encapsulation of Nanomaterials within Intermediary Layer Cross-linked Micelles Using a Photo-Cross-linking Agent

  • Kim, Jin-Sook;Youk, Ji-Ho
    • Macromolecular Research
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    • v.17 no.11
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    • pp.926-930
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    • 2009
  • A new method for encapsulating nanomaterials within intermediary layer cross-linked (ILCL) polymeric micelles using a bifunctional photo-cross-linking agent was developed. For ILCL polymeric micelles, an amphiphilic triblock copolymer of poly(ethylene glycol)-b-poly(2-hydroxyethyl methacrylate)-b-poly(methyl methacrylate) (PEG-PHEMA-PMMA) was synthesized via consecutive atom transfer radical polymerization (ATRP), Di(4-hydroxyl benzophenone) dodecanedioate (BPD) was used as a bifunctional photo-cross-linking agent. The PMMA-tethered Au nanoparticles and BPD, or pyrene and BPD were encapsulated in the PEG-PHEMA-PMMA micelles, and their intermediary layers were photo-cross-linked by UV irradiation for 1 h. The HEMA units donated labile hydrogens to the excited-state benzophenone groups in BPD, and they were subsequently cross-linked by BPD through radical-radical combination. The spherical structures of the PEG-PHEMA-PMMA micelles containing the Au nanoparticles or pyrene were unaffected by the photo-cross-linking process.

Scene-based Nonuniformity Correction by Deep Neural Network with Image Roughness-like and Spatial Noise Cost Functions

  • Hong, Yong-hee;Song, Nam-Hun;Kim, Dae-Hyeon;Jun, Chan-Won;Jhee, Ho-Jin
    • Journal of the Korea Society of Computer and Information
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    • v.24 no.6
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    • pp.11-19
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    • 2019
  • In this paper, a new Scene-based Nonuniformity Correction (SBNUC) method is proposed by applying Image Roughness-like and Spatial Noise cost functions on deep neural network structure. The classic approaches for nonuniformity correction require generally plenty of sequential image data sets to acquire accurate image correction offset coefficients. The proposed method, however, is able to estimate offset from only a couple of images powered by the characteristic of deep neural network scheme. The real world SWIR image set is applied to verify the performance of proposed method and the result shows that image quality improvement of PSNR 70.3dB (maximum) is achieved. This is about 8.0dB more than the improved IRLMS algorithm which preliminarily requires precise image registration process on consecutive image frames.

A Spatial-Temporal Three-Dimensional Human Pose Reconstruction Framework

  • Nguyen, Xuan Thanh;Ngo, Thi Duyen;Le, Thanh Ha
    • Journal of Information Processing Systems
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    • v.15 no.2
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    • pp.399-409
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    • 2019
  • Three-dimensional (3D) human pose reconstruction from single-view image is a difficult and challenging topic. Existing approaches mostly process frame-by-frame independently while inter-frames are highly correlated in a sequence. In contrast, we introduce a novel spatial-temporal 3D human pose reconstruction framework that leverages both intra and inter-frame relationships in consecutive 2D pose sequences. Orthogonal matching pursuit (OMP) algorithm, pre-trained pose-angle limits and temporal models have been implemented. Several quantitative comparisons between our proposed framework and recent works have been studied on CMU motion capture dataset and Vietnamese traditional dance sequences. Our framework outperforms others by 10% lower of Euclidean reconstruction error and more robust against Gaussian noise. Additionally, it is also important to mention that our reconstructed 3D pose sequences are more natural and smoother than others.

Simplified Representation of Image Contour

  • Yoo, Suk Won
    • International Journal of Advanced Culture Technology
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    • v.6 no.4
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    • pp.317-322
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    • 2018
  • We use edge detection technique for the input image to extract the entire edges of the object in the image and then select only the edges that construct the outline of the object. By examining the positional relation between these pixels composing the outline, a simplified version of the outline of the object in the input image is generated by removing unnecessary pixels while maintaining the condition of connection of the outline. For each pixel constituting the outline, its direction is calculated by examining the positional relation with the next pixel. Then, we group the consecutive pixels with same direction into one and then change them to a line segment instead of a point. Among those line segments composing the outline of the object, a line segment whose length is smaller than a predefined minimum length of acceptable line segment is removed by merging it into one of the adjacent line segments. As a result, an outline composed of line segments of over a certain length is obtained through this process.

Visualization Study on Microscale Wetting Dynamics of Water Droplets on Dry and Wet Hydrophilic Membranes

  • Park, Kyungjin;Kim, Seong Yeon;Hong, Jiwoo;Kim, Jong Hyun;Lim, Geunbae
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.277-281
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    • 2022
  • The wetting dynamics of water droplets dispensed on the surface of dry and wet hydrophilic membranes were investigated experimentally from a microscale point of view. By using a high-speed, white-beam x-ray microimaging (WXMI) synchrotron, consecutive images displaying the dynamic motions of the droplets were acquired. Through analyzing the characteristics observed, it was found that the dry hydrophilic membrane showed local hydrophobicity at a certain point during the absorption process with apparent contact angles greater than 90. While on the other hand, the apparent contact angles of a water droplet absorbing into the wet membrane remained less than 90 and showed total hydrophilicity. The observations and interpretation of characteristics that affect the contact, wetting, recoiling, and dynamic behaviors of droplets are significant for controlling liquid droplet impingement in a desired manner.

Evaluation of Coraco-Acromial Arch in Patients with Impingement Syndrome (견관절 충돌 증후군 환자에서 오훼 견봉궁의 자기공명 영상 평가)

  • Rhee Kwang-Jin;Byun Ki-Yong;Kwon Soon-Tae;Byun Kyu-Hwan
    • Clinics in Shoulder and Elbow
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    • v.2 no.1
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    • pp.35-40
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    • 1999
  • Impingement syndrome is caused by a conflictual status between rotator cuff, subacromial bursa and anatomic and functional coracoacromial arch. The purpose of this study was to assessment the coracoacromial arch by MRI and to determine major factors among five components of coracoacromial arch. We analyzed forty-two cases of clinical impingement sign and test positive and postoperative confirmed diagnosed from March, 1991 to January, 1999. We evaluated acromial end abnormality according to the Bigliani acromial type and formation of osteophyte. Clavicular end abnormality classified flat, outward protrusion, inward protrusion to coracoacromial arch. Acromioclavicular joint abnormalities were advanced osteoarthritis and positive signal change. Coracoacromial ligament thickening was above 2 mm in oblique sagittal image. Coracoid process abnormality was inward protrusion to coracoacromial arch. All consecutive patients abnormalities were as follows: clavicular end osteophyte formation and inward protrusion to coracoacrmial arch were 30%, acromial end osteophyte formation was 28%, advanced acromioclavicular joint arthritis and osteophyte formation were 56%, coracoacromial ligament thickening was 24% and no coracoid process inward protrusion to coracoacromial arch. Impingement syndrome combined with rotator cuff tear group abnormalities were clavicular end(40%), acromial end(40%), acromioclavicular joint(20%), coracoacromialligament(20%) and coracoid process abnormality(0%) respectively. Only impingement syndrome group abnormalities were clavicular end(25%), acromial end(31%), acromioclavicular joint(62%), coracoacromial ligament(25%) and coracoid process(0%) respectively. Acromial type I(flat) were 6 cases, type II(curved) were 26 cases and type III(hooked) were 10 cases. We concluded that the most important contributing factors for impingement syndrome was acromial type and second was acromioclavicular joint arthritis and bony spur formation.

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Fault Detection and Diagnosis for Induction Motors Using Variance, Cross-correlation and Wavelets (웨이블렛 계수의 분산과 상관도를 이용한 유도전동기의 고장 검출 및 진단)

  • Tuan, Do Van;Cho, Sang-Jin;Chong, Ui-Pil
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.7
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    • pp.726-735
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    • 2009
  • In this paper, we propose an approach to signal model-based fault detection and diagnosis system for induction motors. The current fault detection techniques used in the industry are limit checking techniques, which are simple but cannot predict the types of faults and the initiation of the faults. The system consists of two consecutive processes: fault detection process and fault diagnosis process. In the fault detection process, the system extracts the significant features from sound signals using combination of variance, cross-correlation and wavelet. Consequently, the pattern classification technique is applied to the fault diagnosis process to recognize the system faults based on faulty symptoms. The sounds generated from different kinds of typical motor's faults such as motor unbalance, bearing misalignment and bearing loose are examined. We propose two approaches for fault detection and diagnosis system that are waveletand-variance-based and wavelet-and-crosscorrelation-based approaches. The results of our experiment show more than 95 and 78 percent accuracy for fault classification, respectively.

The Gauss, Rayleigh and Nakagami Probability Density Distribution Based on the Decreased Exponential Probability Distribution (감쇄지수함수 확률분포에 의한 가우스, 레일레이, 나카가미 확률 밀도 분포)

  • Kim, Jeong-Su;Lee, Moon-Ho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.6
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    • pp.59-68
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    • 2017
  • Random process plays a major role in wireless communication system to analytically derive the probability distribution function of the various statistical distribution. In this paper, we derive the decreasing function of the exponential distribution under the given condition which is expressed as wireless channel condition. The probability distribution function of Gaussian, Laplacian, Rayleigh and Nakagami distribution are also derived. Extensive simulation results of these statistical distributions are provided to prove that random process has a significant role in the wireless communications. In addition, the Rayleigh and Rician channels show specific examples of visible distance communication and invisible distance channel environment. This paper is motivated by that we assume a block fading channel model, where the channel is constant during a transmission block and changes independently between consecutive transmission block, can achieve a better performance in high SNR regime with i.i.d channel. This algorithm for realizing these transforms can be applied to the Kronecker MIMO channel.

An Evaluation of Multiple-input Dual-output Run-to-Run Control Scheme for Semiconductor Manufacturing

  • Fan, Shu-Kai-S.;Lin, Yen
    • Industrial Engineering and Management Systems
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    • v.4 no.1
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    • pp.54-67
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    • 2005
  • This paper provides an evaluation of an optimization-based, multiple-input double-output (MIDO) run-to-run (R2R) control scheme for general semiconductor manufacturing processes. The controller in this research, termed adaptive dual response optimizing controller (ADROC), can serve as a process optimizer as well as a recipe regulator between consecutive runs of wafer fabrication. In evaluation, it is assumed that the equipment model could be appropriately described by a pair of second-order polynomial functions in terms of a set of controllable variables. Of practical relevance is to consider a drifting effect in the equipment model since in common semiconductor practice the process tends to drift due to machine aging and tool wearing. We select a typical application of R2R control to chemical mechanical planarization (CMP) in semiconductor manufacturing in this evaluation, and there are five different CMP process scenarios demonstrated, including mean shift, variance increase, and IMA disturbances. For the controller, ADROC, an on-line estimation technique is implemented in a self-tuning (ST) control manner for the adaptation purpose. Subsequently, an ad hoc global optimization algorithm based on the dual response approach, arising from the response surface methodology (RSM) literature, is used to seek the optimum recipe within the acceptability region for the execution of next run. The main components of ADROC are described and its control performance is assessed. It reveals from the evaluation that ADROC can provide excellent control actions for the MIDO R2R situations even though the process exhibits complicated, nonlinear interaction effects between control variables, and the drifting disturbances.